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arXiv:quant-ph/0103050 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Quantum-classical correspondence for the equilibrium distributions of two interacting spins

Joseph Emerson, L. E. Ballentine

Published Jul 20, 2001• 26 citations
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Abstract

We consider the quantum and classical Liouville dynamics of a nonintegrable model of two coupled spins. Initially localized quantum states spread exponentially to the system size when the classical dynamics are chaotic. The long-time behavior of the quantum probability distributions and, in particular, the parameter-dependent rates of relaxation to the equilibrium state are surprisingly well approximated by the classical Liouville mechanics even for small quantum numbers. As the accessible classical phase space becomes predominantly chaotic, the classical and quantum probability equilibrium configurations approach the microcanonical distribution, although the quantum equilibrium distributions exhibit characteristic "minimum" fluctuations away from the microcanonical state. The magnitudes of the quantum-classical differences arising from the equilibrium quantum fluctuations are studied for both pure and mixed (dynamically entangled) quantum states. In both cases the standard deviation of these fluctuations decreases as (h/J)(1/2), where J is a measure of the system size. In conclusion, under a variety of conditions the differences between quantum and classical Liouville mechanics are shown to become vanishingly small in the classical limit (J/h-->infinity) of a nondissipative model endowed with only a few degrees of freedom.

DOI
10.1103/physreve.64.026217

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We consider the quantum and classical Liouville dynamics of a nonintegrable model of two coupled spins. Initially localized quantum states spread exponentially to the system size when the classical dynamics are chaotic. The long-time behavior of the quantum probability distributions and, in particular, the parameter-dependent rates of relaxation to the equilibrium state are surprisingly well approximated by the classical Liouville mechanics even for small quantum numbers. As the accessible classical phase space becomes predominantly chaotic, the classical and quantum probability equilibrium configurations approach the microcanonical distribution, although the quantum equilibrium distributions exhibit characteristic "minimum" fluctuations away from the microcanonical state. The magnitudes of the quantum-classical differences arising from the equilibrium quantum fluctuations are studied for both pure and mixed (dynamically entangled) quantum states. In both cases the standard deviation of these fluctuations decreases as (h/J)(1/2), where J is a measure of the system size. In conclusion, under a variety of conditions the differences between quantum and classical Liouville mechanics are shown to become vanishingly small in the classical limit (J/h-->infinity) of a nondissipative model endowed with only a few degrees of freedom.
Two approaches to quantum-classical correspondence are distinguished according to the classical dynamical theory with which quantum theory is compared. The first of these, Ehrenfest correspondence, defines a dynamical regime in which the quantum expectation values follow approximately a classical trajectory. The second of these, Liouville correspondence, applies when the quantum probability distributions remain well approximated by a density in the classical phase space. The former applies only for narrow states, whereas the latter may remain valid even for quantum states that have spread to the system size. A spin model is adopted for this correspondence study because the quantum state is discrete and finite- dimensional, and thus no artificial truncation of the Hilbert space is required. The quantum time-evolution is given by a discrete unitary mapping. The corresponding classical model is volume-preserving (non-dissipative) and the time-evolution is given by a symplectic map. In classically chaotic regimes, the widths of initially narrow quantum states grow, on average, exponentially with time, until saturation at the system size. This initial spreading rate is well approximated by the classical Lyapunov exponent when the accessible classical phase space is predominantly chaotic. Because of the exponential growth rate of the quantum variance, the Ehrenfest regime is delimited by a break-time that grows logarithmically with increasing quantum numbers. The small differences between quantum expectation values and corresponding Liouville averages of dynamical variables also grow exponentially, initially, if the classical behaviour is chaotic. This exponential rate is independent of h and consistently larger than the classical Lyapunov exponent by at least a factor of two. Interestingly, this exponential growth rate does not continue until these differences approach magnitudes of order the system size, but crosses over to power-law growth (or simply saturates), when the differences have reached magnitudes no larger than order ħ. Because of the exponential growth of these quantum-classical differences, the Liouville regime is also delimited by a break-time that grows logarithmically with increasing quantum numbers. However, due to the early saturation of the exponential growth of the differences, the Liouville log break-time applies only in a restricted domain. After spreading to the system size, the quantum states relax to an approximately time-independent state. This is characterised by equilibrium distributions that are subject to rapidly oscillating fluctuations about the coarse-grained classical steady-state. If the accessible classical phase space is predominantly chaotic, then the equilibrium quantum probability distributions are nearly microcanonical. Otherwise the steady-state quantum probability distributions accurately reflect the details of the KAM surfaces in the classical phase space. The equilibrium regime quantum fluctuations, which are quantum-classical differences, are shown to approach zero as a negative power of the quantum numbers. Since the differences between quantum expectation values and individual classical trajectories grow exponentially in time to a magnitude that scales with the system size, the Ehrenfest regime is delimited by an unrestricted log break-time. The log break-time may be short compared to experimental time-scales for some chaotic macroscopic bodies, and, as a result, an observable breakdown of Ehrenfest correspondence may arise for some macroscopic systems. Although the Liouville regime is also delimited by a log break-time, an observable breakdown of correspondence between quantum mechanics and Liouville mechanics for macroscopic bodies is not likely since their differences, expressed relative to the dimensions of the observable, approach zero in the limit of large quantum numbers.
The conditions of quantum-classical correspondence for a system of two interacting spins are investigated. Differences between quantum expectation values and classical Liouville averages are examined for both regular and chaotic dynamics well beyond the short-time regime of narrow states. We find that quantum-classical differences initially grow exponentially with a characteristic exponent consistently larger than the largest Lyapunov exponent. We provide numerical evidence that the time of the break between the quantum and classical predictions scales as $\mathrm{log}(\mathcal{J}/\ensuremath{\Elzxh}),$ where J\mathcal{J}J is a characteristic system action. However, this logarithmic break-time rule applies only while the quantum-classical deviations are smaller than $O(\ensuremath{\Elzxh}).$ We find that the quantum observables remain well approximated by classical Liouville averages over long times even for the chaotic motions of a few degree-of-freedom system. To obtain this correspondence it is not necessary to introduce the decoherence effects of a many degree-of-freedom environment.
We investigate quench dynamics in a one-dimensional spin model, comparing both quantum and classical descriptions. Our primary focus is on the different timescales involved in the evolution of the observables as they approach statistical relaxation. Numerical simulations, supported by semianalytical analysis, reveal that the relaxation of single-particle energies (global quantity) and on-site magnetization (local observable) occurs on a timescale independent of the system size L. This relaxation process is equally well-described by classical equations of motion and quantum solutions, demonstrating excellent quantum-classical correspondence, provided the system is strongly chaotic. The correspondence persists even for small quantum spin values (S=1), where a semiclassical approximation is not applicable. Conversely, for the participation ratio, which characterizes the initial state spread in the many-body Hilbert space and which lacks a classical analog, the relaxation timescale is system-size dependent.
The quantum dynamics of a classically chaotic model are studied in the approach to the macroscopic limit. The quantum predictions are compared and contrasted with the classical predictions of both Newtonian and Liouville mechanics. The time-domain scaling of the optimal quantum-classical correspondence is analyzed in detail in the case of both classical theories. In both cases the correspondence for observable quantities is shown to break down on a time-scale that increases very slowly (logarithmically) with increasing system size. In the case of quantum-Liouville correspondence such a short time-scale does not imply a breakdown of correspondence since the largest quantum-Liouville differences reached on this time-scale decrease rapidly (as an inverse power) with increasing system size. Therefore the statistical properties of chaotic dynamics are, as expected, well described by quantum theory in the macroscopic limit. In contrast, the largest quantum-Newtonian differences reached on the log time-scale actually increase in proportion to the system size. Since the invariance properties of the Hamiltonian impose functional constraints on the time-varying chaotic coordinates, it is possible to show, moreover, that if the quantum predictions are believed to describe the coordinates of individual chaotic systems, then they also predict macroscopic violations of any kinematic or dynamic constants of the motion. These results for chaotic systems indicate that a valid description of the time-varying properties of individual macroscopic bodies is not available within the standard interpretive framework of quantum theory.
In this review we summarize and amplify recent investigations of coupled quantum dynamical systems with few degrees of freedom in the short-wavelength, semiclassical limit. Focusing on the correspondence between quantum and classical physics, we mathematically formulate and attempt to answer three fundamental questions. (i) How can one drive a small dynamical quantum system to behave classically? (ii) What determines the rate at which two single-particle quantum-mechanical subsystems become entangled when they interact? (iii) How does irreversibility occur in quantum systems with few degrees of freedom? These three questions are posed in the context of the quantum-classical correspondence for dynamical systems with few degrees of freedom, and we accordingly rely on two short-wavelength approximations to quantum mechanics to answer them: the trajectory-based semiclassical approach on the one hand, and random matrix theory on the other hand. We construct novel investigative procedures towards decoherence and the emergence of classicality out of quantumness in dynamical systems coupled to external degrees of freedom. In particular, we show how dynamical properties of chaotic classical systems, such as local exponential instability in phase space, also affects their quantum counterparts. For instance, it is often the case that the fidelity with which a quantum state is reconstructed after an imperfect time-reversal operation decays with the Lyapunov exponent of the corresponding classical dynamics. For related reasons, but perhaps more surprisingly, the rate at which two interacting quantum subsystems become entangled can also be governed by the subsystem's Lyapunov exponents. Our method allows us to differentiate quantum coherent effects (those related to phase interferences) from classical ones (those related to the necessarily extended envelope of quantal wavefunctions) at each stage in our investigations. This makes it clear that all occurrences of Lyapunov exponents we witness have a classical origin, although they require rather strong decoherence effects to be observed. We extensively rely on numerical experiments to illustrate our findings and briefly comment on possible extensions to more complex problems involving environments with many interacting dynamical systems, going beyond the uncoupled harmonic oscillators model of Caldeira and Leggett.
Phase-space representations of the dynamics of the quantal and classical cat map are used to explore quantum-classical correspondence in a KKK system: As $\ensuremath{\Elzxh}\ensuremath{\rightarrow}0$, the classical chaotic behavior is shown to emerge smoothly and exactly. The quantum dynamics near the classical limit displays both exponential separation of adjacent distributions and long time relaxation, two characteristic features of classical chaotic motion.