Bose-Einstein condensation is a unique phase transition in that it is not driven by inter-particle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question \emph{`How is this ideal Bose gas condensation modified in the presence of interactions between the particles?' } This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers.
Bose-Einstein condensation is a unique phase transition in that it is not driven by inter-particle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question \emph{`How is this ideal Bose gas condensation modified in the presence of interactions between the particles?' } This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers.
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
The realization of Bose-Einstein Condensation (BEC) in dilute gases of ultracold atoms has revolutionized quantum physics by offering an unprecedented platform to study quantum phenomena on macroscopic scales. Ultracold atomic systems, cooled to temperatures near absolute zero, exhibit collective behaviors governed by quantum statistics, coherence, and interactions. This article discusses the theoretical and experimental frameworks underpinning the formation of BECs, focusing on the trapping, cooling, and coherence properties of ultracold bosonic gases. Further, we delve into the role of quantum phase transitions, atom-atom interactions, and external field manipulation in controlling condensate dynamics. The implications of BECs extend into precision measurements, quantum simulation, and quantum computing, positioning them as a cornerstone in modern atomic and condensed matter physics.
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.
Bose–Einstein condensation (BEC) in cold atomic gases was first achieved experimentally in 1995. Since then there has been a surge of activity in this field, with ingenious experiments putting forth more and more astonishing results about the behaviour of matter at very cold temperatures. The theoretical investigation of BEC goes back much further, and even predates the modern formulation of quantum mechanics. It was investigated in two papers by Einstein in 1924 and 1925, respectively, following up on a work by Bose on the derivation of Planck's radiation law. Einstein's result, in its modern formulation, can be found in any textbook on quantum statistical mechanics, and was concerned with ideal, i.e., non-interacting gases. The understanding of BEC in the presence of interparticle interactions poses a formidable challenge to mathematical physics. Some progress has been made in the last ten years or so, and the purpose of this chapter is to explain part of what was achieved and how it is related to the actual experiments on cold gases.
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
We review some recent theoretical work on the phase transition of interacting Bose gases in the presence of external trapping potentials. A general framework for the study of such questions is presented which is based on the application of perturbative momentum-shell renormalization group methods to the trapped gas in the uncondensed phase. After giving an overview of this approach, we first establish its validity by comparing to previous results for homogeneous and harmonically trapped gases. Using this theoretical framework, we then examine various aspects of how external potentials influence the physics of condensation. (i) By studying the case of general power-law potentials and complemented by arguments from variational perturbation theory, it is quantitatively worked out how a growing inhomogeneity of the trapping potential diminishes nonperturbative effects at the transition. (ii) It is shown how by superimposing a weak periodic potentials on the homogeneous system, the characteristic nonperturbative momentum scale of critical interacting Bose gases can be probed. (iii) For a gas in a random potential, it is studied how condensation is affected by the combined influence of disorder effects and particle interactions.