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Tunneling and energy splitting in an asymmetric double-well potential

Dae-Yup Song

Published Aug 4, 2013• 22 citations
OpenAlex

Abstract

An asymmetric double-well potential is considered, assuming that the minima of the wells are quadratic with a frequency ω and the difference of the minima is close to a multiple of �ω. A WKB wave function is constructed on both sides of the local maximum between the wells, by matching the WKB function to the exact wave functions near the classical turning points. The continuities of the wave function and its first derivative at the local maximum then give the energy-level splitting formula, which not only reproduces the instanton result for a symmetric potential, but also elucidates the appearance of resonances of tunneling in the asymmetric potential. Key words: quantum tunneling, energy splitting, double-well potential PACS: 03.65.Sq, 03.65.Ge, 82.20.Xr 1

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An asymmetric double-well potential is considered, assuming that the minima of the wells are quadratic with a frequency ω and the difference of the minima is close to a multiple of �ω. A WKB wave function is constructed on both sides of the local maximum between the wells, by matching the WKB function to the exact wave functions near the classical turning points. The continuities of the wave function and its first derivative at the local maximum then give the energy-level splitting formula, which not only reproduces the instanton result for a symmetric potential, but also elucidates the appearance of resonances of tunneling in the asymmetric potential. Key words: quantum tunneling, energy splitting, double-well potential PACS: 03.65.Sq, 03.65.Ge, 82.20.Xr 1
The accuracy of the WKB approximation when predicting the energy splitting of bound states in a double well potential is the main subject of this paper. The splitting of almost degenerate energy levels below the top of the barrier results from the tunneling and is thus supposed to be exponentially small. By using the standard WKB quantization we deduce an analytical formula for the energy splitting, which is the usual Landau formula with additional quantum corrections. We also examine the accuracy of our and Landau formula numerically for the case of the symmetric double well quartic potential.