We investigate collective behaviour that appears in open, many-body systems of two- and four-level atoms. Here, ``open" refers to the system interacting with an external environment that causes dissipation. We derive a general open quantum master equation to describe the system dynamics only, independent of this environment. We identify processes such as coherent exchange of virtual photons and modified decay rates caused by long-range interactions between all pairs of atoms that scale with distance by inverse power laws. We explore excitation transport within a one-dimensional chain of atoms where the atomic transition dipoles are coupled to the free radiation field. When the interatomic spacing is smaller than or comparable to the wavelength of light associated with the photon emitted from a given transition, virtual photon exchange interactions facilitate excitation transport through the chain. Atomic systems coupled to an environment display dissipative dynamics, however subradiant transport is exhibited from a variety of initial states; spontaneous emission from the chain occurs at a rate much slower than that for an individual atom. In particular, we find a region within the decay spectrum that consists entirely of subradiant states with a corresponding linear dispersion relation in the interaction energy. Identifying this subspace allows for the dispersionless transport of wave packets over long distances with near-zero decay. Moreover, the group velocity of the wave packet and direction of the transport can be controlled via an external uniform magnetic field while preserving its subradiant character. We discuss a number of experimental considerations to justify the feasibility and robustness of this protocol. Initial state preparation is outlined, utilising external laser driving to excite the system into the single excitation sector. Furthermore, we consider positional disorder by explicitly accounting for the external atomic degrees of freedom -- position and momentum -- which allows us to model the positions of all atoms by a motional state representing the occupation of a lattice well with a given width. These discussions are made in the low-temperature limit, where the atomic motion is essentially frozen, and we identify that subradiant transport is indeed robust. Finally, we explore the experimental limits of interatomic spacing and imperfect filling within an experimentally achievable optical lattice. We calculate the photon emission rate -- an experimentally measurable quantity -- and compare the emission spectra to our analysis. By limiting parameters to those achieved experimentally, we observe a reduction, yet not an absence, of collective behaviour. The simplicity and versatility of this system, together with the robustness of subradiance against disorder, makes it relevant for a range of applications such as lossless energy transport and long-time light storage. The lifetime of an atomic excitation could be increased by a factor of thousands to millions for a chain of atoms under the conditions that we explore in this thesis.
We investigate collective behaviour that appears in open, many-body systems of two- and four-level atoms. Here, ``open" refers to the system interacting with an external environment that causes dissipation. We derive a general open quantum master equation to describe the system dynamics only, independent of this environment. We identify processes such as coherent exchange of virtual photons and modified decay rates caused by long-range interactions between all pairs of atoms that scale with distance by inverse power laws. We explore excitation transport within a one-dimensional chain of atoms where the atomic transition dipoles are coupled to the free radiation field. When the interatomic spacing is smaller than or comparable to the wavelength of light associated with the photon emitted from a given transition, virtual photon exchange interactions facilitate excitation transport through the chain. Atomic systems coupled to an environment display dissipative dynamics, however subradiant transport is exhibited from a variety of initial states; spontaneous emission from the chain occurs at a rate much slower than that for an individual atom. In particular, we find a region within the decay spectrum that consists entirely of subradiant states with a corresponding linear dispersion relation in the interaction energy. Identifying this subspace allows for the dispersionless transport of wave packets over long distances with near-zero decay. Moreover, the group velocity of the wave packet and direction of the transport can be controlled via an external uniform magnetic field while preserving its subradiant character. We discuss a number of experimental considerations to justify the feasibility and robustness of this protocol. Initial state preparation is outlined, utilising external laser driving to excite the system into the single excitation sector. Furthermore, we consider positional disorder by explicitly accounting for the external atomic degrees of freedom -- position and momentum -- which allows us to model the positions of all atoms by a motional state representing the occupation of a lattice well with a given width. These discussions are made in the low-temperature limit, where the atomic motion is essentially frozen, and we identify that subradiant transport is indeed robust. Finally, we explore the experimental limits of interatomic spacing and imperfect filling within an experimentally achievable optical lattice. We calculate the photon emission rate -- an experimentally measurable quantity -- and compare the emission spectra to our analysis. By limiting parameters to those achieved experimentally, we observe a reduction, yet not an absence, of collective behaviour. The simplicity and versatility of this system, together with the robustness of subradiance against disorder, makes it relevant for a range of applications such as lossless energy transport and long-time light storage. The lifetime of an atomic excitation could be increased by a factor of thousands to millions for a chain of atoms under the conditions that we explore in this thesis.
Abstract We explore excitation transport within a one-dimensional chain of atoms where the atomic transition dipoles are coupled to the free radiation field. When the atoms are separated by distances smaller or comparable to the wavelength of the transition, the exchange of virtual photons leads to the transport of the excitation through the lattice. Even though this is a strongly dissipative system, we find that the transport is subradiant, that is, the excitation lifetime is orders of magnitude longer than the one of an individual atom. In particular, we show that a subspace of the spectrum is formed by subradiant states with a linear dispersion relation, which allows for the dispersionless transport of wave packets over long distances with virtually zero decay rate. Moreover, the group velocity and direction of the transport can be controlled via an external uniform magnetic field while preserving its subradiant character. The simplicity and versatility of this system, together with the robustness of subradiance against disorder, makes it relevant for a range of applications such as lossless energy transport and long-time light storage.
The objective of this thesis is to expand our understanding of collective light-scattering phenomena, which manifest themselves in the strong suppression of radiation from the scattering medium. In particular, we are interested in subradiance, a collective effect in spontaneous emission which, as a result of the dissipative coupling of atoms through common electromagnetic modes, creates long-lived excitation modes in an ensemble of cold atoms, with lifetimes much longer than those of individual, isolated atoms. Previously, subradiance had been well-characterized for dilute cold-atom scattering media and the low-intensity limit of the driving laser (linear-optics regime). In this thesis, we study this collective phenomenon beyond the linear-optics and dilute regimes.To study experimentally subradiance beyond the linear-optics regime, we varied the saturation parameter of the excitation laser up to relatively large values and we have observed the increase of the subradiant population with increasing saturation parameter. More importantly, we have identified the super-linear scaling of the subradiant population beyond the linear-optics regime, due to a process similar to optical pumping via multi-excitation superradiant states. This study showed that the increase in the intensity of the driving laser beyond the linear-optics regime can overcome the weak coupling of subradiant modes with the external world.Moreover, we have numerically studied subradiance using the vectorial coupled-dipole model, with a focus on understanding the effect of the near-field dipole-dipole interaction. For that, we extensively compared the vectorial and scalar (which does not contain near-field interaction terms) models and studied the subradiant lifetime as a function of the density and optical thickness of the cold-atom cloud. We observed that the near-field terms are detrimental for subradiance, which was seen in the reduction of the subradiant lifetimes with increasing density. This detrimental character of near-field terms can be interpreted as being due to an effective inhomogeneous broadening induced by the near-field interaction, which reduces the subradiant lifetimes as the density increases.The detrimental character of near-field interaction has also been previously numerically identified for Anderson localization of light waves (Anderson localization is a coherent multiple-scattering wave phenomenon in a strongly scattering medium that results in a cessation of a diffusive wave transport; it also yields long-lived modes): the scalar coupled-dipole model predicts Anderson localization of light waves, but not the vectorial one. However, adding a strong magnetic field allows one to recover localized modes for vectorial light. In this context, we numerically studied a possible signature of Anderson localization of light in cold atoms, based on the measurement of intensity fluctuations of the scattered light. We have shown that at the transition to the localized regime, the fluctuations are enhanced. In particular, for vectorial light, we have demonstrated the absence and recovery of enhanced intensity fluctuations without and with the applied magnetic field, which further corroborates that the intensity fluctuations could serve as an experimental way to probe the localized states.
The interaction between light and matter has captivated physicists for centuries, from early studies of vision and refraction in ancient Greece to the development of quantum mechanics and quantum electrodynamics in the past century. While the response of a single quantum emitter to light is well understood, the radiative properties of an ensemble of closely spaced emitters are far more intricate. Coupling to a shared electromagnetic environment induces coherent and dissipative interactions between emitters, giving rise to a collective response that cannot be captured by treating them independently. In the regime of few excitations, the system hosts delocalized subradiant states, that is, coherent superpositions that are largely decoupled from the electromagnetic field and thus decay at suppressed rates. While this weak coupling makes subradiant states attractive for quantum technologies, it also renders them difficult to manipulate. At higher excitation densities, the intrinsic nonlinearity of emitters and the exponential growth of the Hilbert space make theoretical and numerical descriptions of the system and its dynamics increasingly challenging. This thesis explores two fundamental questions: How can subradiant and dark states be selectively accessed and harnessed for practical applications in quantum technologies? And how can interacting ensembles of quantum emitters be efficiently simulated to uncover their many-body physics? The first part of the thesis develops protocols for controlling and addressing dark states in free-space and waveguide-coupled atomic arrays, demonstrating their utility in quantum storage and the deterministic generation of entangled photonic states. Incorporating atomic motion, we further show that collective subradiant states can enhance cooling in dense atomic arrays, offering new avenues for controlling motional dynamics. In the second part, we introduce cumulant expansions of the equations of motion as a powerful tool to analytically and numerically investigate collective decay in the many-body regime. We first examine the collective decay of fully excited atomic arrays in free space, characterizing the onset and scaling of the superradiant burst across different geometries. In collaboration with experiments on ultracold erbium atoms in optical lattices, we provide the first direct observations of many-body collective effects in free-space ordered arrays, including early-time superradiant bursts, late-time subradiant tails, and the emergence of atomic correlations throughout the dynamics. Finally, we theoretically and numerically explore the transient formation of multi-excitation subradiant states, and demonstrate how the existence of multiple dissipation channels suppresses steady-state superradiance in extended arrays.
In contrast to free space, in waveguides the dispersive and dissipative dipole–dipole interactions among quantum emitters exhibit a periodic behavior over remarkably long distances. We propose a novel setup, to our knowledge, exploiting this long-range periodicity in order to create highly excited subradiant states and facilitate fast controlled collective energy transport among far-apart ensembles coupled to a waveguide. For sufficiently large ensembles, collective superradiant emission into the fiber modes dominates over its free space counterpart. We show that, for a large number of emitters, a fast transverse coherent pulse can create almost perfect subradiant states with up to 50% excitation. On the other hand, for a coherent excitation of one sub-ensemble above an overall excitation fraction of 50% we find a nearly lossless and fast energy transfer to the ground state sub-ensemble. This transport can be enhanced or suppressed by controlling the positions of the ensembles relative to each other, while it can also be realized with a random position distribution. In the optimally enhanced case this fast transfer appears as superradiant emission with subsequent superabsorption, yet, without a superradiant decay after the absorption. The highly excited subradiant states, as well as the superradiant excitation transfer, appear as suitable building blocks in applications such as active atomic clocks, quantum batteries, quantum information protocols, and quantum metrology procedures such as fiber-based Ramsey schemes.
Atomic arrays can exhibit collective light emission when the transition wavelength exceeds their lattice spacing. Subradiant states take advantage of this phenomenon to drastically reduce their overall decay rate, allowing for long-lived states in dissipative open systems. We build on previous work to investigate whether or not disorder can further decrease the decay rate of a singly excited atomic array. More specifically, we consider spatial disorder of varying strengths in a one-dimensional (1D) half waveguide and in 1D, two-dimensional (2D), and three-dimensional (3D) atomic arrays in free space and analyze the effect on the most subradiant modes. While we confirm that the dilute half waveguide exhibits an analog of Anderson localization, the dense half waveguide and free-space systems can be understood through the creation of close-packed, few-body subradiant states similar to those found in the Dicke limit. In general, we find that disorder provides little advantage in generating darker subradiant states in free space on average and will often accelerate decay. However, one could potentially change interatomic spacing within the array to engineer specific subradiant states.
Microscopic models based on multilevel atoms are central to optimizing nonlinear optical responses and the coherent control of light. These models are traditionally based on single-atom effects that are parametrically extrapolated to include collective effects, such as an enhanced response or propagation within atomic media. In this work, we present a systematic analysis of the cooperative effects arising in driven systems composed of multilevel atoms coupled via a common electromagnetic environment. The analysis is based on an interplay between dressed states induced by the driving field and photon exchanges, and collective decay channels. This theory is applied to the case of four-wave mixing induced by a pair of lasers acting on an atomic pair with internal levels in the diamond configuration. The effect of interatomic correlations and collective decay over the photons created in this nonlinear process is then explored. We identify three regions of operation: (i) laser-dominated, (ii) intermediate, and (iii) dipole-dominated. The dependence of single- and two-photon correlations is studied in detail for each region by varying atomic orientations and laser parameters consistent with current experiments involving atomic gases. Photonic correlation functions are shown to exhibit a transition from a Lorentz-like dependence on the two-photon detuning—with general features that can be obtained in an isolated atom scheme—to a two-peaked distribution when the dipole-dipole interactions become relevant. For weak Rabi frequencies whose value is smaller than the highest collective decay rate, the atoms are trapped inside their ground state as they approach each other. It is found that the anisotropy of the dipole-dipole interaction and its wave nature are essential to understand the behavior of the photon correlations. Signatures of these processes are identified for existing experimental realizations. The intuition obtained from this connection helps to uncover relevant parameters that could be exploited for quantum control protocols based on dispersive and dissipative cooperative effects in multilevel systems.