This chapter considers what would happen to a mixture with the statistical operator 𝗨 if a quantity 𝖱 with operator 𝖱 is measured in it. It then investigates the thermodynamics of quantum mechanical ensembles from two different points of view. First, the chapter assumes the validity of both of the fundamental laws of thermodynamics, and proceeds on this basis to calculation of the entropy of ensembles. In this effort the normal methods of phenomenological thermodynamics are applied, and quantum mechanics plays a role only insofar as these thermodynamic observations relate to objects whose behavior is regulated by the laws of quantum. Afterwards this chapter proves the validity of these fundamental laws in quantum mechanics. Next, the chapter introduces some reversibility and equilibrium problems. Finally, this chapter discusses the macroscopic measurement.
This chapter considers what would happen to a mixture with the statistical operator 𝗨 if a quantity 𝖱 with operator 𝖱 is measured in it. It then investigates the thermodynamics of quantum mechanical ensembles from two different points of view. First, the chapter assumes the validity of both of the fundamental laws of thermodynamics, and proceeds on this basis to calculation of the entropy of ensembles. In this effort the normal methods of phenomenological thermodynamics are applied, and quantum mechanics plays a role only insofar as these thermodynamic observations relate to objects whose behavior is regulated by the laws of quantum. Afterwards this chapter proves the validity of these fundamental laws in quantum mechanics. Next, the chapter introduces some reversibility and equilibrium problems. Finally, this chapter discusses the macroscopic measurement.
This chapter presents the measurement problem from the point of view of the thermal interpretation of quantum physics. Everything physicists measure is measured in a thermal environment, for which statistical thermodynamics is relevant. The thermal interpretation agrees with how one interprets measurements in thermodynamics, the macroscopic part of quantum physics, derived via statistical mechanics. By its very construction, the thermal interpretation naturally matches the classical properties of our quantum world: The thermal interpretation assigns states-and a realistic interpretation for them-to individual quantum systems, in a way that large quantum systems are naturally described by classical observables. Since measurement devices are large quantum systems, this is the key to solving the measurement problem. We discuss the role played by macroscopic systems and the weak law of large numbers in getting readings with small uncertainty. Since quantum physics makes many deterministic predictions, for example regarding observed spectra, but also assertions about probabilities, we distinguish deterministic and statistical measurements. To clarify the meaning of the concept of measurement, we postulate (in Section 11.1) a measurement principle that defines what it means in the thermal interpretation to measure a quantity with a specified uncertainty. This turns the measurement problem from a philosophical riddle into a scientific problem in the domain of quantum statistical mechanics, namely how the quantum dynamics correlates macroscopic readings from an instrument with properties of the state of a measured microscopic system. The essence of scientific practice is the reproducibility of measurements, discussed in Section 11.2. Unlike in traditional interpretations, single, nonreproducible observations do not count as measurements, since this would violate the reproducibility of measurements-the essence of scientific practice. As a consequence, the measurement of a Hermitian quantity A is regarded as giving an uncertain value approximating the q-expectation {A} rather than (as tradition wanted to have it) as an exact revelation of an eigenvalue of A. This difference is most conspicuous in the interpretation of single discrete microscopic events. Except in very special circumstances, these are not reproducible. Thus, they have no scientific value in themselves and do not constitute measurement results. Scientific value is, however, in ensembles of such observations, which result in approximate measurements of q-probabilities and q-expectations. Sections 11.3 and 11.4 distinguish deterministic and statistical measurements, depending on whether a single observation is reproducible, and discuss the role played by macroscopic systems and the weak law of large numbers in getting readings with small uncertainty. How to measure the q-probabilities of events, described in terms of POVMs, is discussed in Section 11.5. Section 11.6 poses the measurement problem as a problem of the statistical mechanics of measurement devices, and discuss recent work by Allahverdyan, Balian, and Nieuwenhuizen on its resolution. Section 11.7 discusses the problem how, in the thermal interpretation, discrete events can arise, although qexpectations are by their very nature continuous. This is resolved by pointing to work by Breuer and Petruccione on piecewise deterministic processes (PDP). Section 11.8 sheds additional light on the origin of discrete events by an analysis of the role dissipative bistability plays in obtaining discreteness in classical physics.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum systems. In the present contribution a simple but effective theoretical framework is introduced to clarify the connections between a purely mechanical description and the thermodynamic characterization of the equilibrium state of an isolated quantum system. A salient feature of our approach is the very transparent distinction between the statistical aspects and the dynamical aspects in the description of isolated quantum systems. Like in the classical statistical mechanics, the equilibrium distribution of any property is identified on the basis of the time evolution of the considered system. As a consequence equilibrium properties of quantum system appear to depend on the details of the initial state due to the abundance of constants of the motion in the Schrodinger dynamics. On the other hand the study of the probability distributions of some functions, such as the entropy or the equilibrium state of a subsystem, in statistical ensembles of pure states reveals the crucial role of typicality as the bridge between macroscopic thermodynamics and microscopic quantum dynamics. We shall consider two particular ensembles: the random pure state ensemble and the fixed expectation energy ensemble. The relation between the introduced ensembles, the properties of a given isolated system, and the standard quantum statistical description are discussed throughout the presentation. Finally we point out the conditions which should be satisfied by an ensemble in order to get meaningful thermodynamical characterization of an isolated quantum system.
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper, I analyze and calculate the thermodynamic entropy for large but finite quantum mechanical systems. A special feature of this analysis is that the thermodynamic energy of a quantum system is shown to be a continuous variable, rather than being associated with discrete energy eigenvalues. Calculations of the entropy as a function of energy can be carried out with a Legendre transform of thermodynamic potentials obtained from a canonical ensemble. The resultant expressions for the entropy are able to describe equilibrium between quantum systems having incommensurate energy-level spacings. This definition of entropy preserves all required thermodynamic properties, including satisfaction of all postulates and laws of thermodynamics. It demonstrates the consistency of the concept of negative temperature with the principles of thermodynamics.
The quantum mechanical measurement process is analysed in detail, especially from the group theoretical point of view. The first three chapters review the results obtained before briefly. In §1, the classical theory of measurement, originated by von Neumann, is birefly described. The importance of considering more general schemes of measurements than the original one is, however, emphasized. In §2, the role of conservation laws, in imposing limitations on the possibility of measurements, is discussed. Accurately measurable quantities are defined in this context. In §3, the role of conservation laws is further analysed. It is shown that the conserved quantity of the apparatus cannot be used for a “pointer reading.” The following two chapters discuss the nature of the exactly measurable quantities. In §4, exactly measurable quantities are explicitly determined. It is shown that the measurement of projection operators in the Hilbert space of the object which commute with the operators of the restricted Poincaré group give all the information on the states of the object that can be obtained by accurate measurements. In §5, the measurement on objects which are composed of more than one particle is discussed. The last chapter, §6, deals with approximately measurable quantities, but no complete estimate of the unavoidable inaccuracy of the measurement of these is obtained. It also contains some concluding remarks.
Entropy is a fundamental concept which emerged along with other ideas during the development of thermodynamics and statistical mechanics Landau and Lifshitz (1978); Lieb and Yngvason (1999). Entropy has developed foremost out of phenomenological thermodynamical considerations such as the second law of thermodynamics in which it plays a prominent role Wehrl (1978). With the intense interest in the investigation of the physics of matter at the atomic and subatomic quantum levels, it maywell be askedwhether this concept can emerge out of the study of systems at a more fundamental level. In fact, it may be argued that a correct definition is only possible in the framework of quantum mechanics, whereas in classical mechanics, entropy can only be introduced in a rather limited and artificial way. Entropy relates macroscopic and microscopic aspects of nature, and ultimately determines the behavior of macroscopic systems. It is the intention here to present an introduction to this subject in a readable manner from the quantum point of view. There are many reasons for undertaking this. The intense interest in irreversible thermodynamics Grossing (2008), the statistical mechanics of astrophysical objects Padmanabhan (1990); Pathria (1977), quantum gravity and entropy of black holes Peres & al. (2004), testing quantum mechanics Ballentine (1970) and applications to condensed matter and quantum optics Haroche & al. (2006); Raimond & al. (2001) are just a few areas which are directly or indirectly touched on here. Let us begin by introducing the concept of entropy from the quantummechanical perspective, realizing that the purpose is to focus on quantum mechanics in particular. Quantum mechanics makes a clear distinction between observables and states. Observables such as position and momentum are mathematically described by self-adjoint operators in a Hilbert space. States, which are generally mixed, can be described by a density matrix, which is designated by ρ throughout. This operator ρ is Hermitean, has trace one and yields the expectation value of an observable A in the state ρ through the definition