We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation — Carnot refrigeration cycle, employing a spin-1/2 system as the working substance. The thermal machine is alternatively driven by a hot boson bath of inverse temperature β h and a cold boson bath at inverse temperature β c (>β h). While for the engine model the hot bath is constructed to be squeezed, in the refrigeration cycle the cold bath is established to be squeezed, with squeezing parameter r. We obtain the analytical expressions for both efficiency and power in heat engines and for coefficient of performance and cooling rate in refrigerators. We find that, in the high-temperature limit, the efficiency at maximum power is bounded by the analytical value η + = 1 − sech ( 2 r ) ( 1 − η C ) , and the coefficient of performance at the maximum figure of merit is limited by ε + = sech ( 2 r ) ( 1 + ε C ) sech ( 2 r ) ( 1 + ε C ) − ε C − 1 , where η C = 1 – β h/β c and ε C = β h/(β c – β h) are the respective Carnot values of the engines and refrigerators. These analytical results are identical to those obtained from the Carnot engines based on harmonic systems, indicating that the efficiency at maximum power and coefficient at maximum figure of merit are independent of the working substance.
We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation — Carnot refrigeration cycle, employing a spin-1/2 system as the working substance. The thermal machine is alternatively driven by a hot boson bath of inverse temperature β h and a cold boson bath at inverse temperature β c (>β h). While for the engine model the hot bath is constructed to be squeezed, in the refrigeration cycle the cold bath is established to be squeezed, with squeezing parameter r. We obtain the analytical expressions for both efficiency and power in heat engines and for coefficient of performance and cooling rate in refrigerators. We find that, in the high-temperature limit, the efficiency at maximum power is bounded by the analytical value η + = 1 − sech ( 2 r ) ( 1 − η C ) , and the coefficient of performance at the maximum figure of merit is limited by ε + = sech ( 2 r ) ( 1 + ε C ) sech ( 2 r ) ( 1 + ε C ) − ε C − 1 , where η C = 1 – β h/β c and ε C = β h/(β c – β h) are the respective Carnot values of the engines and refrigerators. These analytical results are identical to those obtained from the Carnot engines based on harmonic systems, indicating that the efficiency at maximum power and coefficient at maximum figure of merit are independent of the working substance.
We consider a quantum endoreversible Carnot engine cycle and its inverse operation–Carnot refrigeration cycle, working between a hot bath of inverse temperature βh and a cold bath at inverse temperature βc. For the engine model, the hot bath is constructed to be squeezed, whereas for the refrigeration cycle, the cold bath is set to be squeezed. In the high-temperature limit, we analyze efficiency at maximum power and coefficient of performance at maximum figure of merit, revealing the effects of the times allocated to two thermal-contact and two adiabatic processes on the machine performance. We show that, when the total time spent along the two adiabatic processes is negligible, the efficiency at maximum power reaches its upper bound, which can be analytically expressed in terms of squeezing parameter r: ηana∗=1−sech[2r]1−ηC, with the Carnot efficiency ηC=1−βh/βc and the coefficient of performance at maximum figure of merit is bounded from the upper side by the analytical function: εana∗=1+εCsech[2r](1+εC)−εC−1, where εC=βh/(βc−βh).
Abstract We consider a quantum endoreversible Otto engine cycle and its inverse operation-Otto refrigeration cycle, employing two-level systems as the working substance and operating in dual-squeezed reservoirs. We demonstrate that the efficiency of heat engines at maximum work output and the coefficient of performance for refrigerators at the maximum χ criterion will degenerate to η − = η C/(2 – η C) and ε − = ( 9 + 8 ε C − 3 ) / 2 when symmetric squeezing is satisfied, respectively. We also investigated the influences of squeezing degree on the performance optimization of quantum Otto heat engines at the maximum work output and refrigerators at the maximum χ criterion. These analytical results show that the efficiency of heat engines at maximum work output and the coefficient of performance for refrigerators at the maximum χ criterion can be improved, reduced or even inhibited in asymmetric squeezing. Furthermore, we also find that the efficiency of quantum Otto heat engines at maximum work output is lower than that obtained from the Otto heat engines based on a single harmonic oscillator system. However, the coefficient of performance of the corresponding refrigerator is higher.
We consider the finite-time performance of a quantum Otto engine working between a hot squeezed and a cold thermal bath at inverse temperatures ${\ensuremath{\beta}}_{h}$ and ${\ensuremath{\beta}}_{c}(>{\ensuremath{\beta}}_{h})$ with $({k}_{B}\ensuremath{\equiv}1)\ensuremath{\beta}=1/T$. We derive the analytical expressions for work, efficiency, power, and power fluctuations, in which the squeezing parameter is involved. By optimizing the power output with respect to two frequencies, we derive the efficiency at maximum power as ${\ensuremath{\eta}}_{mp}={({\ensuremath{\eta}}_{C}^{\mathrm{gen}})}^{2}/[{\ensuremath{\eta}}_{C}^{\mathrm{gen}}\ensuremath{-}(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})ln(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})]$, where the generalized Carnot efficiency ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}$ in the high-temperature or small squeezing limit simplifies to an analytic function of squeezing parameter $\ensuremath{\gamma}$: ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}=1\ensuremath{-}{\ensuremath{\beta}}_{h}/[{\ensuremath{\beta}}_{c}cosh(2\ensuremath{\gamma})]$. Within the context of irreversible thermodynamics, we demonstrate that the expression of efficiency at maximum power satisfies a general form derived from nonlinear steady state heat engines. We show that, the power fluctuations are considerably increased, although the engine efficiency is enhanced by squeezing.
The derivation of general performance benchmarks is important in the design of highly optimized heat engines and refrigerators. To obtain them, one may model phenomenologically the leading sources of irreversibility ending up with results that are model independent, but limited in scope. Alternatively, one can take a simple physical system realizing a thermodynamic cycle and assess its optimal operation from a complete microscopic description. We follow this approach in order to derive the coefficient of performance at maximum cooling rate for any endoreversible quantum refrigerator. At striking variance with the universality of the optimal efficiency of heat engines, we find that the cooling performance at maximum power is crucially determined by the details of the specific system-bath interaction mechanism. A closed analytical benchmark is found for endoreversible refrigerators weakly coupled to unstructured bosonic heat baths: an ubiquitous case study in quantum thermodynamics.
We analyze the performance of a quantum Otto cycle, employing a time-dependent harmonic oscillator as the working fluid undergoing sudden expansion and compression strokes during the adiabatic stages, coupled to a squeezed reservoir. First, we show that the maximum efficiency that our engine can achieve is 1/2 only, which is in contrast with earlier studies claiming unit efficiency under the effect of a squeezed reservoir. Then, in the high-temperature limit, we obtain analytic expressions for the upper bound on the efficiency as well as on the coefficient of performance of the Otto cycle. The obtained bounds are independent of the parameters of the system and depend on the reservoir parameters only. Additionally, with a hot squeezed thermal bath, we obtain an analytic expression for the efficiency at maximum work which satisfies the derived upper bound. Further, in the presence of squeezing in the cold reservoir, we specify an operational regime for the Otto refrigerator otherwise forbidden in the standard case. Finally, we find the cost of creating a squeezed state from the thermal state and show that in order to harvest the benefits of squeezing, it is sufficient to squeeze only one mode of the reservoir in resonance with the transition frequency of the working fluid. Further, we show that when the cost of squeezing is included in the definition of the operational efficiency of the engine, the advantages of squeezing fade away. Still, being purely quantum mechanical fuel in nature, squeezed reservoirs are beneficial in their own way by providing us with more compact energy storage medium or offering effectively high-temperature baths without being actually too hot.
A new model of a quantum refrigeration cycle composed of two adiabatic and two isomagnetic field processes is established. The working substance in the cycle consists of many non-interacting spin-1/2 systems. The performance of the cycle is investigated, based on the quantum master equation and semi-group approach. The general expressions of several important performance parameters, such as the coefficient of performance, cooling rate and power input, are given. It is found that the coefficient of performance of this cycle is in the closest analogy to that of the classical Carnot cycle. Furthermore, at high temperatures the optimal relations of the cooling rate and the maximum cooling rate are analysed in detail. Some performance characteristic curves of the cycle are plotted, such as the cooling rate versus the maximum ratio between high and low ``temperatures'' of the working substances, the maximum cooling rate versus the ratio between high and low ``magnetic fields'' and the ``temperature'' ratio between high and low reservoirs. The obtained results are further generalized and discussed, so that they may be directly applied to describing the performance of the quantum refrigerator using spin- J systems as the working substance. Finally, the optimum characteristics of the quantum Carnot and Ericsson refrigeration cycles are derived by analogy.