We consider the spin-1/2 Heisenberg chain with alternating spin exchange in the presence of additional modulation of exchange on odd bonds with period 3. We study the ground state magnetic phase diagram of this hexamer spin chain in the limit of very strong antiferromagnetic (AF) exchange on odd bonds using the numerical Lanczos method and bosonization approach. In the limit of strong magnetic field commensurate with the dominating AF exchange, the model is mapped onto an effective XXZ Heisenberg chain in the presence of uniform and spatially modulated fields, which is studied using the standard continuum-limit bosonization approach. In the absence of additional hexamer modulation, the model undergoes a quantum phase transition from a gapped phase into the only one gapless Lüttinger liquid (LL) phase by increasing the magnetic field. In the presence of hexamer modulation, two new gapped phases are identified in the ground state at magnetization equal to [Formula: see text] and [Formula: see text] of the saturation value. These phases reveal themselves also in the magnetization curve as plateaus at corresponding values of magnetization. As a result, the magnetic phase diagram of the hexamer chain shows seven different quantum phases, four gapped and three gapless, and the system is characterized by six critical fields which mark quantum phase transitions between the ordered gapped and the LL gapless phases.
We investigate the entanglement entropy (EE) of gapped S=1 and
S=1/2 spin chains with dimerization. We find that the effective boundary degrees of freedom as edge states contribute significantly to the EE. For the
S=1/2 dimerized Heisenberg chain, the EE of the sufficiently long chain is essentially explained by the localized
S=1/2 effective spins on the boundaries. As for S=1, the effective spins are also
S=1/2 causing a Kennedy triplet that yields a lower bound for the EE. In this case, the residual entanglement reduces substantially by a continuous deformation of the Heisenberg model to that of the AKLT Hamiltonian.