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Chapman & Hall/CRC eBooks

Quantum Ensembles

Kerson Huang

Published Sep 21, 2009• 0 citations
Publisher

Abstract

A fundamental difference between classical and quantum mechanics is that, while classical mechanics uses real numbers, quantum mechanics uses complex numbers. This is so because quantum mechanics describes a system in terms of wave functions, which are complex numbers, with a modulus and a phase. The phase gives rise to the phenomenon of quantum interference, which has no classical counterpart.

DOI
10.1201/9781439878132-17

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A fundamental difference between classical and quantum mechanics is that, while classical mechanics uses real numbers, quantum mechanics uses complex numbers. This is so because quantum mechanics describes a system in terms of wave functions, which are complex numbers, with a modulus and a phase. The phase gives rise to the phenomenon of quantum interference, which has no classical counterpart.
Quantum mechanics seems to use complex numbers in a fundamentally different way when compared to classical physics. Selected episodes from early stages of the theory are presented to identify different approaches to the use of complex numbers. If for Heisenberg it seemed quite natural to use complex exponentials, Schrödinger clearly struggled with the complex nature of his wave function and tried to assign physical meaning only to its real component. Dirac was probably the first to stress that complex quantities in quantum mechanics cannot be split up into pure real and imaginary parts. Possible educational implications are outlined.
The study of quantum statistical mechanics begins with a review of the basic principles of quantum mechanics. Schrödinger’s equation is introduced and Eigenstates (or stationary states) are defined. Model probability for quantum statistics is assumed to have a uniform distribution in phases. Wave functions for many-body systems are defined. The density matrix is introduced. The Planck entropy and the microcanonical ensemble are defined. The differences between classical and quantum statistical mechanics are all based on the differing concepts of a microscopic ‘state’. While the classical microscopic state (specified by a point in phase space) determines the exact position and momentum of every particle, the quantum mechanical state determines neither; quantum states can only provide probability distributions for observable quantities.
Details of the many-particle system can also be read from my book titled “Quantum Field Theory: Feynman Path Integrals and Diagrammatic Techniques in Condensed Matter” [ 23 ]. The fundamental difference between classical and quantum mechanics relates the concept of indistinguishability of identical particles where each particle can be equipped with an identifying marker without influencing its behavior in classical mechanics. Besides in classical mechanics, the particle follows its own continuous path in phase space and so it is possible to determine the particular process taking place. So, principally, each particle in a group of identical particles can be identified which is not so in quantum mechanics. It is not possible to mark a particle without influencing its physical state, and worse, if a number of identical particles are brought to the same region in space, their wave functions will rapidly spread out and overlap with one another, thereby soon rendering it impossible to say which particle is where. One of the fundamental assumptions for many-particle systems is therefore that identical particles (i.e., particles characterized by the same quantum numbers such as mass, charge and spin) are, in principle, indistinguishable.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
We analyze the difference between classical mechanics and quantum mechanics. We come to the conclusion that this difference can be found in the nature of the observables that are considered for the physical system under consideration. Classical mechanics can only describe a certain kind of what we called ‘‘classical observable.’’ Quantum mechanics can only describe another kind of observable; it cannot describe, however, classical observables. To perform this analysis, we use a theory where every kind of observable can be treated and which is in a natural way a generalization of both classical and quantum mechanics. If in a study of a physical system in this theory we restrict ourselves to the classical observables, we rediscover classical mechanics as a kind of first study of the physical system, where all the nonclassical properties are hidden. If we find that this first study is too rough we can also study the nonclassical part of the physical system by a theory which is eventually quantum mechanics.