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Cambridge University Press eBooks

Effects of Interactions on Bose-Einstein Condensation

Robert P. Smith

Published Oct 4, 2018• 3 citations
Publisher

Abstract

Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.

DOI
10.1017/9781316084366.008

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Effects of Interactions on Bose-Einstein Condensation

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Bose-Einstein condensation is a unique phase transition in that it is not driven by inter-particle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question \emph{`How is this ideal Bose gas condensation modified in the presence of interactions between the particles?' } This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers.

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Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in $L^2$-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. $\textit{Full-text embargoed until: 2026-01-01}$

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The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.

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Foreword

Tony Leggett

At the time of the first workshop in this series in 1993, the only experimentally realized Bose condensate (at least in the simple sense conjectured by Einstein) was liquid 4 He. In the intervening twenty-plus years, much has happened in the world of Bose-Einstein condensation (BEC). Probably the most exciting development has been the attainment of condensation in ultracold bosonic atomic gases such as 87 Rb and 23 Na in 1995, followed a few years later by the achievement of degeneracy and eventually Bardeen-Cooper-Schrieffer (BCS) pairing in their fermionic counterparts, and the experimental realization of the theoretically long-anticipated “BEC-BCS crossover” by using the magnetic field degree of freedom to tune the system through a Feshbach resonance. One particularly fascinating aspect of the latter has been the realization of a “unitary gas” at the resonance itself – a system which prima facie has no characteristic length scale other than the interparticle separation, and is therefore a major challenge to theorists. Other systems in which BEC has been realized, sometimes transiently, include exciton-polariton complexes in semiconducting microcavities and, at least in a formal sense, the magnons in a magnetic insulator, as well as ultracold gases with a nontrivial and sometimes large “spin” degree of freedom. As compared with our “traditional” Bose condensate, liquid 4 He, these new systems typically have many more (and more rapidly adjustable) control parameters, and have therefore permitted qualitatively new types of experiment. One particularly fascinating development has been the use of optical techniques to generate “synthetic gauge fields” and thus mimic some of the topologically nontrivial systems which have recently been of such intense interest in a condensed-matter setting. At the same time, there remain long-standing issues from helium physics, such as the nature and consequences of “spontaneously broken U(1) symmetry,” the “Kibble-Zurek” mechanism, and more generally the relaxation of strongly nonequilibrium states to equilibrium; in some cases, the new systems have been used to address these more quantitatively than was possible with 4 He. The chapters in this volume address all of these questions and more, and should be of intense interest to both the experimental and the theoretical sides of the BEC community.

Cambridge University Press eBooks•Oct 4, 2018•0 citations

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Bose–Einstein condensation (BEC) in cold atomic gases was first achieved experimentally in 1995. Since then there has been a surge of activity in this field, with ingenious experiments putting forth more and more astonishing results about the behaviour of matter at very cold temperatures. The theoretical investigation of BEC goes back much further, and even predates the modern formulation of quantum mechanics. It was investigated in two papers by Einstein in 1924 and 1925, respectively, following up on a work by Bose on the derivation of Planck's radiation law. Einstein's result, in its modern formulation, can be found in any textbook on quantum statistical mechanics, and was concerned with ideal, i.e., non-interacting gases. The understanding of BEC in the presence of interparticle interactions poses a formidable challenge to mathematical physics. Some progress has been made in the last ten years or so, and the purpose of this chapter is to explain part of what was achieved and how it is related to the actual experiments on cold gases.

Oxford University Press eBooks•May 24, 2012•3 citations
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
Bose-Einstein condensation is a unique phase transition in that it is not driven by inter-particle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question \emph{`How is this ideal Bose gas condensation modified in the presence of interactions between the particles?' } This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2L^2L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01\textit{Full-text embargoed until: 2026-01-01}Full-text embargoed until: 2026-01-01
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
Liquid helium 4 had been the only bosonic superfluid available in experiments for a long time. This situation was changed in 1995, when a new superfluid was born with the realization of the Bose–Einstein condensation in ultracold atomic gases. The liquid helium 4 is strongly interacting and has no spin; there is almost no way to change its parameters, such as interaction strength and density. The new superfluid, Bose–Einstein condensate (BEC), offers various advantages over liquid helium. On the one hand, BEC is weakly interacting and has spin degrees of freedom. On the other hand, it is convenient to tune almost all the parameters of a BEC, for example, the kinetic energy by spin–orbit coupling, the density by the external potential, and the interaction by Feshbach resonance. Great efforts have been devoted to studying these new aspects, and the results have greatly enriched our understanding of superfluidity. Here we review these developments by focusing on the stability and critical velocity of various superfluids. The BEC systems considered include a uniform superfluid in free space, a superfluid with its density periodically modulated, a superfluid with artificially engineered spin–orbit coupling, and a superfluid of pure spin current. Due to the weak interaction, these BEC systems can be well described by the mean-field Gross–Pitaevskii theory and their superfluidity, in particular critical velocities, can be examined with the aid of Bogoliubov excitations. Experimental proposals to observe these new aspects of superfluidity are discussed.
At the time of the first workshop in this series in 1993, the only experimentally realized Bose condensate (at least in the simple sense conjectured by Einstein) was liquid 4 He. In the intervening twenty-plus years, much has happened in the world of Bose-Einstein condensation (BEC). Probably the most exciting development has been the attainment of condensation in ultracold bosonic atomic gases such as 87 Rb and 23 Na in 1995, followed a few years later by the achievement of degeneracy and eventually Bardeen-Cooper-Schrieffer (BCS) pairing in their fermionic counterparts, and the experimental realization of the theoretically long-anticipated “BEC-BCS crossover” by using the magnetic field degree of freedom to tune the system through a Feshbach resonance. One particularly fascinating aspect of the latter has been the realization of a “unitary gas” at the resonance itself – a system which prima facie has no characteristic length scale other than the interparticle separation, and is therefore a major challenge to theorists. Other systems in which BEC has been realized, sometimes transiently, include exciton-polariton complexes in semiconducting microcavities and, at least in a formal sense, the magnons in a magnetic insulator, as well as ultracold gases with a nontrivial and sometimes large “spin” degree of freedom. As compared with our “traditional” Bose condensate, liquid 4 He, these new systems typically have many more (and more rapidly adjustable) control parameters, and have therefore permitted qualitatively new types of experiment. One particularly fascinating development has been the use of optical techniques to generate “synthetic gauge fields” and thus mimic some of the topologically nontrivial systems which have recently been of such intense interest in a condensed-matter setting. At the same time, there remain long-standing issues from helium physics, such as the nature and consequences of “spontaneously broken U(1) symmetry,” the “Kibble-Zurek” mechanism, and more generally the relaxation of strongly nonequilibrium states to equilibrium; in some cases, the new systems have been used to address these more quantitatively than was possible with 4 He. The chapters in this volume address all of these questions and more, and should be of intense interest to both the experimental and the theoretical sides of the BEC community.
Bose–Einstein condensation (BEC) in cold atomic gases was first achieved experimentally in 1995. Since then there has been a surge of activity in this field, with ingenious experiments putting forth more and more astonishing results about the behaviour of matter at very cold temperatures. The theoretical investigation of BEC goes back much further, and even predates the modern formulation of quantum mechanics. It was investigated in two papers by Einstein in 1924 and 1925, respectively, following up on a work by Bose on the derivation of Planck's radiation law. Einstein's result, in its modern formulation, can be found in any textbook on quantum statistical mechanics, and was concerned with ideal, i.e., non-interacting gases. The understanding of BEC in the presence of interparticle interactions poses a formidable challenge to mathematical physics. Some progress has been made in the last ten years or so, and the purpose of this chapter is to explain part of what was achieved and how it is related to the actual experiments on cold gases.