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arXiv:quant-ph/9611052 · Journal of Mathematical Physics

Quantum canonical transformations and exact solution of the Schrödinger equation

Ali Mostafazadeh

Published Jul 1, 1997• 17 citations
arXivHTMLPDF

Abstract

Time-dependent unitary transformations are used to study the Schrödinger equation for explicitly time-dependent Hamiltonians of the form H(t)=R(t)⋅J, where R is an arbitrary real vector-valued function of time and J is the angular momentum operator. The solution of the Schrödinger equation for the most general Hamiltonian of this form is shown to be equivalent to the special case R=(1,0,ν(t)). This corresponds to the problem of a driven two-level atom for the spin half representation of J. It is also shown that by requiring the magnitude of R to depend on its direction in a particular way, one can solve the Schrödinger equation exactly. In particular, it is shown that for every Hamiltonian of the form H(t)=R(t)⋅J there is another Hamiltonian with the same eigenstates for which the Schrödinger equation is exactly solved. The application of the results to the exact solution of the parallel transport equation and exact holomony calculation for SU(2) principal bundles (Yang–Mills gauge theory) is also pointed out.

DOI
10.1063/1.531864

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Time-dependent unitary transformations are used to study the Schrödinger equation for explicitly time-dependent Hamiltonians of the form H(t)=R(t)⋅J, where R is an arbitrary real vector-valued function of time and J is the angular momentum operator. The solution of the Schrödinger equation for the most general Hamiltonian of this form is shown to be equivalent to the special case R=(1,0,ν(t)). This corresponds to the problem of a driven two-level atom for the spin half representation of J. It is also shown that by requiring the magnitude of R to depend on its direction in a particular way, one can solve the Schrödinger equation exactly. In particular, it is shown that for every Hamiltonian of the form H(t)=R(t)⋅J there is another Hamiltonian with the same eigenstates for which the Schrödinger equation is exactly solved. The application of the results to the exact solution of the parallel transport equation and exact holomony calculation for SU(2) principal bundles (Yang–Mills gauge theory) is also pointed out.
Solutions of the Schrödinger equation with an exact time dependence are derived as eigenfunctions of dynamical invariants which are constructed from time-independent operators using time-dependent unitary transformations. Exact solutions and a closed form expression for the corresponding time evolution operator are found for a wide range of time-dependent Hamiltonians in d dimensions, including non-Hermitean -symmetric Hamiltonians. Hamiltonians are constructed using time-dependent unitary spatial transformations comprising dilatations, translations and rotations and solutions are found in several forms: as eigenfunctions of a quadratic invariant, as coherent state eigenfunctions of boson operators, as plane wave solutions from which the general solution is obtained as an integral transform by means of the Fourier transform, and as distributional solutions for which the initial wavefunction is the Dirac δ-function. For the isotropic harmonic oscillator in d dimensions radial solutions are found which extend known results for d = 1, including Barut–Girardello and Perelomov coherent states (i.e., vector coherent states), which are shown to be related to eigenfunctions of the quadratic invariant by the ζ-transformation. This transformation, which leaves the Ermakov equation invariant, implements SU(1, 1) transformations on linear dynamical invariants. coherent states are derived also for the time-dependent linear potential. Exact solutions are found for Hamiltonians with electromagnetic interactions in which the time-dependent magnetic and electric fields are not necessarily spatially uniform. As an example, it is shown how to find exact solutions of the time-dependent Schrödinger equation for the Dirac magnetic monopole in the presence of time-dependent magnetic and electric fields of a specified form.
We find a relationship between unitary transformations of the dynamics of quantum systems with time-dependent Hamiltonians and gauge theories. In particular, we show that the nonrelativistic dynamics of spin-12\frac{1}{2}21​ particles in a magnetic field Bi(t){B}^{i}(t)Bi(t) can be formulated in a natural way as an SU(2) gauge theory, with the magnetic field Bi(t){B}^{i}(t)Bi(t) playing the role of the gauge potential Ai{A}^{i}Ai. The present approach can also be applied to systems of n levels with time-dependent potentials, U(n)U(n)U(n) being the gauge group. This geometric interpretation provides a powerful method to find exact solutions of the Schr\"odinger equation. The root of the present approach rests in the Hermiticity property of the Hamiltonian operators involved. In addition, the relationship with true gauge symmetries of n-level quantum systems is discussed.
Explicitly time-dependent Hamiltonians are ubiquitous in applications of quantum theory. It is therefore necessary to solve the time-dependent Schrödinger equation directly. The system’s dynamics is associated with a unitary time-evolution operator (a propagator), formally given as an infinite Dyson series. Time-dependent observables are invariant under unitary time-dependent transformations, where it is sometimes useful to transform the time-evolution from the states into the corresponding operators. This is carried out in part (in full) by transforming to the interaction (Heisenberg) picture. The corresponding equations of motion for the time-dependent operators are introduced. For quadratic potential energy functions, the time evolution of quantum expectation values coincides with the corresponding classical dynamics. This is demonstrated and analyzed in detail for Gaussian wave packets and a coherent state. Finally, we derive exact and approximate expressions for time-dependent transition probabilities and transition rates between quantum states. The validity of time-dependent perturbation theory is analyzed by comparison to exact dynamics.
Quantum canonical transformations corresponding to time-dependent diffeomorphisms of the configuration space are studied. A special class of these transformations which correspond to time-dependent dilatations is used to identify a previously unknown class of exactly solvable time-dependent harmonic oscillators. The Caldirola-Kanai oscillator belongs to this class. For a general time-dependent harmonic oscillator, it is shown that choosing the dilatation parameter to satisfy the classical equation of motion, one obtains the solution of the Schrödinger equation. A simple generalization of this result leads to the reduction of the Schrödinger equation to a second-order ordinary differential equation whose special case is the auxiliary equation of the Lewis-Riesenfeld invariant theory. The time-evolution operator is expressed in terms of a positive real solution of this equation in a closed form, and the time-dependent position and momentum operators are calculated.
Given a time-independent Hamiltonian H~\widetilde HH , one can construct a time-dependent Hamiltonian HtH_tHt​ by means of the gauge transformation Ht=UtH~Ut†−iUt∂tUt†H_t=U_t\kern1pt \widetilde H \kern1pt U^\dagger_t-i\kern1pt U_t\kern1pt\partial_t U_t^\daggerHt​=Ut​HUt†​−iUt​∂t​Ut†​ . Here UtU_tUt​ is the unitary transformation that relates the solutions of the corresponding Schrödinger equations. In the many-body case one is usually interested in Hamiltonians with few-body (often, at most two-body) interactions. We refer to such Hamiltonians as physical. We formulate sufficient conditions on UtU_tUt​ ensuring that HtH_tHt​ is physical as long as H~\widetilde HH is physical (and vice versa). This way we obtain a general method for finding pairs of physical Hamiltonians HtH_tHt​ and H~\widetilde HH such that the driven many-body dynamics governed by HtH_tHt​ can be reduced to the quench dynamics due to the time-independent H~\widetilde HH . We apply this method to a number of many-body systems. First we review the mapping of a spin system with isotropic Heisenberg interaction and arbitrary time-dependent magnetic field to a time-independent system without a magnetic field [F. Yan, L. Yang, and B. Li, Phys. Lett. A 251, 289–293; 259, 207–211 (1999)]. Then we demonstrate that essentially the same gauge transformation eliminates an arbitrary time-dependent magnetic field from a system of interacting fermions. Further, we apply the method to the quantum Ising spin system and a spin coupled to a bosonic environment. We also discuss a more general situation where H~=H~t\widetilde H = \widetilde H_tH=Ht​ is time-dependent but dynamically integrable.
The time-dependent Schrodinger for an atom in a radiation field has a very special form, at least within the dipole approximation: The time-dependence of the Hamiltonian is contained entirely in a c-number which appears as a factor in the interaction, V(t), of the atom with the radiation field. In the velocity gauge this factor is the vector potential, A(t), of the field — we have V(t)= − (e/µc)A (t) • p, where e, µ, and p are the charge, reduced mass, and canonical momentum (in the center of mass frame) of the electron — while in the length gauge this factor is the electric field vector F(t) — we have V(t) = –eF(t) • x, where x is the position coordinate. To our knowledge, this factorization property has not been fully exploited in previous approaches to solving the timedependent Schrodinger equation1. As we show here, in an application to multiphoton ionization of atomic hydrogen, it is an extremely useful property; and although at first sight it would seem to be a unique feature of the atom-radiation system, this is not so, for, as Solov’ev2 has pointed out, the time-dependent Schrödinger equation for colliding atoms or ions can be transformed into a form in which a scaled time-dependence also appears only in c-number factors of the (transformed) interactions.