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WSEAS TRANSACTIONS ON MATHEMATICS

Algebraic Method of Solution of Schrödinger’s Equation ofa Quantum Model

L.A-M. Hanna, Rania A. Alharbey, Sebawe Abdalla, Shoukry S. Hassan

Published Aug 17, 2020• 2 citations
Publisher

Abstract

This work is aiming to show the advantage of using the Lie algebraic decomposition technique to solvefor Schrödinger’s wave equation for a quantum model, compared with the direct method of solution. The advantageis a two-fold: one is to derive general form of solution, and, two is relatively manageable to deal with the case oftime-dependent system Hamiltonian. Specifically, we consider the model of 2-level optical atom and solve for thecorresponding Schrödinger’s wave equation using the Lie algebraic decomposition technique. The obtained formof solution for the wave function is used to examine computationally the atomic localization in the coordinate space.For comparison, the direct method of solution of the wave function is analysed in order to show its complicationwhen dealing with time-dependent Hamiltonian.The possibility of using the Lie algebraic method for a qubit model(a driven quantum dot model) is briery discussed, if Schrödinger’s wave function is to be examined for the qubitlocalization.

DOI
10.37394/23206.2020.19.43

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This work is aiming to show the advantage of using the Lie algebraic decomposition technique to solvefor Schrödinger’s wave equation for a quantum model, compared with the direct method of solution. The advantageis a two-fold: one is to derive general form of solution, and, two is relatively manageable to deal with the case oftime-dependent system Hamiltonian. Specifically, we consider the model of 2-level optical atom and solve for thecorresponding Schrödinger’s wave equation using the Lie algebraic decomposition technique. The obtained formof solution for the wave function is used to examine computationally the atomic localization in the coordinate space.For comparison, the direct method of solution of the wave function is analysed in order to show its complicationwhen dealing with time-dependent Hamiltonian.The possibility of using the Lie algebraic method for a qubit model(a driven quantum dot model) is briery discussed, if Schrödinger’s wave function is to be examined for the qubitlocalization.
A representation of invariants in quantum mechanics for a general time-dependent Hamiltonian is provided. The main properties of these operators and their relevance for solving the Schrödinger equation are discussed in light of this representation. In particular, the well-known Lewis and Riesenfeld’s method is shown to be recovered quite directly by the present approach. A detailed analysis is concerned with Hamiltonians which at each instant are elements of a finite dimensional Lie algebra. Exploiting the Wei and Norman’s theory for such Hamiltonians, it is found that the evolution of a quantum system is always determined, in part or fully, by an invariant which belongs to the same algebra.
Time-dependent unitary transformations are used to study the Schrödinger equation for explicitly time-dependent Hamiltonians of the form H(t)=R(t)⋅J, where R is an arbitrary real vector-valued function of time and J is the angular momentum operator. The solution of the Schrödinger equation for the most general Hamiltonian of this form is shown to be equivalent to the special case R=(1,0,ν(t)). This corresponds to the problem of a driven two-level atom for the spin half representation of J. It is also shown that by requiring the magnitude of R to depend on its direction in a particular way, one can solve the Schrödinger equation exactly. In particular, it is shown that for every Hamiltonian of the form H(t)=R(t)⋅J there is another Hamiltonian with the same eigenstates for which the Schrödinger equation is exactly solved. The application of the results to the exact solution of the parallel transport equation and exact holomony calculation for SU(2) principal bundles (Yang–Mills gauge theory) is also pointed out.
The Wave-particle duality and the Schrodinger cat paradox pose important notions on quantum mechanical systems, in which a quantum system can exist in two physically opposite or distinct states. This motivates scientists from the days of Louis de Broglie to confidently look at matter as having a dual nature, which is a physical particle that can also be visualized as a wave entity. This paper seeks to provide an elegant method of solving the time-independent Schrodinger Equation (TISE) for a quantum simple harmonic oscillator (QSHO). A fully algebraic method is presented, the paper explains in detail how simple algebra, coupled with basic quantum mechanical operator commutation algebra can be employed to solve the TISE without resorting to complicated mathematical methods of solving second-order differential equations. The construction of the Hamiltonian is explained and an analogy between the classical simple harmonic oscillator (CSHO) and the QSHO is drawn to develop the solution method. The action of creation and annihilation operators on wave functions is exploited to generate states with higher and lower energies respectively and to generate a Hamiltonian that can act on a system and generate required quantum states. The aim is to generate the ground state of the QSHO and its associated energy value. From this state, other higher energy states can be generated by the action of the creation operator. The use of algebraic methods has been seen to be versatile as it does not explicitly rely on any particular basis or coordinate system. The method allows operators to be manipulated in different bases for example the momentum operator can be given as P ̂ x=-iℏ (∂/∂x) in a spatial coordinate basis or as a pure number p ̂ =p in the momentum basis.
In this paper we generalize Wang's approach [J. Phys. A 20, 5041 (1987)] and investigate the algebraic structure of the Schr\"odinger equation associated with a general driven time-dependent oscillator. Using the Lie-algebraic technique we obtain an exact form of the time-evolution operator which, in turn, enables us to derive the propagator of the system readily. Since the propagator is for the most general time-dependent oscillator, results for any special case can be easily deduced from it. These results will be useful for future studies in quantum optics as well as in atomic and molecular physics.
Quantum technologies rely on the control of quantum systems at the level of individual quanta. Mathematically, this control is described by Hamiltonian or Liouvillian evolution, requiring the application of various techniques to solve the resulting dynamic equations. Here, we present a tutorial for how the quantum dynamics of systems can be solved using a Lie-algebra decoupling method. The approach involves identifying a Lie algebra that governs the dynamics of the system, enabling the derivation of differential equations to solve the Schrödinger equation. As background, we include an overview of Lie groups and Lie algebras aimed at a general-physicist audience. We then prove the Lie-algebra decoupling theorem and apply it to both closed and open dynamics. The results represent a broad methodology to find the dynamics of quantum systems with applications across many fields of modern quantum research.
An alternative method for obtaining analytical solutions of the time-independent Schrödinger equation (TISE) is developed and applied to 1-dimensional model quantum systems of interest in atomic and molecular physics. The method is based on proposing a wave function that is a product of two functions, one of them an integrating factor. The differential equation resulting from operating the TISE on the product wave function is compared with a differential equation with a known solution. This comparison produces a system of differential equations for the integrating factor. This system of equations is easily solved for model quantum systems such as the harmonic oscillator, the hydrogen atom and the Morse oscillator. The method presented simplifies some approaches shown in textbooks, based on asymptotic analyses of the TISE, and power series methods with recurrence relations. In addition, the method presented here facilitates the understanding of the relationship between the ordinary differential equations of the mathematical physics and the TISE of physical models as the harmonic oscillator, the Hydrogen atom, and the Morse oscillator.