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arXiv:1809.08975 · Journal of Statistical Mechanics Theory and Experiment

Axiomatic construction of quantum Langevin equations

Rúbia Araújo, Sascha Wald, Malte Henkel

Published May 1, 2019• 13 citations
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Abstract

Abstract A phenomenological construction of quantum Langevin equations, based on the physical criteria of (i) the canonical equal-time commutators, (ii) the Kubo formula, (iii) the virial theorem and (iv) the quantum fluctuation–dissipation theorem is presented. The case of a single harmonic oscillator coupled to a large external bath is analysed in detail. This allows to distinguish a Markovian semi-classical approach, due to Bedeaux and Mazur, from a non-Markovian full quantum approach, due to to Ford, Kac and Mazur. The quantum-fluctuation–dissipation theorem is seen to be incompatible with a Markovian dynamics. Possible applications to the quantum spherical model are discussed.

DOI
10.1088/1742-5468/ab11dc

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Abstract A phenomenological construction of quantum Langevin equations, based on the physical criteria of (i) the canonical equal-time commutators, (ii) the Kubo formula, (iii) the virial theorem and (iv) the quantum fluctuation–dissipation theorem is presented. The case of a single harmonic oscillator coupled to a large external bath is analysed in detail. This allows to distinguish a Markovian semi-classical approach, due to Bedeaux and Mazur, from a non-Markovian full quantum approach, due to to Ford, Kac and Mazur. The quantum-fluctuation–dissipation theorem is seen to be incompatible with a Markovian dynamics. Possible applications to the quantum spherical model are discussed.
The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non-Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non-Markovian frameworks for a consistent description of open quantum dynamics.
Abstract The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non -Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non -Markovian frameworks for a consistent description of open quantum dynamics.
A case study of the non-equilibrium dynamics of open quantum systems in the markovian approximation is presented for two dynamical models based on a single harmonic oscillator in an external field. Specified through distinct forms of ohmic damping, their quantum Langevin equations are derived from an identical set of physical criteria, namely the canonical commutator between position and momentum, the Kubo formula, the virial theorem and the quantum equilibrium variance. The associated Lindblad equations are derived but only one of them is completely positive. Transforming those into Fokker-Planck equations for the Wigner functions, both models are shown to evolve towards the same Gibbs state, for a vanishing external field. The phenomenological differences between the models are illustrated through their quantum relaxations and through the phase diagrammes derived from their re-interpretation as mean-field approximations of an interacting many-body system.
Abstract This review provides a brief and quick introduction to the quantum Langevin equation for an oscillator, while focusing on the steady-state thermodynamic aspects. A derivation of the quantum Langevin equation is carefully outlined based on the microscopic model of the heat bath as a collection of a large number of independent quantum oscillators, the so-called independent-oscillator model. This is followed by a discussion on the relevant ‘weak-coupling’ limit. In the steady state, we analyze the quantum counterpart of energy equipartition theorem which has generated a considerable amount of interest in recent literature. The free energy, entropy, specific heat, and third law of thermodynamics are discussed for one-dimensional quantum Brownian motion in a harmonic well. Following this, we explore some aspects of dissipative diamagnetism in the context of quantum Brownian oscillators, emphasizing upon the role of confining potentials and also upon the environment-induced classical-quantum crossover. We discuss situations where the system-bath coupling is via the momentum variables by focusing on a gauge-invariant model of momentum-momentum coupling in the presence of a vector potential; for this problem, we derive the quantum Langevin equation and discuss quantum thermodynamic functions. Finally, the topic of fluctuation theorems is discussed (albeit, briefly) in the context of classical and quantum cyclotron motion of a particle coupled to a heat bath.
Abstract We propose a Langevin equation to describe the quantum Brownian motion of bounded particles based on a distinctive formulation concerning both the fluctuation and dissipation forces. The fluctuation force is similar to that employed in the classical case. It is a white noise with a variance proportional to the temperature. The dissipation force is not restricted to be proportional to the velocity and is determined in a way as to guarantee that the stationary state is given by a density operator of the Gibbs canonical type. To this end we derived an equation that gives the time evolution of the density operator, which turns out to be a quantum Fokker–Planck–Kramers equation. The approach is applied to the harmonic oscillator in which case the dissipation force is found to be non Hermitian and proportional to the velocity and position.
The system of nonlinear Langevin equations was obtained by using Hamiltonian's operator of two coupling quantum oscillators which are interacting with heat bath. By using the analytical solution of these equations, the analytical expressions for transport coefficients was found. Generalized Langevin equations and fluctuation-dissipation relations are derived for the case of a nonlinear non-Markovian noise. The explicit expressions for the time-dependent friction and diffusion coefficients are presented for the case of linear couplings in the coordinate between the collective two coupled harmonic oscillators and heat bath.