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Chaos and quantum-classical correspondence for two- coupled spins

Joseph Emerson

Published Jan 1, 2001• 1 citation
OpenAlex

Abstract

Two approaches to quantum-classical correspondence are distinguished according to the classical dynamical theory with which quantum theory is compared. The first of these, Ehrenfest correspondence, defines a dynamical regime in which the quantum expectation values follow approximately a classical trajectory. The second of these, Liouville correspondence, applies when the quantum probability distributions remain well approximated by a density in the classical phase space. The former applies only for narrow states, whereas the latter may remain valid even for quantum states that have spread to the system size. A spin model is adopted for this correspondence study because the quantum state is discrete and finite- dimensional, and thus no artificial truncation of the Hilbert space is required. The quantum time-evolution is given by a discrete unitary mapping. The corresponding classical model is volume-preserving (non-dissipative) and the time-evolution is given by a symplectic map. In classically chaotic regimes, the widths of initially narrow quantum states grow, on average, exponentially with time, until saturation at the system size. This initial spreading rate is well approximated by the classical Lyapunov exponent when the accessible classical phase space is predominantly chaotic. Because of the exponential growth rate of the quantum variance, the Ehrenfest regime is delimited by a break-time that grows logarithmically with increasing quantum numbers. The small differences between quantum expectation values and corresponding Liouville averages of dynamical variables also grow exponentially, initially, if the classical behaviour is chaotic. This exponential rate is independent of h and consistently larger than the classical Lyapunov exponent by at least a factor of two. Interestingly, this exponential growth rate does not continue until these differences approach magnitudes of order the system size, but crosses over to power-law growth (or simply saturates), when the differences have reached magnitudes no larger than order ħ. Because of the exponential growth of these quantum-classical differences, the Liouville regime is also delimited by a break-time that grows logarithmically with increasing quantum numbers. However, due to the early saturation of the exponential growth of the differences, the Liouville log break-time applies only in a restricted domain. After spreading to the system size, the quantum states relax to an approximately time-independent state. This is characterised by equilibrium distributions that are subject to rapidly oscillating fluctuations about the coarse-grained classical steady-state. If the accessible classical phase space is predominantly chaotic, then the equilibrium quantum probability distributions are nearly microcanonical. Otherwise the steady-state quantum probability distributions accurately reflect the details of the KAM surfaces in the classical phase space. The equilibrium regime quantum fluctuations, which are quantum-classical differences, are shown to approach zero as a negative power of the quantum numbers. Since the differences between quantum expectation values and individual classical trajectories grow exponentially in time to a magnitude that scales with the system size, the Ehrenfest regime is delimited by an unrestricted log break-time. The log break-time may be short compared to experimental time-scales for some chaotic macroscopic bodies, and, as a result, an observable breakdown of Ehrenfest correspondence may arise for some macroscopic systems. Although the Liouville regime is also delimited by a log break-time, an observable breakdown of correspondence between quantum mechanics and Liouville mechanics for macroscopic bodies is not likely since their differences, expressed relative to the dimensions of the observable, approach zero in the limit of large quantum numbers.

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Making use of appropriate quantum-classical correspondence we have examined the differential behavior of regular and chaotic trajectories in terms of quantum decoherence, the evolution of average quantities, and variances and entropy in a driven double-well oscillator in contact with the surroundings. Our numerical analysis has shown that even on a short time scale the decay of the average quantum coherence is multiexponential. While the onset of decoherence is much faster for a regular trajectory, the decay is faster asymptotically for a chaotic trajectory compared to a regular one. The coupling of the system to the environment turns chaotic in a regular evolution. The environment also affects the evolution of quantum variances for a regular trajectory almost from the beginning, while it has an insignificant effect on chaotic evolution up to a time after which, for both trajectories, noise in the quantum variances exhibits remarkable suppression, although fluctuations of the reservoir modes, in general, tend to increase the level of variances. We identify three stages of quantum evolution; a short decoherence regime followed by a Liouville flow, the latter regime being dominated by the classical curvature of the potential. This is the regime at which growth of entropy or quantum variances is exponential, the rate being determined by the classical largest Lyapunov exponent. The last stage is the irreversible flow dominated by diffusion which suppresses noises in the quantum variances. \textcopyright{} 1996 The American Physical Society.

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The threshold for quantum-classical correspondence is $D \sim \hbar^{\frac43}$

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In chaotic quantum systems, an initially localized quantum state can deviate strongly from the corresponding classical phase-space distribution after the Ehrenfest time $t_{\mathrm{E}} \sim \log(\hbar^{-1})$, even in the limit $\hbar \to 0$. Decoherence by the environment is often invoked to explain the persistence of the quantum-classical correspondence at longer timescales. Recent rigorous results for Lindblad dynamics with phase-space diffusion strength $D$ show that quantum and classical evolutions remain close for times that are exponentially longer than the Ehrenfest time whenever $D \gg \hbar^{\frac43}$, in units set by the classical Hamiltonian. At the same time, some heuristic arguments have suggested the weaker condition $D \gg \hbar^{2}$ always suffices. Here we construct an explicit Lindbladian that demonstrates that the scaling $D \sim \hbar^{\frac43}$ is indeed the threshold for quantum-classical correspondence beyond the Ehrenfest time. Our example uses a smooth time-dependent Hamiltonian and linear Lindblad operators generating homogeneous isotropic diffusion. It exhibits an $\hbar$-independent quantum-classical discrepancy at the Ehrenfest time whenever $D \ll \hbar^{\frac43}$, even for $\hbar$-independent "macroscopic" smooth observables.

quant-pharXiv:2512.17623•Dec 22, 2025•0 citations
Two approaches to quantum-classical correspondence are distinguished according to the classical dynamical theory with which quantum theory is compared. The first of these, Ehrenfest correspondence, defines a dynamical regime in which the quantum expectation values follow approximately a classical trajectory. The second of these, Liouville correspondence, applies when the quantum probability distributions remain well approximated by a density in the classical phase space. The former applies only for narrow states, whereas the latter may remain valid even for quantum states that have spread to the system size. A spin model is adopted for this correspondence study because the quantum state is discrete and finite- dimensional, and thus no artificial truncation of the Hilbert space is required. The quantum time-evolution is given by a discrete unitary mapping. The corresponding classical model is volume-preserving (non-dissipative) and the time-evolution is given by a symplectic map. In classically chaotic regimes, the widths of initially narrow quantum states grow, on average, exponentially with time, until saturation at the system size. This initial spreading rate is well approximated by the classical Lyapunov exponent when the accessible classical phase space is predominantly chaotic. Because of the exponential growth rate of the quantum variance, the Ehrenfest regime is delimited by a break-time that grows logarithmically with increasing quantum numbers. The small differences between quantum expectation values and corresponding Liouville averages of dynamical variables also grow exponentially, initially, if the classical behaviour is chaotic. This exponential rate is independent of h and consistently larger than the classical Lyapunov exponent by at least a factor of two. Interestingly, this exponential growth rate does not continue until these differences approach magnitudes of order the system size, but crosses over to power-law growth (or simply saturates), when the differences have reached magnitudes no larger than order ħ. Because of the exponential growth of these quantum-classical differences, the Liouville regime is also delimited by a break-time that grows logarithmically with increasing quantum numbers. However, due to the early saturation of the exponential growth of the differences, the Liouville log break-time applies only in a restricted domain. After spreading to the system size, the quantum states relax to an approximately time-independent state. This is characterised by equilibrium distributions that are subject to rapidly oscillating fluctuations about the coarse-grained classical steady-state. If the accessible classical phase space is predominantly chaotic, then the equilibrium quantum probability distributions are nearly microcanonical. Otherwise the steady-state quantum probability distributions accurately reflect the details of the KAM surfaces in the classical phase space. The equilibrium regime quantum fluctuations, which are quantum-classical differences, are shown to approach zero as a negative power of the quantum numbers. Since the differences between quantum expectation values and individual classical trajectories grow exponentially in time to a magnitude that scales with the system size, the Ehrenfest regime is delimited by an unrestricted log break-time. The log break-time may be short compared to experimental time-scales for some chaotic macroscopic bodies, and, as a result, an observable breakdown of Ehrenfest correspondence may arise for some macroscopic systems. Although the Liouville regime is also delimited by a log break-time, an observable breakdown of correspondence between quantum mechanics and Liouville mechanics for macroscopic bodies is not likely since their differences, expressed relative to the dimensions of the observable, approach zero in the limit of large quantum numbers.
The conditions of quantum-classical correspondence for a system of two interacting spins are investigated. Differences between quantum expectation values and classical Liouville averages are examined for both regular and chaotic dynamics well beyond the short-time regime of narrow states. We find that quantum-classical differences initially grow exponentially with a characteristic exponent consistently larger than the largest Lyapunov exponent. We provide numerical evidence that the time of the break between the quantum and classical predictions scales as $\mathrm{log}(\mathcal{J}/\ensuremath{\Elzxh}),$ where J\mathcal{J}J is a characteristic system action. However, this logarithmic break-time rule applies only while the quantum-classical deviations are smaller than $O(\ensuremath{\Elzxh}).$ We find that the quantum observables remain well approximated by classical Liouville averages over long times even for the chaotic motions of a few degree-of-freedom system. To obtain this correspondence it is not necessary to introduce the decoherence effects of a many degree-of-freedom environment.
We consider the quantum and classical Liouville dynamics of a nonintegrable model of two coupled spins. Initially localized quantum states spread exponentially to the system size when the classical dynamics are chaotic. The long-time behavior of the quantum probability distributions and, in particular, the parameter-dependent rates of relaxation to the equilibrium state are surprisingly well approximated by the classical Liouville mechanics even for small quantum numbers. As the accessible classical phase space becomes predominantly chaotic, the classical and quantum probability equilibrium configurations approach the microcanonical distribution, although the quantum equilibrium distributions exhibit characteristic "minimum" fluctuations away from the microcanonical state. The magnitudes of the quantum-classical differences arising from the equilibrium quantum fluctuations are studied for both pure and mixed (dynamically entangled) quantum states. In both cases the standard deviation of these fluctuations decreases as (h/J)(1/2), where J is a measure of the system size. In conclusion, under a variety of conditions the differences between quantum and classical Liouville mechanics are shown to become vanishingly small in the classical limit (J/h-->infinity) of a nondissipative model endowed with only a few degrees of freedom.
The quantum dynamics of a classically chaotic model are studied in the approach to the macroscopic limit. The quantum predictions are compared and contrasted with the classical predictions of both Newtonian and Liouville mechanics. The time-domain scaling of the optimal quantum-classical correspondence is analyzed in detail in the case of both classical theories. In both cases the correspondence for observable quantities is shown to break down on a time-scale that increases very slowly (logarithmically) with increasing system size. In the case of quantum-Liouville correspondence such a short time-scale does not imply a breakdown of correspondence since the largest quantum-Liouville differences reached on this time-scale decrease rapidly (as an inverse power) with increasing system size. Therefore the statistical properties of chaotic dynamics are, as expected, well described by quantum theory in the macroscopic limit. In contrast, the largest quantum-Newtonian differences reached on the log time-scale actually increase in proportion to the system size. Since the invariance properties of the Hamiltonian impose functional constraints on the time-varying chaotic coordinates, it is possible to show, moreover, that if the quantum predictions are believed to describe the coordinates of individual chaotic systems, then they also predict macroscopic violations of any kinematic or dynamic constants of the motion. These results for chaotic systems indicate that a valid description of the time-varying properties of individual macroscopic bodies is not available within the standard interpretive framework of quantum theory.
Making use of appropriate quantum-classical correspondence we have examined the differential behavior of regular and chaotic trajectories in terms of quantum decoherence, the evolution of average quantities, and variances and entropy in a driven double-well oscillator in contact with the surroundings. Our numerical analysis has shown that even on a short time scale the decay of the average quantum coherence is multiexponential. While the onset of decoherence is much faster for a regular trajectory, the decay is faster asymptotically for a chaotic trajectory compared to a regular one. The coupling of the system to the environment turns chaotic in a regular evolution. The environment also affects the evolution of quantum variances for a regular trajectory almost from the beginning, while it has an insignificant effect on chaotic evolution up to a time after which, for both trajectories, noise in the quantum variances exhibits remarkable suppression, although fluctuations of the reservoir modes, in general, tend to increase the level of variances. We identify three stages of quantum evolution; a short decoherence regime followed by a Liouville flow, the latter regime being dominated by the classical curvature of the potential. This is the regime at which growth of entropy or quantum variances is exponential, the rate being determined by the classical largest Lyapunov exponent. The last stage is the irreversible flow dominated by diffusion which suppresses noises in the quantum variances. \textcopyright{} 1996 The American Physical Society.
The equations of motion for phase-space moments and correlations are derived systematically for quantum and classical dynamics, and are solved numerically for chaotic and regular motions of the H\'enon-Heiles model. For very narrow probability distributions, Ehrenfest's theorem implies that the centroid of the quantum state will approximately follow a classical trajectory. But the error in Ehrenfest's theorem does not scale with $\ensuremath{\Elzxh},$ and is found to be governed essentially by classical quantities. The difference between the centroids of the quantum and classical probability distributions, and the difference between the variances of those distributions, scale as ${\ensuremath{\Elzxh}}^{2},$ and so are the true measures of quantum effects. For chaotic motions, these differences between quantum and classical motions grow exponentially, with a larger exponent than does the variance of the distributions. For regular motions, the variance of the distributions grows as t2,{t}^{2},t2, whereas the differences between the quantum and classical motions grow as t3.{t}^{3}.t3.
The threshold for quantum-classical correspondence is D∼ℏ43D \sim \hbar^{\frac43}D∼ℏ34​
In chaotic quantum systems, an initially localized quantum state can deviate strongly from the corresponding classical phase-space distribution after the Ehrenfest time tE∼log⁡(ℏ−1)t_{\mathrm{E}} \sim \log(\hbar^{-1})tE​∼log(ℏ−1), even in the limit ℏ→0\hbar \to 0ℏ→0. Decoherence by the environment is often invoked to explain the persistence of the quantum-classical correspondence at longer timescales. Recent rigorous results for Lindblad dynamics with phase-space diffusion strength DDD show that quantum and classical evolutions remain close for times that are exponentially longer than the Ehrenfest time whenever D≫ℏ43D \gg \hbar^{\frac43}D≫ℏ34​, in units set by the classical Hamiltonian. At the same time, some heuristic arguments have suggested the weaker condition D≫ℏ2D \gg \hbar^{2}D≫ℏ2 always suffices. Here we construct an explicit Lindbladian that demonstrates that the scaling D∼ℏ43D \sim \hbar^{\frac43}D∼ℏ34​ is indeed the threshold for quantum-classical correspondence beyond the Ehrenfest time. Our example uses a smooth time-dependent Hamiltonian and linear Lindblad operators generating homogeneous isotropic diffusion. It exhibits an ℏ\hbarℏ-independent quantum-classical discrepancy at the Ehrenfest time whenever D≪ℏ43D \ll \hbar^{\frac43}D≪ℏ34​, even for ℏ\hbarℏ-independent "macroscopic" smooth observables.