Quantum Theory of Dissipative Processes and Non-Equilibrium Thermodynamics

Ilya Prigogine

Roumen Tsekov

A new approach to dissipative quantum mechanics is proposed. The irreversible processes occurring in an isothermic system are treated on the basis of statistical and linear non-equilibrium thermodynamics. The equilibrium probability density provided by the present theory coincides with the quantum canonical Gibbs distribution. In the classical limit the obtained kinetic equation reduces to a Markov theory result.

Mário Motta, Antonio Mezzacapo, Giacomo Guarnieri

Thermodynamic uncertainty relations (TURs) are a set of inequalities expressing a fundamental trade-off between precision and dissipation in non-equilibrium classical and quantum thermodynamic processes. TURs show that achieving low fluctuations in a thermodynamic quantity (e.g., heat or work) requires a minimum entropy production, with profound implications for the efficiency of biological and artificial thermodynamic processes. The accurate evaluation of TURs is a necessary requirement to quantify the fluctuation and dissipation entailed by a thermodynamic process, and ultimately to optimize the performance of quantum devices, whose operation is fundamentally a quantum thermodynamic process. Here, we simulate TURs in a transverse-field Ising model subjected to a time-dependent driving protocol, using quantum and classical computers in concert. Varying the duration and strength of the drive as well as the system size, we verify the validity of TURs, identify quantum signatures in the work statistics within the linear response regime, and observe TUR saturation in the high-temperature limit.

C. Ray Smith, Vittorio Verda, Michael R. von Spakovsky

Revista, Zen, PHYSICS, 10

This paper explores topological thermodynamics in driven dissipative quantum materials, a field at the intersection of non-equilibrium statistical mechanics, quantum topology, and condensed matter physics. We review theoretical frameworks and experimental advancements, highlighting how driving forces and dissipative processes influence the formation, stability, and characterization of topological phases. A special focus is placed on Floquet engineering for open quantum systems, where periodic driving and environmental coupling lead to novel non-equilibrium steady states with exotic topological properties. We discuss challenges in defining thermodynamic quantities like temperature and entropy in these far-from-equilibrium settings and examine how topological invariants manifest in dissipative dynamics and transport. The paper uniquely synthesizes advancements in periodically driven, open quantum systems by critically examining how dissipation, often seen as detrimental, can be precisely engineered to reveal or even stabilize topological order. This offers a distinct perspective on designing next-generation quantum technologies. Key theoretical tools, including generalized Floquet theory, Keldysh formalism, and non-Hermitian descriptions, are discussed alongside experimental platforms like photonic quantum gases and cold atomic systems.

Álvaro Tejero, Martín de la Rosa

In this work, we present a geometrical formulation of quantum thermodynamics based on contact geometry and principal fiber bundles. The quantum thermodynamic state space is modeled as a contact manifold, with equilibrium Gibbs states forming a Legendrian submanifold that encodes the fundamental thermodynamic relations. A principal fiber bundle over the manifold of density operators distinguishes the quantum state structure from thermodynamic labels: its fibers represent non-equilibrium configurations, and their unique intersections with the equilibrium submanifold enforce thermodynamic consistency. Quasistatic processes correspond to minimizing geodesics under the Bures-Wasserstein metric, leading to minimal dissipation, while the divergence of geodesic length toward rank-deficient states geometrically derives the unattainability aspect of the third law. Non-equilibrium extensions, formulated through pseudo-Riemannian metrics and connections on the principal bundle, introduce curvature-induced holonomy that quantifies a geometric source of irreversibility in cyclic processes. In this framework, the thermodynamic laws in the quantum regime emerge naturally as geometric consequences.