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A New Method of Measuring the Lifetimes of Excited States of Atoms

R. W. P. McWhirter

Published Jan 1, 1960• 0 citations
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Edward S. Fry, W. Williams

The oscillator strength for the resonance ($1^{1}S\ensuremath{-}2^{1}P$) transition in atomic helium has been determined from a measurement of the lifetime of the $2^{1}P$ state. This lifetime was obtained using a modified zero-field level crossing (Hanle) method. The scattering sample was a thermal velocity beam of $2^{1}S$ metastable atoms. Resonant 2-\ensuremath{\mu} ($2^{1}S\ensuremath{-}2^{1}P$) radiation is absorbed by the $2^{1}S$ atoms, which are excited to the $2^{1}P$ state. This state then primarily decays to the ground $1^{1}S$ state with the emission of resonance (584 \AA{}) radiation. The lifetime of the $2^{1}P$ state was determined from measurements of the magnetic-field dependence of the angular distribution of the 584 \AA{} intensity. This new technique eliminates the problem of constructing a vacuum ultraviolet resonance lamp. The measured lifetime $\ensuremath{\tau} (2^{1}P)$ is (5.63 \ifmmode\pm\else\textpm\fi{} 0.22) \ifmmode\times\else\texttimes\fi{} ${10}^{\ensuremath{-}10}$ sec. The resulting absorption oscillator strength for the resonance transition is 0.273 \ifmmode\pm\else\textpm\fi{} 0.011. This oscillator strength agrees with the theoretical value.

Physical Review•Jul 5, 1969•14 citations
We report resolution of the 1% discrepancy between theory and experiment for the lifetime of the first excited state of Na. Determining the atomic lifetime by a novel method, we have measured the natural linewidth of the $3{}^{2}{S}_{1/2}\ensuremath{\rightarrow}3{}^{2}{P}_{3/2}$ transition with <0.25<0.25%<0.25 accuracy through precision spectroscopy on an optically prepared sample of ultracold, two-level atoms. The resulting 32P3/23{}^{2}{P}_{3/2}32P3/2​ lifetime of 16.237(35) ns disagrees with previous time-domain measurements but is in good agreement with recent calculations and a new fast beam result.
The oscillator strength for the resonance ($1^{1}S\ensuremath{-}2^{1}P$) transition in atomic helium has been determined from a measurement of the lifetime of the 21P2^{1}P21P state. This lifetime was obtained using a modified zero-field level crossing (Hanle) method. The scattering sample was a thermal velocity beam of 21S2^{1}S21S metastable atoms. Resonant 2-\ensuremath{\mu} ($2^{1}S\ensuremath{-}2^{1}P$) radiation is absorbed by the 21S2^{1}S21S atoms, which are excited to the 21P2^{1}P21P state. This state then primarily decays to the ground 11S1^{1}S11S state with the emission of resonance (584 \AA{}) radiation. The lifetime of the 21P2^{1}P21P state was determined from measurements of the magnetic-field dependence of the angular distribution of the 584 \AA{} intensity. This new technique eliminates the problem of constructing a vacuum ultraviolet resonance lamp. The measured lifetime $\ensuremath{\tau} (2^{1}P)$ is (5.63 \ifmmode\pm\else\textpm\fi{} 0.22) \ifmmode\times\else\texttimes\fi{} ${10}^{\ensuremath{-}10}$ sec. The resulting absorption oscillator strength for the resonance transition is 0.273 \ifmmode\pm\else\textpm\fi{} 0.011. This oscillator strength agrees with the theoretical value.