A case study of the non-equilibrium dynamics of open quantum systems in the markovian approximation is presented for two dynamical models based on a single harmonic oscillator in an external field. Specified through distinct forms of ohmic damping, their quantum Langevin equations are derived from an identical set of physical criteria, namely the canonical commutator between position and momentum, the Kubo formula, the virial theorem and the quantum equilibrium variance. The associated Lindblad equations are derived but only one of them is completely positive. Transforming those into Fokker-Planck equations for the Wigner functions, both models are shown to evolve towards the same Gibbs state, for a vanishing external field. The phenomenological differences between the models are illustrated through their quantum relaxations and through the phase diagrammes derived from their re-interpretation as mean-field approximations of an interacting many-body system.
A case study of the non-equilibrium dynamics of open quantum systems in the markovian approximation is presented for two dynamical models based on a single harmonic oscillator in an external field. Specified through distinct forms of ohmic damping, their quantum Langevin equations are derived from an identical set of physical criteria, namely the canonical commutator between position and momentum, the Kubo formula, the virial theorem and the quantum equilibrium variance. The associated Lindblad equations are derived but only one of them is completely positive. Transforming those into Fokker-Planck equations for the Wigner functions, both models are shown to evolve towards the same Gibbs state, for a vanishing external field. The phenomenological differences between the models are illustrated through their quantum relaxations and through the phase diagrammes derived from their re-interpretation as mean-field approximations of an interacting many-body system.
The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non-Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non-Markovian frameworks for a consistent description of open quantum dynamics.
Abstract The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non -Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non -Markovian frameworks for a consistent description of open quantum dynamics.
Abstract A phenomenological construction of quantum Langevin equations, based on the physical criteria of (i) the canonical equal-time commutators, (ii) the Kubo formula, (iii) the virial theorem and (iv) the quantum fluctuation–dissipation theorem is presented. The case of a single harmonic oscillator coupled to a large external bath is analysed in detail. This allows to distinguish a Markovian semi-classical approach, due to Bedeaux and Mazur, from a non-Markovian full quantum approach, due to to Ford, Kac and Mazur. The quantum-fluctuation–dissipation theorem is seen to be incompatible with a Markovian dynamics. Possible applications to the quantum spherical model are discussed.
This article has to do with the derivation and solution of the Fokker-Planck equation associated to the momentum-integrated Wigner function of a particle subjected to a harmonic external field in contact with an ohmic thermal bath of quantum harmonic oscillators. The strategy employed is a simplified version of the phenomenological approach of Schramm, Jung, and Grabert of interpreting the operators as c numbers to derive the quantum master equation arising from a twofold transformation of the Wigner function of the entire phase space. The statistical properties of the random noise comes from the integral functional theory of Grabert, Schramm, and Ingold. By means of a single Wigner transformation, a simpler equation than that mentioned before is found. The Wigner function reproduces the known results of the classical limit. This allowed us to rewrite the underdamped classical Langevin equation as a first-order stochastic differential equation with time-dependent drift and diffusion terms.
In the framework of the Lindblad theory for open quantum systems the damping of the harmonic oscillator is studied. A generalization of the fundamental constraints on quantum mechanical diffusion coefficients which appear in the master equation for the damped quantum oscillator is presented; the Schrödinger and Heisenberg representations of the Lindblad equation are given explicitly. On the basis of these representations it is shown that various master equations for the damped quantum oscillator used in the literature are particular cases of the Lindblad equation and that the majority of these equations are not satisfying the constraints on quantum mechanical diffusion coefficients. Analytical expressions for the first two moments of coordinate and momentum are also obtained by using the characteristic function of the Lindblad master equation. The master equation is transformed into Fokker-Planck equations for quasiprobability distributions. A comparative study is made for the Glauber P representation, the antinormal ordering Q representation and the Wigner W representation. It is proven that the variances for the damped harmonic oscillator found with these representations are the same. By solving the Fokker-Planck equations in the steady state, it is shown that the quasiprobability distributions are two-dimensional Gaussians with widths determined by the diffusion coefficients. The density matrix is represented via a generating function, which is obtained by solving a time-dependent linear partial differential equation derived from the master equation. Illustrative examples for specific initial conditions of the density matrix are provided.
Open quantum systems play a central role in contemporary nanoscale technologies, including molecular electronics, quantum heat engines, quantum computation and information processing. A major theoretical challenge is to construct dynamical models that are simultaneously consistent with classical thermodynamics and complete positivity. In this work, we develop a framework that addresses this issue by extending classical stochastic dynamics to the quantum domain. We begin by formulating a generalized Langevin equation in which both friction and noise act symmetrically on the two Hamiltonian equations. From this, we derive a generalized Klein-Kramers equation expressed in terms of Poisson brackets, and we show that it admits the Boltzmann distribution as its stationary solution while satisfying the first and second laws of thermodynamics along individual trajectories. Applying canonical quantization to this classical framework yields two distinct quantum master equations, depending on whether the friction operators are taken to be Hermitian or non-Hermitian. By analyzing the dynamics of a harmonic oscillator, we determine the conditions under which these equations reduce to a Lindblad-type generator. Our results demonstrate that complete positivity is ensured only when friction and noise are included in both Hamiltonian equations, thus fully justifying the classical construction. Moreover, we find that the friction coefficients must satisfy the same positivity condition in both the Hermitian and non-Hermitian formulations, revealing a form of universality that transcends the specific operator representation. The formalism offers a versatile tool for deriving quantum versions of the thermodynamic laws and is directly applicable to a wide class of nonequilibrium nanoscale systems.