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Critical phenomena: General considerations. Mean-field theory (MFT)

Jean Zinn‐Justin

Published Apr 15, 2021• 0 citations
Publisher

Abstract

Abstract This chapter is devoted to a brief review of general properties of phase transitions in macroscopic physics and, in particular in lattice models. Some of these lattice models actually appear as lattice regularizations of Euclidean (imaginary time) quantum physics theory (QFT). Most of the transitions considered in this work have the following character: spins on the lattice, or macroscopic particles in the continuum, interact through short-range forces, assumed, for simplicity, to decay exponentially. For simple systems, it is possible to find a local observable, called order parameter, whose expectation values depend on the phase in the several phase region, for example, the spin in ferromagnetic systems. In the disordered phase, the connected two-point function decreases exponentially at large distance, at a rate characterized by the correlation length (the inverse of the smallest physical mass in particle physics). In continuous transitions, the correlation length diverges at the critical temperature. Within the mean-field approximation (consistent with Landau's theory of critical phenomena), it can be shown that the singular behaviour of thermodynamic quantities at the critical temperature is universal. These properties can also be reproduced by calculating correlation functions with a perturbed Gaussian measure. It is then shown that the leading corrections to the mean-field approximation, in Ising-like systems, diverge at the critical temperature for dimensions smaller than or equal to $4$.

DOI
10.1093/oso/9780198834625.003.0014

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Abstract This chapter is devoted to a brief review of general properties of phase transitions in macroscopic physics and, in particular in lattice models. Some of these lattice models actually appear as lattice regularizations of Euclidean (imaginary time) quantum physics theory (QFT). Most of the transitions considered in this work have the following character: spins on the lattice, or macroscopic particles in the continuum, interact through short-range forces, assumed, for simplicity, to decay exponentially. For simple systems, it is possible to find a local observable, called order parameter, whose expectation values depend on the phase in the several phase region, for example, the spin in ferromagnetic systems. In the disordered phase, the connected two-point function decreases exponentially at large distance, at a rate characterized by the correlation length (the inverse of the smallest physical mass in particle physics). In continuous transitions, the correlation length diverges at the critical temperature. Within the mean-field approximation (consistent with Landau's theory of critical phenomena), it can be shown that the singular behaviour of thermodynamic quantities at the critical temperature is universal. These properties can also be reproduced by calculating correlation functions with a perturbed Gaussian measure. It is then shown that the leading corrections to the mean-field approximation, in Ising-like systems, diverge at the critical temperature for dimensions smaller than or equal to 444.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
Abstract In Chapter 14, the singular behavior of ferromagnetic systems with O(N) symmetry and short-range interactions, near a second order phase transition has been determined in the mean-field approximation, which is also a quasi-Gaussian approximation. The mean-field approximation predicts a set of universal properties, properties independent of the detailed structure of the microscopic Hamiltonian, the dimension of space, and, to a large extent, of the symmetry of systems. However, the leading corrections to the mean-field approximation, in dimensions smaller than or equal to four, diverge at the critical temperature, and the universal predictions of the mean-field approximation cannot be correct. Such a problem originates from the non-decoupling of scales and leads to the question of possible universality. In Chapter 9, the question has been answered in four dimensions using renormalization theory, and related renormalization group (RG) equations. Moreover, below four dimensions, in an expansion around the mean-field, the most singular terms near criticality can be also formally recovered from a continuum, low-mass φ4 field theory. More generally, following Wilson, to understand universality beyond the mean-field approximation, it is necessary to build a general renormalization group in the form of flow equations for effective Hamiltonians and to find fixed points of the flow equations. Near four dimensions, the flow equations can be approximated by the renormalization group of quantum field theory (QFT), and the fixed points and critical behaviours derived within the framework of the Wilson-Fisher ϵ expansion.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
1. Quantum Field Theory and Renormalization Group 2. Gaussian Expectation Values. Steepest Descent Method . 3. Universality and Continuum Limit 4. Classical Statistical Physics: One Dimension 5. Continuum Limit and Path Integral 6. Ferromagnetic Systems. Correlations 7. Phase transitions: Generalities and Examples 8. Quasi-Gaussian Approximation: Universality, Critical Dimension 9. Renormalization Group: General Formulation 10. Perturbative Renormalization Group: Explicit Calculations 11. Renormalization group: N-component fields 12. Statistical Field Theory: Perturbative Expansion 13. The sigma4 Field Theory near Dimension 4 14. The O(N) Symmetric (phi2)2 Field Theory: Large N Limit 15. The Non-Linear sigma-Model 16. Functional Renormalization Group Appendix 1. Quantum Field Theory and Renormalization Group 2. Gaussian Expectation Values. Steepest Descent Method . 3. Universality and Continuum Limit 4. Classical Statistical Physics: One Dimension 5. Continuum Limit and Path Integral 6. Ferromagnetic Systems. Correlations 7. Phase transitions: Generalities and Examples 8. Quasi-Gaussian Approximation: Universality, Critical Dimension 9. Renormalization Group: General Formulation 10. Perturbative Renormalization Group: Explicit Calculations 11. Renormalization group: N-component fields 12. Statistical Field Theory: Perturbative Expansion 13. The sigma4 Field Theory near Dimension 4 14. The O(N) Symmetric (phi2)2 Field Theory: Large N Limit 15. The Non-Linear sigma-Model 16. Functional Renormalization Group Appendix
Overview As discussed in Chapter 16 , when we approach the critical temperature of a phase coexistence line, several fascinating things start to happen which together have come to be known as “critical phenomena.” It is observed that the spatial correlation between relevant order parameters like density, magnetization, etc. becomes infinitely large. This is reflected in the divergence of inverse susceptibility of the respective order parameters. Landau’s theory explains this in terms of the flattening of the free energy surface but fails to unravel many of the other mysteries of critical phenomena that have kept scientists engaged now for about a century. Critical phenomena are characterized by certain singular properties, like the universality of the critical exponents. Several aspects of the critical phenomena are discussed in this chapter with an aim to maintain continuity with earlier chapters. A simple theory (like that of Landau) cannot explain many of the observed features and this problem remained unsolved for a long time until K. G. Wilson could develop a sophisticated theory that explained almost everything. At the core of Wilson’s method is the renormalization group technique. Physically, this technique employs the expected invariance of the Hamiltonian due to a transformation that removes local interactions and replaces them by effective longer range interactions. Because of the existence of long range correlations, the transformation is expected to converge to a fixed point. The procedure is quite mathematical and is the only robust method to obtain the critical exponents. Here we discuss the method briefly, as an introduction to the subject.
This chapter describes the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, the general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Phase transitions occur in macroscopic systems when one or more external parameters like temperature, pressure, electrical field, magnetic field, etc are varied. The chapter demonstrates the utility of the alternative formulations of thermodynamics and statistical mechanics in the context of phase transitions and shows how their use clarifies and unifies the theory of phase transitions. It deals with the basic thermodynamic description of a single component fluid. To understand different phases and associated transitions, one studies how the couplings flow in the parameter space under repeated Renormalization Group (RG) transformations. The flows around the fixed point are easily studied by linearizing the RG equations around the fixed points and determining the eigenvalues and eigenvectors of the linearized RG transformations.