In this work, we introduce a method for deriving exact master equations from the dynamical map for finite open quantum systems coupled to (in)finite reservoirs, using the principle of minimal dissipation. The exact dynamics of the central spin model, which models a finite-bath open quantum system, is developed for two interaction types: Heisenberg and stochastic pure-dephasing interactions. The Heisenberg interaction yields a novel phase-covariant quantum channel in the strong-coupling regime, offering a new platform for studying a range of quantum information protocols. The stochastic pure-dephasing interaction provides the microscopic derivation of the paradigmatic non-Markovian random telegraph noise (RTN) channel, establishing its quantum foundation and offering insight into stochastic couplings. We derive the closed-form master equations for both models. As a demonstration, we explore the thermodynamic performance of these systems as quantum batteries. A direct relationship between quantum heat current and charging power is revealed, and RTN quantum batteries are shown to have advantages in charge storage.
In this work, we introduce a method for deriving exact master equations from the dynamical map for finite open quantum systems coupled to (in)finite reservoirs, using the principle of minimal dissipation. The exact dynamics of the central spin model, which models a finite-bath open quantum system, is developed for two interaction types: Heisenberg and stochastic pure-dephasing interactions. The Heisenberg interaction yields a novel phase-covariant quantum channel in the strong-coupling regime, offering a new platform for studying a range of quantum information protocols. The stochastic pure-dephasing interaction provides the microscopic derivation of the paradigmatic non-Markovian random telegraph noise (RTN) channel, establishing its quantum foundation and offering insight into stochastic couplings. We derive the closed-form master equations for both models. As a demonstration, we explore the thermodynamic performance of these systems as quantum batteries. A direct relationship between quantum heat current and charging power is revealed, and RTN quantum batteries are shown to have advantages in charge storage.
The focus is on understanding the quantum thermodynamics of strongly coupled non-Markovian quantum systems. To this end, a non-trivial, non-Markovian model of a central spin surrounded by a spin bath is taken up, and its exact evolution is derived for arbitrary system-bath couplings. The fundamental quantum thermodynamic quantities, such as system and bath internal energies, work, heat, entropy production, and ergotropy, are calculated using the dynamics and the original system (bath) Hamiltonian. An explicit expression for the work, a mismatch between the system and bath internal energies, is derived. The thermodynamic entropy of the system at thermal equilibrium is studied using the Hamiltonian of mean force in the strong coupling regime. The role of a canonical Hamiltonian in calculating the above thermodynamic quantities, a recently developed technique, is also investigated. Furthermore, an interesting observation relevant to the spin bath acting as a charger is made in a scenario where the central spin is envisaged as a quantum battery.
The spin-boson model, describing a two-level system coupled to a bosonic bath, is extensively studied as a paradigmatic dissipative quantum system, exhibiting rich dynamical behavior and even a localization transition in the strong coupling regime. Here, we additionally consider dephasing as a source of Markovian dissipation on top of the non-Markovian dynamics due to an Ohmic bath, and investigate the dynamics of the spin. We show that the characteristic frequency of the spin dynamics, while strongly renormalized by the bosonic bath, changes in a simple fashion (or does not change at all) with dephasing. To obtain these results, we develop an exact nonperturbative method known as the stochastic Schr\"odinger equation, mimicking the Ohmic bath via a stochastic magnetic field combined with the Lindblad quantum master equation due to dephasing, which allows us to numerically compute the dynamics. Furthermore, we derive weak-coupling analytic results utilizing the well-known noninteracting blip approximation. Our findings are relevant to quantum simulation of the spin-boson model in the regime of strong coupling in trapped ions and circuit QED architectures among others.
We introduce a systematic framework to derive the effective Hamiltonian governing the coherent dynamics of non-Markovian open quantum systems. By applying the minimal dissipation principle, we uniquely isolate the coherent contribution to the time-local generator of the reduced dynamics. We derive a general expression for the effective Hamiltonian and develop a recursive perturbative expansion that expresses it in terms of system-bath interaction terms and bath correlation functions. This expansion provides a systematic tool for analyzing energy renormalization effects across different coupling regimes. Applying our framework to paradigmatic spin systems, we reveal how environmental correlations influence energy shifts and eigenbasis rotations, offering insights into strong-coupling effects and non-Markovian quantum thermodynamics.
Understanding the dynamics of dissipative quantum systems, particularly beyond the weak coupling approximation, is central to various quantum applications. While numerically exact methods provide accurate solutions, they often lack the analytical insight provided by theoretical approaches. In this study, we employ the recently developed method dubbed the effective Hamiltonian theory to understand the dynamics of system-bath configurations without resorting to a perturbative description of the system-bath coupling energy. Through a combination of mapping steps and truncation, the effective Hamiltonian theory offers both analytical insights into signatures of strong couplings in open quantum systems and a straightforward path for numerical simulations. To validate the accuracy of the method, we apply it to two canonical models: a single spin immersed in a bosonic bath and two noninteracting spins in a common bath. In both cases, we study the transient regime and the steady state limit at nonzero temperature and spanning system-bath interactions from the weak to the strong regime. By comparing the results of the effective Hamiltonian theory with numerically exact simulations, we show that although the former overlooks non-Markovian features in the transient equilibration dynamics, it correctly captures non-perturbative bath-generated couplings between otherwise non-interacting spins, as observed in their synchronization dynamics and correlations. Altogether, the effective Hamiltonian theory offers a powerful approach for understanding strong coupling dynamics and thermodynamics, capturing the signatures of such interactions in both relaxation dynamics and in the steady state limit.
Abstract Coupling with an external environment inevitably affects the dynamics of a quantum system. Here, we consider how charging performances of a quantum battery, modelled as a two level system, are influenced by the presence of an Ohmic thermal reservoir. The latter is coupled to both longitudinal and transverse spin components of the quantum battery including decoherence and pure dephasing mechanisms. Charging and discharging dynamics of the quantum battery, subjected to a static driving, are obtained exploiting a proper mapping into the so-called spin-boson model. Analytic expressions for the time evolution of the energy stored in the weak coupling regime are presented relying on a systematic weak damping expansion. Here, decoherence and pure dephasing dissipative coupling are discussed in details. We argue that the former results in better charging performances, showing also interesting features reminiscent of the Lamb shift level splitting renormalization induced by the presence of the reservoir. Charging stability is also addressed, by monitoring the energy behaviour after the charging protocol has been switched off. This study presents a general framework to investigate relaxation effects, able to include also non Markovian effects, and it reveals the importance of controlling and, possibly, engineering system-bath coupling in the realization of quantum batteries.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.