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arXiv:2305.06312

Limitations of the Markovian approximation in the harmonic oscillator

Michele Coppola, Zoubair Daouma, Malte Henkel

Published May 10, 2023• 0 citations
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Abstract

The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non-Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non-Markovian frameworks for a consistent description of open quantum dynamics.

DOI
10.48550/arxiv.2305.06312

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The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non-Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non-Markovian frameworks for a consistent description of open quantum dynamics.
Abstract The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non -Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non -Markovian frameworks for a consistent description of open quantum dynamics.
A case study of the non-equilibrium dynamics of open quantum systems in the markovian approximation is presented for two dynamical models based on a single harmonic oscillator in an external field. Specified through distinct forms of ohmic damping, their quantum Langevin equations are derived from an identical set of physical criteria, namely the canonical commutator between position and momentum, the Kubo formula, the virial theorem and the quantum equilibrium variance. The associated Lindblad equations are derived but only one of them is completely positive. Transforming those into Fokker-Planck equations for the Wigner functions, both models are shown to evolve towards the same Gibbs state, for a vanishing external field. The phenomenological differences between the models are illustrated through their quantum relaxations and through the phase diagrammes derived from their re-interpretation as mean-field approximations of an interacting many-body system.
Abstract A phenomenological construction of quantum Langevin equations, based on the physical criteria of (i) the canonical equal-time commutators, (ii) the Kubo formula, (iii) the virial theorem and (iv) the quantum fluctuation–dissipation theorem is presented. The case of a single harmonic oscillator coupled to a large external bath is analysed in detail. This allows to distinguish a Markovian semi-classical approach, due to Bedeaux and Mazur, from a non-Markovian full quantum approach, due to to Ford, Kac and Mazur. The quantum-fluctuation–dissipation theorem is seen to be incompatible with a Markovian dynamics. Possible applications to the quantum spherical model are discussed.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
We consider a model of non-Markovian quantum Brownian motion that consists of a harmonic oscillator bilinearly coupled to a thermal bath, both via its position and via its momentum operators. We derive the master equation for such a model, and we solve the equations of motion for a generic Gaussian system state. We then investigate the resulting evolution of the first and second moments for both an Ohmic and a super-Ohmic spectral density. In particular, we show that, irrespective of the specific form of the spectral density, the coupling with the momentum enhances the dissipation experienced by the system, accelerating its relaxation to the equilibrium as well as modifying the asymptotic state of the dynamics. Eventually, we characterize explicitly the non-Markovianity of the evolution using a general criterion which relies on the positivity of the master equation coefficients.
We study quantum non-Markovian dynamics of the Caldeira-Leggett model, a prototypical model for quantum Brownian motion describing a harmonic oscillator linearly coupled to a reservoir of harmonic oscillators. Employing the exact analytical solution of this model one can determine the size of memory effects for arbitrary couplings, temperatures, and frequency cutoffs. Here, quantum non-Markovianity is defined in terms of the flow of information between the open system and its environment, which is quantified through the Bures metric as distance measure for quantum states. This approach allows us to discuss quantum memory effects in the whole range from weak to strong dissipation for arbitrary Gaussian initial states. A comparison of our results with the corresponding results for the spin-boson problem show a remarkable similarity in the structure of non-Markovian behavior of the two paradigmatic models.