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CRC Press eBooks

Introduction

D.Ya. Petrina, V.I. Gerasimenko, P V Malyshev

Published Apr 11, 2002• 0 citations
Publisher

Abstract

In the present monograph, we study infinite classical statistical systems, i.e., systems of infinitely many particles in the infinite phase space. The states of these systems are completely defined by infinite sequences of correlation functions. The key problem of statistical mechanics is to determine the state of a many-particle system at any time if the initial state is known, i.e., to determine its evolution. The other important problem is to determine and investigate equilibrium (stationary) states of statistical systems.

DOI
10.1201/9781482265026-7

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In the present monograph, we study infinite classical statistical systems, i.e., systems of infinitely many particles in the infinite phase space. The states of these systems are completely defined by infinite sequences of correlation functions. The key problem of statistical mechanics is to determine the state of a many-particle system at any time if the initial state is known, i.e., to determine its evolution. The other important problem is to determine and investigate equilibrium (stationary) states of statistical systems.
The study of quantum statistical mechanics begins with a review of the basic principles of quantum mechanics. Schrödinger’s equation is introduced and Eigenstates (or stationary states) are defined. Model probability for quantum statistics is assumed to have a uniform distribution in phases. Wave functions for many-body systems are defined. The density matrix is introduced. The Planck entropy and the microcanonical ensemble are defined. The differences between classical and quantum statistical mechanics are all based on the differing concepts of a microscopic ‘state’. While the classical microscopic state (specified by a point in phase space) determines the exact position and momentum of every particle, the quantum mechanical state determines neither; quantum states can only provide probability distributions for observable quantities.
Introduction. 1: Evolution of States of Quantum Systems of Finitely Many Particles. 1. Principal Concepts of Quantum Mechanics. 2. Evolution of States of Quantum Systems with Arbitrarily Many Particles. 3. Evolution of States in the Heisenberg Representation and in the Interaction Representation. Mathematical Supplement I. References. 2: Evolution of States of Infinite Quantum Systems. 4. Bogolyubov Equations for Statistical Operators. 5. Solution of the Bogolyubov Equations. 6. Gibbs Distributions. Mathematical Supplement II. Mathematical Supplement III. References. 3: Thermodynamic Limit. 7. Thermodynamic Limit for Statistical Operators. 8. Statistical Operators in the Case of Quantum Statistics. 9. Bogolyubov's Principle of Weakening of Correlations. Mathematical Supplement IV. References. 4: Mathematical Problems in the Theory of Superconductivity. 10. Frohlich Model. 11. Bogolyubov's Compensation Principle for 'Dangerous' Diagrams. Compensation Equations. 12. Bardeen--Cooper--Schrieffer (BCS) Hamiltonian. 13. Microscopic Theory of Superfluidity. Mathematical Supplement V. References. 6: Green's Functions. 14. Green's Functions. Equations for Green's Functions. 15. Investigation of the Equations for Green's Functions in the Theory of Superconductivity and Superfluidity. 16. Green's Functions in the Thermodynamic Limit. References. 6: Exactly Solvable Models. 17. Description of the Hamiltonians of Model Systems. 18. Functional Spaces of Translation--Invariant Function. 19. ModelHamiltonians in the Spaces of Translation Invariant Functions. 20. Model BCS Hamiltonian in the Space hT. Equivalence of General and Model Hamiltonians in the Space of Pairs. 21. Equations for Green's Functions and their Solutions. Mathematical Supplement VI. References. 7: Quasiaverages. Theorem on Singularities of Green's Functions of 1/q2-Type. 22. Quasiaverages. 23. Green's Functions and their Spectral Representations. 24. Theorem on Singularities of Green's Functions of 1/q2-Type. References. Subject Index.
Classical and quantum statistical mechanics are cast here in the language of projective geometry to provide a unified geometrical framework for statistical physics. After reviewing the Hilbert–space formulation of classical statistical thermodynamics, we show that the specification of a canonical polarity on the real projective space RPn induces a Riemannian metric on the state space of statistical mechanics. In the case of the canonical ensemble, equilibrium thermal states are determined by a Hamiltonian gradient flow with respect to this metric. This flow is characterized by the property that it induces a projective automorphism on the state manifold. The measurement problem for thermal systems is studied by the introduction of the concept of a random state. The general methodology is then extended to establish a new framework for the quantum–mechanical dynamics of equilibrium thermal states. In this case, the relevant phase space is the complex projective space CPn, here regarded as a real manifold γ endowed with the Fubini–Study metric and a compatible symplectic structure. A distinguishing feature of quantum thermal dynamics is the inherent multiplicity of thermal trajectories in the state space, associated with the non–uniqueness of the infinite–temperature state. We are then led to formulate a geometric characterization of the standard KMS relation often considered in the context of C* algebras. Finally, we develop a theory of the quantum microcanonical and canonical ensembles, based on the geometry of the quantum phase space γ. The example of a particle of quantum spin–1/2 particle in a heat bath is studied in detail.
The statistical mechanics of systems whose evolution is governed by mixed quantum-classical dynamics is investigated. The algebraic properties of the quantum-classical time evolution of operators and of the density matrix are examined and compared to those of full quantum mechanics. The equilibrium density matrix that appears in this formulation is stationary under the dynamics and a method for its calculation is presented. The response of a quantum-classical system to an external force which is applied from the distant past when the system is in equilibrium is determined. The structure of the resulting equilibrium time correlation function is examined and the quantum-classical limits of equivalent quantum time correlation functions are derived. The results provide a framework for the computation of equilibrium time correlation functions for mixed quantum-classical systems.