This chapter presents a simple approximation scheme — the mean field approximation — which allows a study of the neighbourhood of the transition temperature. It distinguishes between first and second order phase transitions. In the latter case, the correlation length diverges at the critical (transition) temperature. This has important physical consequences: in the mean field approximation, the singular behaviour of thermodynamic quantities at the critical temperature, and more generally in the neighbourhood of the critical temperature and in small magnetic field, is universal, that is, does not depend on the details of the interactions, on the dimension of space and, in the high temperature phase at least, on the symmetry of the models.
This chapter presents a simple approximation scheme — the mean field approximation — which allows a study of the neighbourhood of the transition temperature. It distinguishes between first and second order phase transitions. In the latter case, the correlation length diverges at the critical (transition) temperature. This has important physical consequences: in the mean field approximation, the singular behaviour of thermodynamic quantities at the critical temperature, and more generally in the neighbourhood of the critical temperature and in small magnetic field, is universal, that is, does not depend on the details of the interactions, on the dimension of space and, in the high temperature phase at least, on the symmetry of the models.
Abstract This chapter is devoted to a brief review of general properties of phase transitions in macroscopic physics and, in particular in lattice models. Some of these lattice models actually appear as lattice regularizations of Euclidean (imaginary time) quantum physics theory (QFT). Most of the transitions considered in this work have the following character: spins on the lattice, or macroscopic particles in the continuum, interact through short-range forces, assumed, for simplicity, to decay exponentially. For simple systems, it is possible to find a local observable, called order parameter, whose expectation values depend on the phase in the several phase region, for example, the spin in ferromagnetic systems. In the disordered phase, the connected two-point function decreases exponentially at large distance, at a rate characterized by the correlation length (the inverse of the smallest physical mass in particle physics). In continuous transitions, the correlation length diverges at the critical temperature. Within the mean-field approximation (consistent with Landau's theory of critical phenomena), it can be shown that the singular behaviour of thermodynamic quantities at the critical temperature is universal. These properties can also be reproduced by calculating correlation functions with a perturbed Gaussian measure. It is then shown that the leading corrections to the mean-field approximation, in Ising-like systems, diverge at the critical temperature for dimensions smaller than or equal to 4.
In the preceding two chapters, we have discussed various types of order that can occur in nature and how the ordering process can be quantified by the introduction of order parameters. We also developed a formalism for dealing with the thermodynamics of ordered states. In this chapter, we will use mean-field theory to study phase transitions and the properties of various ordered phases. Mean-field theory is an approximation for the thermodynamic properties of a system based on treating the order parameter as spatially constant. It is a useful description if spatial fluctuations are not important. It becomes an exact theory only when the range of interactions becomes infinite. It, nevertheless, makes quantitatively correct predictions about some aspects of phase transitions (e.g. critical exponents) in high spatial dimensions where each particle or spin has many nearest neighbors, and it makes qualitatively correct predictions in physical dimensions. Mean-field theory has the enormous advantage of being mathematically simple, and it is almost invariably the first approach taken to predict phase diagrams and properties of new experimental systems. Before proceeding, let us review some simple facts about phase transitions. At high temperatures, there is no order, and the order parameter 〈φ〉 is zero. At a critical temperature, T c , order sets in so that, for temperatures below T c , 〈φ〉 is nonzero. If 〈φ〉 rises continuously from zero, as shown in Fig. 4.0.1a, the transition is second order .
Abstract In Chapter 14, the singular behavior of ferromagnetic systems with O(N) symmetry and short-range interactions, near a second order phase transition has been determined in the mean-field approximation, which is also a quasi-Gaussian approximation. The mean-field approximation predicts a set of universal properties, properties independent of the detailed structure of the microscopic Hamiltonian, the dimension of space, and, to a large extent, of the symmetry of systems. However, the leading corrections to the mean-field approximation, in dimensions smaller than or equal to four, diverge at the critical temperature, and the universal predictions of the mean-field approximation cannot be correct. Such a problem originates from the non-decoupling of scales and leads to the question of possible universality. In Chapter 9, the question has been answered in four dimensions using renormalization theory, and related renormalization group (RG) equations. Moreover, below four dimensions, in an expansion around the mean-field, the most singular terms near criticality can be also formally recovered from a continuum, low-mass φ4 field theory. More generally, following Wilson, to understand universality beyond the mean-field approximation, it is necessary to build a general renormalization group in the form of flow equations for effective Hamiltonians and to find fixed points of the flow equations. Near four dimensions, the flow equations can be approximated by the renormalization group of quantum field theory (QFT), and the fixed points and critical behaviours derived within the framework of the Wilson-Fisher ϵ expansion.
Abstract This first chapter is an elementary introduction to the models and methods that will be used later. The ferromagnetic (Curie) transition serves as our prototype for all second-order phase transitions, and serves also to introduce the notions of broken symmetry and of order parameter. The basic model of ferromagnetism, namely the Ising model, is described in Section 1.2, and solved for an elementary case. The reason why this model is so important is that it has an exact solution in two dimensions, which exhibits spontaneous magnetization. Section 1.3 is devoted to a first approach to mean-field methods, which remain amongst the most frequently exploited approximations even today. They will lead us to define a first set of critical exponents; the listing of such exponents will then be completed in Section 1.4, once correlation functions have been defined. Finally, in Section 1.5 a qualitative description of critical phenomena will enable us, in a first approximation, to define the concept of scale invariance and its relation to the behaviour of the theory under dilatations.
This and the four next chapters are devoted to the study of several aspects of the theory of phase transition. This has been for more than one century, and still remains, a subject of intense experimental and theoretical activity, with important breakthroughs having impacts on different fields in physics but also on other disciplines such as mathematics, economics, sociology, biology In the first section of this chapter, the transition between the ferromagnetic and paramagnetic phases of the Ising system will be studied in the framework of a mean field approximation. The problem will first be addressed by means of the intuitive Weiss molecular field approximation ( Section 9.1.2 ) and then by means of the more detailed Bragg-Williams approximation ( Section 9.1.3 ) which will serve as a base to develop, in Section 9.2 , a general theory of continuous phase transitions: the Landau mean field theory for which the concept of order parameter will first be introduced. Other types of phase transitions will then be studied using the mean field approximation. Phase transitions in liquid crystals will be studied in Section 9.3 . These are systems with a tensor order parameter which exhibit a rich phenomenology. Finally, in Section 9.4 , a transition of a fairly more elaborate nature than a simple first or second order phase transition will be discussed.
Mean-field theory, presented in the preceding chapter, correctly describes the qualitative features of most phase transitions and, in some cases, the quantitative features. Since mean-field theory replaces the actual configurations of the local variables (e.g. spins) by their average value, it neglects the effects of fluctuations about this mean. These fluctuations may or may not be important. The more spins that interact with a particular test spin, the more the test spin sees an effective average or mean field. If the test spin interacts with two neighbors, the averaging is minimal and the fluctuations are large and important. The number of spins producing the effective field increases with the range of the interaction and with the dimension. Thus we will find that mean-field theory is a good approximation in high dimensions but fails to provide a quantitatively correct description of second-order critical points in low dimensions. This chapter will be devoted to the study of second-order phase transitions when mean-field theory is not a good approximation. We will begin by considering fluctuations of the order parameter about its spatially uniform mean-field value. We will find that for spatial dimensions below an upper critical dimension d c (typically d c = 4), fluctuations always become important and invalidate mean-field theory for temperatures sufficiently close to T c . This will motivate a generalization of Landau theory that incorporates spatial fluctuations about a mean-field free energy minimum.