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Journal of Physics A Mathematical and Theoretical

Exact time dependence of solutions to the time-dependent Schrödinger equation

Max A. Lohe

Published Dec 9, 2008• 65 citations
Publisher

Abstract

Solutions of the Schrödinger equation with an exact time dependence are derived as eigenfunctions of dynamical invariants which are constructed from time-independent operators using time-dependent unitary transformations. Exact solutions and a closed form expression for the corresponding time evolution operator are found for a wide range of time-dependent Hamiltonians in d dimensions, including non-Hermitean -symmetric Hamiltonians. Hamiltonians are constructed using time-dependent unitary spatial transformations comprising dilatations, translations and rotations and solutions are found in several forms: as eigenfunctions of a quadratic invariant, as coherent state eigenfunctions of boson operators, as plane wave solutions from which the general solution is obtained as an integral transform by means of the Fourier transform, and as distributional solutions for which the initial wavefunction is the Dirac δ-function. For the isotropic harmonic oscillator in d dimensions radial solutions are found which extend known results for d = 1, including Barut–Girardello and Perelomov coherent states (i.e., vector coherent states), which are shown to be related to eigenfunctions of the quadratic invariant by the ζ-transformation. This transformation, which leaves the Ermakov equation invariant, implements SU(1, 1) transformations on linear dynamical invariants. coherent states are derived also for the time-dependent linear potential. Exact solutions are found for Hamiltonians with electromagnetic interactions in which the time-dependent magnetic and electric fields are not necessarily spatially uniform. As an example, it is shown how to find exact solutions of the time-dependent Schrödinger equation for the Dirac magnetic monopole in the presence of time-dependent magnetic and electric fields of a specified form.

DOI
10.1088/1751-8113/42/3/035307

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Solutions of the Schrödinger equation with an exact time dependence are derived as eigenfunctions of dynamical invariants which are constructed from time-independent operators using time-dependent unitary transformations. Exact solutions and a closed form expression for the corresponding time evolution operator are found for a wide range of time-dependent Hamiltonians in d dimensions, including non-Hermitean -symmetric Hamiltonians. Hamiltonians are constructed using time-dependent unitary spatial transformations comprising dilatations, translations and rotations and solutions are found in several forms: as eigenfunctions of a quadratic invariant, as coherent state eigenfunctions of boson operators, as plane wave solutions from which the general solution is obtained as an integral transform by means of the Fourier transform, and as distributional solutions for which the initial wavefunction is the Dirac δ-function. For the isotropic harmonic oscillator in d dimensions radial solutions are found which extend known results for d = 1, including Barut–Girardello and Perelomov coherent states (i.e., vector coherent states), which are shown to be related to eigenfunctions of the quadratic invariant by the ζ-transformation. This transformation, which leaves the Ermakov equation invariant, implements SU(1, 1) transformations on linear dynamical invariants. coherent states are derived also for the time-dependent linear potential. Exact solutions are found for Hamiltonians with electromagnetic interactions in which the time-dependent magnetic and electric fields are not necessarily spatially uniform. As an example, it is shown how to find exact solutions of the time-dependent Schrödinger equation for the Dirac magnetic monopole in the presence of time-dependent magnetic and electric fields of a specified form.
The theory of explicitly time-dependent invariants is developed for quantum systems whose Hamiltonians are explicitly time dependent. The central feature of the discussion is the derivation of a simple relation between eigenstates of such an invariant and solutions of the Schrödinger equation. As a specific well-posed application of the general theory, the case of a general Hamiltonian which settles into constant operators in the sufficiently remote past and future is treated and, in particular, the transition amplitude connecting any initial state in the remote past to any final state in the remote future is calculated in terms of eigenstates of the invariant. Two special physical systems are treated in detail: an arbitrarily time-dependent harmonic oscillator and a charged particle moving in the classical, axially symmetric electromagnetic field consisting of an arbitrarily time-dependent, uniform magnetic field, the associated induced electric field, and the electric field due to an arbitrarily time-dependent uniform charge distribution. A class of explicitly time-dependent invariants is derived for both of these systems, and the eigenvalues and eigenstates of the invariants are calculated explicitly by operator methods. The explicit connection between these eigenstates and solutions of the Schrödinger equation is also calculated. The results for the oscillator are used to obtain explicit formulas for the transition amplitude. The usual sudden and adiabatic approximations are deduced as limiting cases of the exact formulas.
Explicitly time-dependent Hamiltonians are ubiquitous in applications of quantum theory. It is therefore necessary to solve the time-dependent Schrödinger equation directly. The system’s dynamics is associated with a unitary time-evolution operator (a propagator), formally given as an infinite Dyson series. Time-dependent observables are invariant under unitary time-dependent transformations, where it is sometimes useful to transform the time-evolution from the states into the corresponding operators. This is carried out in part (in full) by transforming to the interaction (Heisenberg) picture. The corresponding equations of motion for the time-dependent operators are introduced. For quadratic potential energy functions, the time evolution of quantum expectation values coincides with the corresponding classical dynamics. This is demonstrated and analyzed in detail for Gaussian wave packets and a coherent state. Finally, we derive exact and approximate expressions for time-dependent transition probabilities and transition rates between quantum states. The validity of time-dependent perturbation theory is analyzed by comparison to exact dynamics.
The one-dimensional Schrödinger equation associated with a time-dependent Coulomb potential is studied. The invariant operator method (Lewis and Riesenfeld) and unitary transformation approach are employed to derive quantum solutions of the system. We obtain an ordinary second-order differential equation whose analytical exact solution has been unknown. It is confirmed that the form of this equation is similar to the radial Schrödinger equation for the hydrogen atom in a (arbitrary) strong magnetic field. The qualitative properties for the eigenstates spectrum are described separately for the different values of the parameter ω 0 appearing in the x 2 term, x being the position, i.e., ω 0 > 0, ω 0 < 0 and ω 0 = 0. For the ω 0 = 0 case, the eigenvalue equation of invariant operator reduces to a solvable form and, consequently, we have provided exact eigenstates of the time-dependent Hamiltonian system.
The harmonic oscillator with a time-dependent frequency has a family of linear quantum invariants for the time-dependent Schrödinger equation, which are determined by any two independent solutions to the classical equation of motion. Ermakov and Pinney have shown that a general solution to the time-dependent oscillator with an inverse cubic term can be expressed in terms of two independent solutions to the time-dependent oscillator. We explore the connection between linear quantum invariants and the Ermakov-Pinney solution for the time-dependent harmonic oscillator. We advance a novel method to construct Ermakov-Pinney solutions to a class of time-dependent oscillators and the wave functions for the time-dependent Schrödinger equation. We further show that the first and the second Pöschl-Teller potentials belong to a special class of exact time-dependent oscillators. A perturbation method is proposed for any slowly-varying time-dependent frequency.