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Morgan & Claypool Publishers eBooks

Non-relativistic quantum mechanics

Nick Evans, Stephen F. King

Published Jun 1, 2018• 1 citation
Publisher

Abstract

To set the scene for the work to come we begin here by reviewing the basics of nonrelativistic quantum mechanics. We will mostly work in one dimension. We will motivate the form of the Schrödinger equation, discuss the information content and interpretation of the wave function, and finally work through the simple example of the square well, including introducing the ideas of orthogonality and completeness.

DOI
10.1088/978-1-6817-4983-9ch1

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To set the scene for the work to come we begin here by reviewing the basics of nonrelativistic quantum mechanics. We will mostly work in one dimension. We will motivate the form of the Schrödinger equation, discuss the information content and interpretation of the wave function, and finally work through the simple example of the square well, including introducing the ideas of orthogonality and completeness.
The universe we live in is both strange and interesting. This strangeness comes about because, at the most fundamental level, the universe is governed by the laws of quantum mechanics. This is the most spectacularly accurate and powerful theory ever devised, one that has given us insights into many aspects of the world, from the structure of matter to the meaning of information. This textbook provides a comprehensive account of all things quantum. It starts by introducing the wavefunction and its interpretation as an ephemeral wave of complex probability, before delving into the mathematical formalism of quantum mechanics and exploring its diverse applications, from atomic physics and scattering, to quantum computing. Designed to be accessible, this volume is suitable for both students and researchers, beginning with the basics before progressing to more advanced topics.
Abstract The mathematics underpinning quantum mechanics is reviewed and discussed at length. The Sturm-Liouville theory of linear differential equations is presented. It is shown that the solutions form a complete set of orthogonal functions with real eigenvalues, and the magnitude of the eigenvalues form an ascending series beginning from a minimum. The formulation of the Dirac bra-ket notation and its meaning and applications is developed. We examine the idea of Hilbert space and the general abstract form of the theory as developed by Dirac and Jordan, introducing the Dirac notation which will be used in the rest of the book.
It is argued (Part A) that quantum mechanics can be derived as a principle-based dynamical framework, the basic equation of which is an alternative form of the Hamilton-Jacobi equation. Schrodinger's equation obtains as a result of linearising that equation, and so-called wave functions can be given no straightforward physical interpretation. It is suggested, partly in relation to a theorem by Gromov, that a finite action quantum would make it practically inevitable, for purposes of prediction, to resort to a probabilistic formulation. The structure of the space of square-integrable solutions of the Schrodinger equation happens to lend itself to the introduction of the appropriate kind of predictive scheme. Investigating the nature and scope of such a scheme is the subject of Part B. It is shown that basic features of the formalism of quantum theory, like composition rules for 'amplitudes' or the 'Born' probability rule, can be derived independently of any physical assumptions. A generalisation of the basic formalism using tensor product composition appears to be required if all correlations are to be extracted from locally accessed data. A detailed discussion of quantum teleportation leads to the conclusion that a 'one-shot' account leads to a distorted picture of what is actually achieved. An analogy with classical cryptography is made and the statistical significance of the 'transfer', which does not require introducing any novel form of 'quantum information', is emphasised. Results obtained over the last decade using the extended formalism of positive operator-valued measures are reviewed and discussed. These lend further support to the idea that the set of basic 'quantum' rules functions as a general kind of probabilistic scheme for prediction, the structural features of which are not constrained in any direct way by the underlying physics. On the other hand, the very existence of such a predictive framework hinges on selecting a particular class of solutions of the Schrodinger equation, which selection has been incorrectly interpreted as reflecting a physical necessity.