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PARTICLE TRAJECTORIES AND THE PERCEPTION OF CLASSICAL MOTION IN THE FREE PROPAGATION OF WAVE PACKETS.

J S Briggs

Published Oct 25, 2021• 0 citations
Publisher

Abstract

The free propagation in time of a normalisable wave packet is the oldest problem of continuum quantum mechanics. Its motion from microscopic to macroscopic distance is the way in which most quantum systems are detected experimentally. Although much studied and analysed since 1927 and presented in many text books, here the problem is re-appraised from the standpoint of semi-classical mechanics. Particular aspects are the emergence of deterministic trajectories of particles emanating from a region of atomic dimensions and the interpretation of the wave function as describing a single particle or an ensemble of identical particles. Of possible wave packets, that of gaussian form is most studied due to the simple exact form of the time-dependent solution in real and in momentum space. Furthermore, this form is important in laser optics. Here the equivalence of the time-dependent Schroedinger equation to the paraxial equation for the propagation of light is demonstrated explicitly. This parallel helps to understand the relevance of trajectory concepts and the conditions necessary for the perception of motion as classical.

DOI
10.22541/au.163519359.99380185/v1

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The free propagation in time of a normalisable wave packet is the oldest problem of continuum quantum mechanics. Its motion from microscopic to macroscopic distance is the way in which most quantum systems are detected experimentally. Although much studied and analysed since 1927 and presented in many text books, here the problem is re-appraised from the standpoint of semi-classical mechanics. Particular aspects are the emergence of deterministic trajectories of particles emanating from a region of atomic dimensions and the interpretation of the wave function as describing a single particle or an ensemble of identical particles. Of possible wave packets, that of gaussian form is most studied due to the simple exact form of the time-dependent solution in real and in momentum space. Furthermore, this form is important in laser optics. Here the equivalence of the time-dependent Schroedinger equation to the paraxial equation for the propagation of light is demonstrated explicitly. This parallel helps to understand the relevance of trajectory concepts and the conditions necessary for the perception of motion as classical.
Abstract The free propagation in time of a normalisable wave packet is the oldest problem of continuum quantum mechanics. Its motion from microscopic to macroscopic distance is the way in which most quantum systems are detected experimentally. Although much studied and analysed since 1927 and presented in many textbooks, here the problem is re‐appraised from the standpoint of semi‐classical mechanics. Particular aspects are the emergence of deterministic trajectories of particles emanating from a region of atomic dimension and the interpretation of the wave function as describing a single particle or an ensemble of identical particles. Of possible wave packets, that of Gaussian form is most studied due to the simple exact form of the time‐dependent solution in real and in momentum space. Furthermore, this form is important in laser optics. Here the equivalence of the time‐dependent Schrödinger equation to the paraxial equation for the propagation of light is demonstrated explicitly. This parallel helps to understand the relevance of trajectory concepts and the conditions necessary for the perception of quantum motion as classical. Key Points The paper addresses a problem of fundamental quantum mechanics, important in both physics and chemistry. Within physics, the subject is relevant to the disciplines of both quantum mechanics and classical optics. The matter presented is topical also for researchers in the history and philosophy of physics.
Unbound wave packets propagating to macroscopic space and time coordinates become proportional to their (Fourier transform) momentum distribution at earlier times whereby the asymptotic coordinates and the initial momenta are connected everywhere by appropriate classical trajectories. This asymptotic imaging theorem is relevant to every quantum reaction involving macroscopic extraction and detection of fragments emerging from a microscopic volume. It justifies the usual assumption of classical particle motion used in the design of particle detectors. We illustrate this quantum to semiclassical transition with the example of the free propagation of a wave packet in one dimension, a standard problem treated in introductory lectures on quantum mechanics. We indicate generalizations appropriate for more advanced discussions.
Abstract The two‐dimensional paraxial equation of optics and the two‐dimensional time‐dependent Schrödinger equation, derived as approximations of the three‐dimensional Helmholtz equation and the three‐dimensional time‐independent Schrödinger equation, respectively, are identical. Here the free propagation in space and time of Hermite–Gauss wave packets (optics) or harmonic oscillator eigenfunctions (quantum mechanics) is examined in detail. The Gouy phase is shown to be a dynamic phase, appearing as the integral of the adiabatic eigenfrequency or eigenenergy. The wave packets propagate adiabatically in that at each space or time point they are solutions of the instantaneous harmonic problem. In both cases, it is shown that the form of the wave function is unchanged along the loci of the normals to wave fronts. This invariance along such trajectories is connected to the propagation of the invariant amplitude of the corresponding free wave number (optics) or momentum (quantum mechanics) wave packets. It is shown that the van Vleck classical density of trajectories function appears in the wave function amplitude over the complete trajectory. A transformation to the co‐moving frame along a trajectory gives a constant wave function multiplied by a simple energy or frequency phase factor. The Gouy phase becomes the proper time in this frame. Key Points This paper builds a bridge between quantum mechanics (QM) and classical optics in that the identity of the paraxial equation of optics and the Schrödinger equation of QM is shown, the Bohmian trajectories of QM are defined in optics, the Gouy phase of optics is defined in QM and given a new interpretation and The space and momentum wave functions are equivalent along a trajectory.
Abstract The standard description of the transition from quantum to classical mechanics presented in most text books is the proof that the quantum expectation values of position and momentum obey equations of Newtonian form. This is the Ehrenfest theorem. It is combined with the requirement that wave packets remain localised to describe a single particle moving according to classical mechanics. Hence, the natural spreading of wave packets is viewed as a quantum effect. In contradiction to this view, here it is argued that the spreading, where different momentum components separate, is the signature of the quantum to classical transition. The asymptotic spatial wave function becomes proportional to the initial momentum space wave function, which mirrors exactly the well-known far-field diffraction pattern in optics. Trajectories, defined as the locus of the normals to the expanding wave front, are used to illustrate the transition from quantum to classical motion. Again this is the analogue of the wave to beam transition in optics. It is suggested that this analysis of the quantum to classical transition should be incorporated routinely into introductory quantum mechanics courses.
A consistent description of the motion of a particle by wave propagation implies not only a geometrical equivalence between a trajectory and a ray but also a kinematical equivalence between the time rates at which the particle or wave is traversing its path. This may be tentatively achieved by using a wave configuration, known as a wave packet, represented as a continuous superposition of monochromatic waves. If the wave packet can be regarded as a point, having zero amplitude everywhere except in a very small region, its motion along a trajectory might be interpreted as the motion of a single particle. The representation of a particle in space and time by means of a highly localized wave packet is a basic assumption of wave mechanics. The behavior of the wave packet as a whole will account for experiments where particle-like properties are observed, whereas individual wavelength components of packet will appear in experiments which depend upon interference and diffraction effects.
The behaviour of localized quantum wave packet has lately become an object of much interest to forge a link between classical and quantum mechanics. Wave packet is often taken as the best approximation of quantum theory to a classical particle. If the wave packet is regarded as a point, with zero amplitude everywhere except in a very small region, then its motion can be interpreted as the motion of a single particle. The advent of short-pulsed lasers made it possible to produce and detect superposition of electron states for many physical systems. Such superposition leads to the formation of localized electron wave packets. The localized wave packet solution disperses or spreads in time, however, at a later time, it reforms and appears as its initial state. Revivals in quantum systems were first studied in the Jaynes–Cumming model, describing a two-level atom interacting with a resonant monochromatic field.