We study the thermodynamics of Bose-Einstein condensation in a weakly interacting quasi-homogeneous atomic gas, prepared in an optical-box trap. We characterise the critical point for condensation and observe saturation of the thermal component in a partially condensed cloud, in agreement with Einstein's textbook picture of a purely statistical phase transition. Finally, we observe the quantum Joule-Thomson effect, namely isoenthalpic cooling of an (essentially) ideal gas. In our experiments this cooling occurs spontaneously, due to energy-independent collisions with the background gas in the vacuum chamber. We extract a Joule-Thomson coefficient $\mu_{\rm JT} > 10^9$ K/bar, about ten orders of magnitude larger than observed in classical gases.
We study the thermodynamics of Bose-Einstein condensation in a weakly interacting quasi-homogeneous atomic gas, prepared in an optical-box trap. We characterise the critical point for condensation and observe saturation of the thermal component in a partially condensed cloud, in agreement with Einstein's textbook picture of a purely statistical phase transition. Finally, we observe the quantum Joule-Thomson effect, namely isoenthalpic cooling of an (essentially) ideal gas. In our experiments this cooling occurs spontaneously, due to energy-independent collisions with the background gas in the vacuum chamber. We extract a Joule-Thomson coefficient μJT>109 K/bar, about ten orders of magnitude larger than observed in classical gases.
We study the thermodynamics of Bose-Einstein condensation in a weakly interacting quasihomogeneous atomic gas, prepared in an optical-box trap. We characterize the critical point for condensation and observe saturation of the thermal component in a partially condensed cloud, in agreement with Einstein's textbook picture of a purely statistical phase transition. Finally, we observe the quantum Joule-Thomson effect, namely isoenthalpic cooling of an (essentially) ideal gas. In our experiments this cooling occurs spontaneously, due to energy-independent collisions with the background gas in the vacuum chamber. We extract a Joule-Thomson coefficient μJT>10(9) K/bar, about 10 orders of magnitude larger than observed in classical gases.
This thesis describes studies of out-of-equilibrium dynamics in an interacting homogeneous Bose gas. We use the versatile platform of an ultracold gas of 39K, prepared in an optical box trap. The experiment features both tuneable interaction strengths and a homogeneous atomic density. We examine first a weakly interacting near-equilibrium system, followed by far-from-equilibrium dynamics under moderate interactions, and finally combine strong interactions with highly non-equilibrium dynamics in studies of the unitary Bose gas. We start with a theoretical study of the effects of three-body recombination on the temperature of a weakly interacting, partially condensed gas. Contrary to the expectation of heating, we find that for appropriate values of the condensed fraction and gas parameter, the system temperature is expected to decrease. Not only do we predict lower temperatures, however, but also for the condensate fraction to grow. We then present experiments in which we engineer a far-from-equilibrium momentum distribution, and study the dynamics as the gas relaxes. As the distribution evolves, we observe bidirectional dynamic scaling, with a flow of particles to lower momenta while energy is transported to higher ones. These flows are characterised by spatiotemporal scaling exponents, which we find do not vary appreciably over a range of moderate interaction strengths. Finally, we look to the unitary Bose gas, quenching clouds into the strongly interacting regime. This regime offers insight into universal behaviour that depends only on the interparticle spacing, as well as being an avenue for the study of Efimov physics. However, few things come for free; strongly interacting Bose systems are plagued by high atom-loss and heating rates. We study atom-loss rates and the dynamics of correlations in our gases, isolate the coherent effects from the dissipative ones, and identify a quasi-equilibrium state that features a non-zero condensate fraction.
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
A simple picture describes the results of recent treatments of partially--condensed, dilute, trapped Bose gases at temperature T > 0. The condensate wave function is nearly identical to that of a T = 0 condensate with the same number of condensate atoms, Ν0.The cloud of non-condensed atoms is described by the statistical mechanics of an ideal Bose gas in the com- bined potentials of the magnetic trap and the cloud-condensate interaction.We provide a physical motivation for this result, show how it emerges in the Hartree-Fock-Bogo liubov-Popov approximation, and explore some of its implications for future experiments.
When a gas of bosonic atoms is cooled sufficiently near to absolute zero, it undergoes a startling transition from a collection of randomly-behaved individual atoms to a phase in which thousands, even millions, of atoms act in collective unison. In this new phase, known as a Bose-Einstein condensate (BEC), the atoms all occupy the exact same quantum mechanical ground state and can be collectively described by a single phase-coherent wavefunction of macroscopic size. But how exactly does this harmonious behaviour arise within a collection of incoherent atoms as their temperature decreases? Does the condensate wavefunction grow from a single central nucleus, or does it emerge simultaneously throughout the system? And how does the situation differ when the gas is cooled suddenly, away from thermodynamic equilibrium? Can non-equilibrium behaviour be inherited by the condensate that forms? In this thesis we aim to answer these and other questions by studying the formation dynamics of Bose-Einstein condensates and the development of phase coherence. The research described herein makes use of several theoretical tools, which we lay out on the workbench in Chapter 2: Semi-classical Hartree-Fock theory provides a mean-field description of a condensate and thermal cloud at equilibrium; Quantum kinetic theory is used to calculate the dynamics of condensate growth into an equilibrium state, from a non-equilibrium thermal cloud; The stochastic projected Gross-Pitaevskii equation (SPGPE) employs a classical-field description to encapsulate the non-equilibrium dynamics of the condensate and low-energy region of the atom cloud, coupled to an equilibrium thermal cloud. This thesis is composed of four principal studies, each constituting a separate chapter.In Chapter 3 we study the formation of a Bose-Einstein condensate in a cigar-shaped 3D harmonic trap, induced by the controlled addition of an attractive ``dimple'' potential along the weak axis in a recent experiment [Garrett et al., Phys. Rev. A 83, 013630 (2011)]. In this manner condensation is induced without cooling due to a localized increase in the phase space density. We perform a quantitative analysis of the thermodynamic transformation in both the sudden and adiabatic regimes for a range of dimple widths and depths. We find good agreement with equilibrium calculations based on self-consistent semi-classical Hartree-Fock theory describing the condensate and thermal cloud. We observe there is an optimal dimple depth that results in a maximum in the condensate fraction. We also study the non-equilibrium dynamics of condensate formation in the sudden turn-on regime, finding good agreement for the observed time dependence of the condensate fraction with calculations based on quantum kinetic theory. In Chapter 4 we study the onset of phase coherence during the formation of a BEC following a sudden quench to below the transition temperature. Using the SPGPE, we simulate a recent experiment performed at ANU in which a sudden RF quench is applied to a dilute gas of metastable Helium atoms confined in an elongated 3D harmonic magnetic trap. At regularly-spaced intervals following the quench, broadband RF pulses are applied to homogeneously outcouple small (<5%) pulses of atoms, which expand and fall to a microchannel plate detector. The second-order correlation function at the detector, postulated to provide a measure of phase coherence of the in-situ cloud from which they were outcoupled, is measured versus time and compared with the condensate growth curve. A delay was observed in the relaxation of the second-order correlation function, relative to the peak in the number of condensate atoms. In our simulations we incorporate the effects of periodic outcoupling both the condensate and thermal cloud, and monitor the time-dependence of first- and second-order correlation functions in both position and momentum space. We observe long-range phase coherence in the final equilibrium state, though mild persistent phase fluctuations are present. We also observe the curious phenomenon of ``superbunching'' - an enhancement of density fluctuations - at specific values of the momentum, which we relate to anomalous correlations of fluctuations. Despite obtaining a good quantitative fit to the experimentally-measured condensate growth curve in our SPGPE simulations, we do not observe any evidence of the delay in coherence observed in the experiment, which remains unexplained. In Chapter 5 we use the SPGPE to study the crossover from a true BEC with long-range phase coherence to a quasicondensate dominated by phase fluctuations, for the case of a Bose gas in an highly-elongated 3D harmonic trap. We use parameters corresponding to an experiment in which a sudden quench resulted in the formation of a non-equilibrium condensate, the dynamics of which we study in the chapter that follows. Sweeping through a range of temperatures and chemical potentials within the crossover region, we reveal the behaviour of phase fluctuations through analysis of correlation functions. We compare the ideal-gas approximation for the transition temperature with the more accurate value obtained via the Binder cumulant. By comparing the phase coherence length with the spatial extent across which density fluctuations are suppressed, we identify the BEC/quasicondensate crossover point. We compare directly with predictions of mean-field theory [Petrov et al., Phys. Rev. Lett. 87, 050404 (2001)] and find that phase fluctuations persist to lower temperatures in our SPGPE simulations. We calculate anomalous correlations of the fluctuation field and show that the resulting correction to the mean-field condensate self-interaction energy is significant within the quasicondensate regime. In Chapter 6 we study the formation of a BEC into a non-equilibrium state by simulating an experiment in which a dilute gas of Rubidium-87 atoms in a highly-elongated 3D harmonic magnetic trap is rapidly quenched to below the transition temperature. Following the quench, a condensate is observed to form with an excessively elongated shape, and subsequently undergo damped quadrupole shape oscillations [Shvarchuck et al., Phys. Rev. Lett. 89, 270404 (2002)]. We simulate this experiment by modifying the SPGPE to incorporate a hydrodynamic thermal cloud, parametrized by axially and temporally-dependent temperature and chemical potential. Comparison against simulations without this axial dependence suggests the hydrodynamic behaviour of the thermal cloud plays a crucial role in the formation of a non-equilibrium condensate. Analyses of the first-order correlation function and the condensate wavefunction reveal the spontaneous formation of quantum vortices, as well as strong phase fluctuations at equilibrium indicating quasicondensate behaviour.