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Physical Review A

Electron Correlations in the Unified Model for Stark Broadening

Hubert Capes, Dietrich Voslamber

Published Oct 1, 1972• 1 citation
Publisher
DOI
10.1103/physreva.6.1689

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Application of the Model Microfield Method to Stark Profiles of Alkali Metal Resonance Lines

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Abstract Stark widths and shifts of alkali metal resonance lines are calculated by the model microfield method (MMM). The im pact results of Griem for the prevailing electronic broadening are recovered by the unified MMM. Both theories are in close agreement with recent experimental results. It is shown further that the shift values are very sensitive to the line strength values of the involved transitions. The reliability of the experimentally observed regularities through the alkali sequence is next discussed. On the basis of the MMM results these regularities can be understood in term s of the line strengths and frequencies of transitions from the main levels actually involved.

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Comments on the validity of the unified classical path theory of Stark broadening

E. W. Smith, J. Cooper, C. R. Vidal

In a recent paper by Frisch and Brissaud (ibid., Vol. 4, 1230, 1971) certain aspects of the unified classical path theory for Stark broadening are criticized; since it is felt that their results could be misleading. Some comments on their paper are offered.

Journal of Physics B Atomic and Molecular Physics•Feb 1, 1972•4 citations
Abstract Stark widths and shifts of alkali metal resonance lines are calculated by the model microfield method (MMM). The im pact results of Griem for the prevailing electronic broadening are recovered by the unified MMM. Both theories are in close agreement with recent experimental results. It is shown further that the shift values are very sensitive to the line strength values of the involved transitions. The reliability of the experimentally observed regularities through the alkali sequence is next discussed. On the basis of the MMM results these regularities can be understood in term s of the line strengths and frequencies of transitions from the main levels actually involved.