We analyze here through exact calculations the thermodynamical effects in depolarizing a quantum spin-bath initially at zero temperature through a quantum probe coupled to an infinite temperature bath by evaluating the heat and entropy changes. We show that the correlations induced in the bath during the depolarizing process does not allow for the entropy of the bath to increase towards its maximal limit. On the contrary, the energy deposited in the bath can be completely extracted in a finite time. We explore these findings through an exactly solvable central spin model, wherein a central spin-1/2 system is homogeneously coupled to a bath of identical spins. Further, we show that, upon destroying these unwanted correlations, we boost the rate of both energy extraction and entropy towards their limiting values. We envisage that these studies are relevant for quantum battery research wherein both charging and discharging processes are key to characterizing the battery performance.
We analyze here through exact calculations the thermodynamical effects in depolarizing a quantum spin-bath initially at zero temperature through a quantum probe coupled to an infinite temperature bath by evaluating the heat and entropy changes. We show that the correlations induced in the bath during the depolarizing process does not allow for the entropy of the bath to increase towards its maximal limit. On the contrary, the energy deposited in the bath can be completely extracted in a finite time. We explore these findings through an exactly solvable central spin model, wherein a central spin-1/2 system is homogeneously coupled to a bath of identical spins. Further, we show that, upon destroying these unwanted correlations, we boost the rate of both energy extraction and entropy towards their limiting values. We envisage that these studies are relevant for quantum battery research wherein both charging and discharging processes are key to characterizing the battery performance.
The focus is on understanding the quantum thermodynamics of strongly coupled non-Markovian quantum systems. To this end, a non-trivial, non-Markovian model of a central spin surrounded by a spin bath is taken up, and its exact evolution is derived for arbitrary system-bath couplings. The fundamental quantum thermodynamic quantities, such as system and bath internal energies, work, heat, entropy production, and ergotropy, are calculated using the dynamics and the original system (bath) Hamiltonian. An explicit expression for the work, a mismatch between the system and bath internal energies, is derived. The thermodynamic entropy of the system at thermal equilibrium is studied using the Hamiltonian of mean force in the strong coupling regime. The role of a canonical Hamiltonian in calculating the above thermodynamic quantities, a recently developed technique, is also investigated. Furthermore, an interesting observation relevant to the spin bath acting as a charger is made in a scenario where the central spin is envisaged as a quantum battery.
In this work, we introduce a method for deriving exact master equations from the dynamical map for finite open quantum systems coupled to (in)finite reservoirs, using the principle of minimal dissipation. The exact dynamics of the central spin model, which models a finite-bath open quantum system, is developed for two interaction types: Heisenberg and stochastic pure-dephasing interactions. The Heisenberg interaction yields a novel phase-covariant quantum channel in the strong-coupling regime, offering a new platform for studying a range of quantum information protocols. The stochastic pure-dephasing interaction provides the microscopic derivation of the paradigmatic non-Markovian random telegraph noise (RTN) channel, establishing its quantum foundation and offering insight into stochastic couplings. We derive the closed-form master equations for both models. As a demonstration, we explore the thermodynamic performance of these systems as quantum batteries. A direct relationship between quantum heat current and charging power is revealed, and RTN quantum batteries are shown to have advantages in charge storage.
An exact reduced dynamical map along with its operator sum representation is derived for a central spin interacting with a thermal spin environment. The dynamics of the central spin shows high sustainability of quantum traits such as coherence and entanglement in the low-temperature regime. However, for sufficiently high temperature and when the number of bath particles approaches the thermodynamic limit, this feature vanishes and the dynamics closely mimics Markovian evolution. The properties of the long-time-averaged state and the trapped information of the initial state for the central qubit are also investigated in detail, confirming that the nonergodicity of the dynamics can be attributed to the finite temperature and finite size of the bath. It is shown that if a certain stringent resonance condition is satisfied, the long-time-averaged state retains quantum coherence, which can have far reaching technological implications in engineering quantum devices. An exact time-local master equation of the canonical form is derived. With the help of this master equation, the nonequilibrium properties of the central spin system are studied by investigating the detailed balance condition and irreversible entropy production rate. The result reveals that the central qubit thermalizes only in the limit of very high temperature and large number of bath spins.
We study the energy-transfer process in quantum battery systems consisting of multiple central spins and bath spins. Here with ``quantum battery'' we refer to the central spins, whereas the bath serves as the ``charger.'' For the single-central-spin battery, we analytically derive the time evolutions of the energy transfer and the charging power with arbitrary number of bath spins. For the case of multiple central spins in the battery, we find the scaling-law relation between the maximum power Pmax and the number of central spins NB. It approximately satisfies a scaling law relation ${P}_{\mathrm{max}}\ensuremath{\propto}{N}_{B}^{\ensuremath{\alpha}}$, where scaling exponent $\ensuremath{\alpha}$ varies with the bath spin number N from the lower bound $\ensuremath{\alpha}=1/2$ to the upper bound $\ensuremath{\alpha}=3/2$. The lower and upper bounds correspond to the limits $N\ensuremath{\rightarrow}1$ and $N\ensuremath{\gg}{N}_{B}$, respectively. In thermodynamic limit, by applying the Holstein-Primakoff transformation, we rigorously prove that the upper bound is Pmax=0.72BANNB3/2, which shows the same advantage in scaling of a recent charging protocol based on the Tavis-Cummings model. Here B and A are the external magnetic field and coupling constant between the battery and the charger.
We consider a central-spin battery where Nb central spins serve as battery cells and Nc bath spins serve as charging units. It is shown that the energy stored in the battery that can be extractable is quantified by the ergotropy, and that battery-charger entanglement is quantified via the Von Neumann entropy. By using an exact approach to a one-cell and two-cell battery, our analytical results suggest that, during the charging process, the extractable work slowly increases before the battery-charger entanglement reaches its maximum and then it will rapidly increase when the entanglement begins to decrease. In particular, we rigorously show that there is an inverse relationship between the extractable work and the entanglement at the end of the charging process. Moreover, we investigate different approaches to realize optimal work extraction without wasted energy. Among them a central-spin battery with an unpolarized Dicke state as the charger possesses a universal charging time $\ensuremath{\propto}1/{N}_{c}$, large extractable work and Nc-improvement of charging power compared with the battery in the Tavis-Cummings limit. The above-mentioned results have also been numerically verified in multicell batteries. Our results pave the way to improve extractable work storage in the central-spin battery and highlight a competitive relation between the extractable work and the battery-charger entanglement.
Recently, there has been an upsurge of interest in quantum thermodynamic devices, notably quantum batteries. Quantum batteries serve as energy storage devices governed by the rules of quantum thermodynamics. Here, we propose a model of a quantum battery wherein the system of interest can be envisaged as a battery, and the ambient environment acts as a charger (dissipation) mechanism, modeled along the ubiquitous quantum Brownian motion. We employ quantifiers such as ergotropy and its (in)coherent manifestations, as well as instantaneous and average powers, to characterize the performance of the quantum battery. We investigate the influence of the bath's temperature and the system's coupling with the environment via momentum and position coordinates on the discharging and recharging dynamics. Moreover, we probe the memory effects of the system's dynamics and obtain a relationship between the system's non-Markovian evolution and the battery's recharging process.