Abstract We investigate the properties of a trace-gas sensing scheme based on Rydberg excitations at the example of an idealized model system. Rydberg states in thermal rubidium (Rb) are created using a 2-photon cw excitation. These Rydberg-excited atoms ionize via collisions with a background gas of nitrogen (N2). The emerging charges are then measured as an electric current, which is on the order of several picoampere. Due to the 2-photon excitation, this sensing method has a large intrinsic selectivity combined with a promising sensitivity of 10 ppb at an absolute concentration of 1 ppm. The determination of the detection limit is limited by the optical reference measurement but is at least 500 ppb.
Abstract We investigate the properties of a trace-gas sensing scheme based on Rydberg excitations at the example of an idealized model system. Rydberg states in thermal rubidium (Rb) are created using a 2-photon cw excitation. These Rydberg-excited atoms ionize via collisions with a background gas of nitrogen (N2). The emerging charges are then measured as an electric current, which is on the order of several picoampere. Due to the 2-photon excitation, this sensing method has a large intrinsic selectivity combined with a promising sensitivity of 10 ppb at an absolute concentration of 1 ppm. The determination of the detection limit is limited by the optical reference measurement but is at least 500 ppb.
Abstract Within the last few years, Rydberg excitons, bound electron–hole pairs in highly excited states, have emerged as a promising technology platform for quantum nonlinear optics, quantum information processing, and quantum sensing. The advanced device designs and sensing concepts in these fields require strong nonlinearities at the few-photon or few-carrier level. Rydberg states offer the required strong nonlinearities as the relevant physical quantities at the heart of such nonlinear effects scale strongly with the principal quantum number, n, of the excited state: For example, their polarizability scales as n7 n 7 , resulting in an enormous sensitivity to external fields. We review recent experimental and theoretical results that pave the way toward quantum sensing of the electric fields originating from static charge carriers and strongly diluted electron–hole plasmas. We also discuss the strong nonlinear optical properties of Rydberg excitons and how they could be utilized in terms of sensing. Graphical abstract
Rydberg atoms are neutral atoms excited to high principal quantum number states, which endows them with exaggerated properties such as large electric dipole moments, long lifetimes, and extreme sensitivity to external electromagnetic fields. These characteristics form the foundation of Rydberg atom-based sensors, an emerging class of quantum devices capable of optically detecting electric fields across frequencies from DC to the terahertz regime. Rydberg-based electrometry operates through both Autler–Townes (AT) splitting of resonant Rydberg transitions and Stark-shift measurements for high-frequency or far-detuned fields, enabling broadband field sensing from DC to the THz regime. Using ladder-type electromagnetically induced transparency (EIT) and AT splitting, these sensors enable non-invasive, SI-traceable measurements of field amplitude, frequency, phase, and polarization. Recent developments have demonstrated broadband electric field probes, voltage calibration standards, and compact RF receivers based on thermal vapor cells and integrated photonic architectures. Furthermore, innovations in multi-photon EIT, superheterodyne readout, and multi wave mixing have expanded the dynamic range and bandwidth of Rydberg-based electrometry. Despite challenges related to environmental perturbations, linewidth broadening, and laser stabilization, ongoing advances in atomic control, hybrid photonic integration, and EIT-based readout promise scalable, chip-compatible sensors. This review summarizes the physical principles, experimental progress, and emerging applications of Rydberg atom-based sensing, emphasizing their potential for next generation quantum metrology, wireless communication, and precision field mapping.
We present a very sensitive and scalable method to measure the population of highly excited Rydberg states in a thermal vapor cell of rubidium atoms. We detect the Rydberg ionization current in a 5 mm electrically contacted cell. The measured current is found to be in qualitatively good agreement with a theory for the Rydberg population based on a master equation for the three-level problem, including an ionization channel and the full Doppler distributions at the corresponding temperatures. The signal-to-noise ratio of the current detection is substantially better than that of purely optical techniques.
The detection of microwave (MW) fields with room-temperature Rydberg atomic vapors is a novel technique of optical sensing, introducing a range of merits typically not possible to achieve with conventional antennas [1]. Firstly, the atomic response to MW fields is dependent on a given transition dipole moment between Rydberg energy levels - as this value can be precisely derived from the theory of alkali atoms, e.g. rubidium, Rydberg sensors are intrinsically calibrated and there is no dependency on particular device. Secondly, the detector does not contain any metal parts (apart from trace amount of rubidium), introducing very little distortion to the measured field, so the detection is stealthy, and the detector is practically invulnerable even to strong fields. Typically, however, the best state-of-the-art performance is achieved with an additional local oscillator MW field [2], emitted from the antenna, in which case the scheme is no longer all-optical and some advantages are lost.
We investigate the phenomenon of optical bistability in a driven ensemble of Rydberg atoms. By performing two experiments with thermal vapors of rubidium and cesium, we are able to shed light on the underlying interaction mechanisms causing such a nonlinear behavior. Due to the different properties of these two atomic species, we conclude that the large polarizability of Rydberg states in combination with electric fields of spontaneously ionized Rydberg atoms is the relevant interaction mechanism. In the case of rubidium, we directly measure the electric field in a bistable situation via two-species spectroscopy. In cesium, we make use of the different sign of the polarizability for different l states and the possibility of applying electric fields. Both these experiments allow us to rule out dipole-dipole interactions and support our hypothesis of a charge-induced bistability.
Rydberg atoms, which have a highly excited outer electron, are easily manipulated by electric fields. Using a magneto-optical trap, we cool Rubidium atoms to a few hundred millionths of a Kelvin above absolute zero and then excite to Rydberg states. Our first project looks at the dipole-dipole interactions of two atoms starting in the 33p state and ending in the 34s and 33s states. The standard technique is to apply an increasing electric field that ionizes the Rydberg electron and sends it to a detector, but unfortunately the signals overlap. A genetic algorithm is used to separate the signals by controlling the ionization pathway. In order to understand how a Rydberg atom ionizes we need to build a model. The current model, which uses a semi-empirical formula, neglects important quantum phase information. In our second project we are building a computational model that includes continuum states along with discrete states. We present progress on a new model which takes into account the differences in normalization for continuum and discrete states.