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European Journal of Physics

Expanding wave packets and the quantum to classical transition

J S Briggs

Published May 22, 2024• 1 citation
Publisher

Abstract

Abstract The standard description of the transition from quantum to classical mechanics presented in most text books is the proof that the quantum expectation values of position and momentum obey equations of Newtonian form. This is the Ehrenfest theorem. It is combined with the requirement that wave packets remain localised to describe a single particle moving according to classical mechanics. Hence, the natural spreading of wave packets is viewed as a quantum effect. In contradiction to this view, here it is argued that the spreading, where different momentum components separate, is the signature of the quantum to classical transition. The asymptotic spatial wave function becomes proportional to the initial momentum space wave function, which mirrors exactly the well-known far-field diffraction pattern in optics. Trajectories, defined as the locus of the normals to the expanding wave front, are used to illustrate the transition from quantum to classical motion. Again this is the analogue of the wave to beam transition in optics. It is suggested that this analysis of the quantum to classical transition should be incorporated routinely into introductory quantum mechanics courses.

DOI
10.1088/1361-6404/ad4f35

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Abstract The standard description of the transition from quantum to classical mechanics presented in most text books is the proof that the quantum expectation values of position and momentum obey equations of Newtonian form. This is the Ehrenfest theorem. It is combined with the requirement that wave packets remain localised to describe a single particle moving according to classical mechanics. Hence, the natural spreading of wave packets is viewed as a quantum effect. In contradiction to this view, here it is argued that the spreading, where different momentum components separate, is the signature of the quantum to classical transition. The asymptotic spatial wave function becomes proportional to the initial momentum space wave function, which mirrors exactly the well-known far-field diffraction pattern in optics. Trajectories, defined as the locus of the normals to the expanding wave front, are used to illustrate the transition from quantum to classical motion. Again this is the analogue of the wave to beam transition in optics. It is suggested that this analysis of the quantum to classical transition should be incorporated routinely into introductory quantum mechanics courses.
Unbound wave packets propagating to macroscopic space and time coordinates become proportional to their (Fourier transform) momentum distribution at earlier times whereby the asymptotic coordinates and the initial momenta are connected everywhere by appropriate classical trajectories. This asymptotic imaging theorem is relevant to every quantum reaction involving macroscopic extraction and detection of fragments emerging from a microscopic volume. It justifies the usual assumption of classical particle motion used in the design of particle detectors. We illustrate this quantum to semiclassical transition with the example of the free propagation of a wave packet in one dimension, a standard problem treated in introductory lectures on quantum mechanics. We indicate generalizations appropriate for more advanced discussions.
The free propagation in time of a normalisable wave packet is the oldest problem of continuum quantum mechanics. Its motion from microscopic to macroscopic distance is the way in which most quantum systems are detected experimentally. Although much studied and analysed since 1927 and presented in many text books, here the problem is re-appraised from the standpoint of semi-classical mechanics. Particular aspects are the emergence of deterministic trajectories of particles emanating from a region of atomic dimensions and the interpretation of the wave function as describing a single particle or an ensemble of identical particles. Of possible wave packets, that of gaussian form is most studied due to the simple exact form of the time-dependent solution in real and in momentum space. Furthermore, this form is important in laser optics. Here the equivalence of the time-dependent Schroedinger equation to the paraxial equation for the propagation of light is demonstrated explicitly. This parallel helps to understand the relevance of trajectory concepts and the conditions necessary for the perception of motion as classical.
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Abstract The free propagation in time of a normalisable wave packet is the oldest problem of continuum quantum mechanics. Its motion from microscopic to macroscopic distance is the way in which most quantum systems are detected experimentally. Although much studied and analysed since 1927 and presented in many textbooks, here the problem is re‐appraised from the standpoint of semi‐classical mechanics. Particular aspects are the emergence of deterministic trajectories of particles emanating from a region of atomic dimension and the interpretation of the wave function as describing a single particle or an ensemble of identical particles. Of possible wave packets, that of Gaussian form is most studied due to the simple exact form of the time‐dependent solution in real and in momentum space. Furthermore, this form is important in laser optics. Here the equivalence of the time‐dependent Schrödinger equation to the paraxial equation for the propagation of light is demonstrated explicitly. This parallel helps to understand the relevance of trajectory concepts and the conditions necessary for the perception of quantum motion as classical. Key Points The paper addresses a problem of fundamental quantum mechanics, important in both physics and chemistry. Within physics, the subject is relevant to the disciplines of both quantum mechanics and classical optics. The matter presented is topical also for researchers in the history and philosophy of physics.
The evolution of the free-particle wave function in one dimension is the same as scalar Fresnel diffraction from a one-dimensional structure. Quantum mechanics courses often explore the propagation of Gaussian wave packets, but the diffractionlike mathematics is sufficiently tractable to investigate the propagation of other wave packets, both numerically and analytically. More importantly, the diffraction analogy facilitates the development of an intuitive understanding of the role that the initial phase plays in free-particle wave packet evolution. This article considers some of the effects of the initial phase function on the subsequent evolution of free-particle wave packets in the position representation. These considerations reinforce the idea that the classical mechanics limit embodied in the correspondence principle and formalized in the Ehrenfest theorem is necessarily an incomplete representation of quantum behavior.
The mechanism of the transition of a dynamical system from quantum to classical mechanics is of continuing interest. Practically it is of importance for the interpretation of multi-particle coincidence measurements performed at macroscopic distances from a microscopic reaction zone. Here we prove the generalized imaging theorem which shows that the spatial wave function of any multi-particle quantum system, propagating over distances and times large on an atomic scale but still microscopic, and subject to deterministic external fields and particle interactions, becomes proportional to the initial momentum wave function where the position and momentum coordinates define a classical trajectory . Currently, the quantum to classical transition is considered to occur via decoherence caused by stochastic interaction with an environment. The imaging theorem arises from unitary Schrödinger propagation and so is valid without any environmental interaction. It implies that a simultaneous measurement of both position and momentum will define a unique classical trajectory, whereas a less complete measurement of say position alone can lead to quantum interference effects.