The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
When a gas of bosonic atoms is cooled sufficiently near to absolute zero, it undergoes a startling transition from a collection of randomly-behaved individual atoms to a phase in which thousands, even millions, of atoms act in collective unison. In this new phase, known as a Bose-Einstein condensate (BEC), the atoms all occupy the exact same quantum mechanical ground state and can be collectively described by a single phase-coherent wavefunction of macroscopic size. But how exactly does this harmonious behaviour arise within a collection of incoherent atoms as their temperature decreases? Does the condensate wavefunction grow from a single central nucleus, or does it emerge simultaneously throughout the system? And how does the situation differ when the gas is cooled suddenly, away from thermodynamic equilibrium? Can non-equilibrium behaviour be inherited by the condensate that forms? In this thesis we aim to answer these and other questions by studying the formation dynamics of Bose-Einstein condensates and the development of phase coherence. The research described herein makes use of several theoretical tools, which we lay out on the workbench in Chapter 2: Semi-classical Hartree-Fock theory provides a mean-field description of a condensate and thermal cloud at equilibrium; Quantum kinetic theory is used to calculate the dynamics of condensate growth into an equilibrium state, from a non-equilibrium thermal cloud; The stochastic projected Gross-Pitaevskii equation (SPGPE) employs a classical-field description to encapsulate the non-equilibrium dynamics of the condensate and low-energy region of the atom cloud, coupled to an equilibrium thermal cloud. This thesis is composed of four principal studies, each constituting a separate chapter.In Chapter 3 we study the formation of a Bose-Einstein condensate in a cigar-shaped 3D harmonic trap, induced by the controlled addition of an attractive ``dimple'' potential along the weak axis in a recent experiment [Garrett et al., Phys. Rev. A 83, 013630 (2011)]. In this manner condensation is induced without cooling due to a localized increase in the phase space density. We perform a quantitative analysis of the thermodynamic transformation in both the sudden and adiabatic regimes for a range of dimple widths and depths. We find good agreement with equilibrium calculations based on self-consistent semi-classical Hartree-Fock theory describing the condensate and thermal cloud. We observe there is an optimal dimple depth that results in a maximum in the condensate fraction. We also study the non-equilibrium dynamics of condensate formation in the sudden turn-on regime, finding good agreement for the observed time dependence of the condensate fraction with calculations based on quantum kinetic theory. In Chapter 4 we study the onset of phase coherence during the formation of a BEC following a sudden quench to below the transition temperature. Using the SPGPE, we simulate a recent experiment performed at ANU in which a sudden RF quench is applied to a dilute gas of metastable Helium atoms confined in an elongated 3D harmonic magnetic trap. At regularly-spaced intervals following the quench, broadband RF pulses are applied to homogeneously outcouple small (<5%) pulses of atoms, which expand and fall to a microchannel plate detector. The second-order correlation function at the detector, postulated to provide a measure of phase coherence of the in-situ cloud from which they were outcoupled, is measured versus time and compared with the condensate growth curve. A delay was observed in the relaxation of the second-order correlation function, relative to the peak in the number of condensate atoms. In our simulations we incorporate the effects of periodic outcoupling both the condensate and thermal cloud, and monitor the time-dependence of first- and second-order correlation functions in both position and momentum space. We observe long-range phase coherence in the final equilibrium state, though mild persistent phase fluctuations are present. We also observe the curious phenomenon of ``superbunching'' - an enhancement of density fluctuations - at specific values of the momentum, which we relate to anomalous correlations of fluctuations. Despite obtaining a good quantitative fit to the experimentally-measured condensate growth curve in our SPGPE simulations, we do not observe any evidence of the delay in coherence observed in the experiment, which remains unexplained. In Chapter 5 we use the SPGPE to study the crossover from a true BEC with long-range phase coherence to a quasicondensate dominated by phase fluctuations, for the case of a Bose gas in an highly-elongated 3D harmonic trap. We use parameters corresponding to an experiment in which a sudden quench resulted in the formation of a non-equilibrium condensate, the dynamics of which we study in the chapter that follows. Sweeping through a range of temperatures and chemical potentials within the crossover region, we reveal the behaviour of phase fluctuations through analysis of correlation functions. We compare the ideal-gas approximation for the transition temperature with the more accurate value obtained via the Binder cumulant. By comparing the phase coherence length with the spatial extent across which density fluctuations are suppressed, we identify the BEC/quasicondensate crossover point. We compare directly with predictions of mean-field theory [Petrov et al., Phys. Rev. Lett. 87, 050404 (2001)] and find that phase fluctuations persist to lower temperatures in our SPGPE simulations. We calculate anomalous correlations of the fluctuation field and show that the resulting correction to the mean-field condensate self-interaction energy is significant within the quasicondensate regime. In Chapter 6 we study the formation of a BEC into a non-equilibrium state by simulating an experiment in which a dilute gas of Rubidium-87 atoms in a highly-elongated 3D harmonic magnetic trap is rapidly quenched to below the transition temperature. Following the quench, a condensate is observed to form with an excessively elongated shape, and subsequently undergo damped quadrupole shape oscillations [Shvarchuck et al., Phys. Rev. Lett. 89, 270404 (2002)]. We simulate this experiment by modifying the SPGPE to incorporate a hydrodynamic thermal cloud, parametrized by axially and temporally-dependent temperature and chemical potential. Comparison against simulations without this axial dependence suggests the hydrodynamic behaviour of the thermal cloud plays a crucial role in the formation of a non-equilibrium condensate. Analyses of the first-order correlation function and the condensate wavefunction reveal the spontaneous formation of quantum vortices, as well as strong phase fluctuations at equilibrium indicating quasicondensate behaviour.
We investigate the dynamics of formation of topological defects in ultra-cold quantum gases. Using classical field methods, such as the truncated Wigner approximation and the stochastic Gross-Pitaevskii equation, we explore the connection between the rate of a phase transition and the number of topological defects formed as a consequence of it. We show that in various systems such defects form in number comparable with the predictions of the Kibble-Zurek theory, known for thirty years but as yet unverified experimentally. We also consider the spontaneous production of entangled vortices following a quantum phase transition in a multi-component spin-1 Bose-Einstein condensate (BEC). To begin, we provide a literature review and describe some of the background theory of multi-component condensates, stochastic methods and Kibble-Zurek theory. Part of this thesis focus on a two component Bose-Einstein condensates of the same atomic species. In particular on the quantum critical point separating the miscible from the immiscible phase of such systems. We show that such phase transition cannot only be achieved with the tuning of the interaction constants between the components, but also through changes in the intensity of the coupling between atoms in different hyperfine states. We first determine the value of the critical coupling, and also the critical exponents defining the universality class of the coupling—induced phase transition. We then proceed to simulate the dynamics of the transition in effective 1D ring and harmonically trapped condensates, and test the results against predictions of the Kibble-Zurek (KZ) mechanism. We find good agreement between the KZ theory and the numerical results in the ring geometry, and we motivate the origin of the discrepancies between the two in harmonically trapped BECs. We use the ”equivalence” of inhomogeneous phase transitions in anisotropic systems and spatially inhomogeneous quenches to engineer coupling quenches and systematically study key aspects of the inhomogeneous KZ mechanism. The coupling induced miscible—immiscible transition results in the formation of a stable pattern of domains that easily be detected and counted in current ultra-cold gases experiment, and the scheme is a viable candidate for the first experimental testing of the KZ predictions. We then examine the spontaneous formation of a superflow as result of the thermal Bose-Einstein phase transition in ring traps. According to the Kibble-Zurek theory, the fast production of a condensate in a ring trap should result in the formation of solitons, with the number depending on the rate of the temperature quench. Solitons are short-living topological defects and their observation in ultra-cold gases experiments remains challenging. We show here that even after they decay, solitons leave a signature in the variance of the final winding number of the condensate. Solitons fragment a 1D condensate into regions of random phase, hence the larger the number of solitons, the higher the probability that the resulting phase wraps around the ring by a multiple of 2π. We numerically simulate the BEC transition in this system with the stochastic Gross-Pitaevskii equation, and observe that the winding number scales with the quenching time as predicted by the KZ mechanism. We examine the effect of inhomogeneity on the expectation value of the winding number, and find that the tilting of the ring greatly suppress the spontaneous formation of vortices. This has implications for the necessary horizontal alignment of any experiment on this system. Finally, we consider the polar to anti-ferromagnetic phase transition in magnetically quenched spin-1 BEC. In this quantum phase transition a pure condensate of atoms in the mF = 0 Zeeman sublevel is converted into a three component BEC with atoms in mF = 0, ±1 through spin changing collisions. An analogous mechanism, four—wave mixing, in quantum optics produces entangled photons, and it has been proposed in ultra-cold gases as a method to obtain Einstein-Podolski-Rosen entanglement of macroscopic atomic ensembles. We begin with a rotating 1D spinor condensate of atoms in the mF = 0 component, and perform a quench of the magnetic field through the critical point. We show how the transition produces a pair of entangled components with different winding numbers, and quantify the entanglement as a function of the modes considered and of the type of magnetic quench, sudden or instantaneous. Lastly, we propose a method to use the original spin zero component as coherent source to perform homodyne detection and consider the two rotating entangled components as a resource for the sensing of rotations.
The study of Bose-Einstein condensation has undergone a remarkable expansion during the last twenty years. Observations of this phenomenon have been reported in a number of diverse atomic, optical, and condensed matter systems, facilitated by remarkable experimental advances. The synergy of experimental and theoretical work in this broad research area is unique, leading to the establishment of Bose-Einstein condensation as a universal interdisciplinary area of modern physics. This chapter reviews the broad expansion of Bose-Einstein condensation physics in the past two decades. Introduction The field of Bose-Einstein condensation (BEC) has undergone an explosive expansion during the past twenty years. Newcomers to this field are now often introduced to this as a universal phenomenon, which nonetheless exhibits diverse (and sometimes strikingly different) manifestations. Despite such differences, the common underlying theme creates a unique identity across many different energy and length scales. The study of BEC as a universal phenomenon was highlighted in a focused conference in 1993, leading to the publication of the well-known “green book” [1], which surveyed the breadth of the field of condensate physics at that time. The success of the conference led to a second meeting in 1995, at which Eric Cornell and Carl Wieman announced the achievement of Bose-Einstein condensation of ultracold 87 Rb atoms in a harmonic trap. That work began an explosion of new research in the field of cold atoms, which has continued to this day, and this very success inevitably led many of those studying cold atoms to pay less attention to other types of condensates. Wolfgang Ketterle gives a historical overview of this exciting period of time in Chapter 3. Recently, various scientific meetings have worked to re-establish the physical connections across different BEC systems, and in 2013 a workshop was held with the focused goal of improving communications across disciplines. This present book is an outgrowth of that meeting. The Situation Before the Revolution Because of the great success of the cold atom BEC and other BEC systems in the past twenty years, it may be hard for young scientists to understand the climate of BEC research in the early 1990s. At that time, there was only one known example of BEC, namely liquid helium-4, and there was a small but vocal minority of scientists who questioned whether BEC was established even in that system.
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.
The emergence of macroscopic coherence in a many-body quantum system is a ubiquitous phenomenon across different physical systems and scales. This Chapter reviews key concepts characterizing such systems (correlation functions, condensation, quasi-condensation) and applies them to the study of emerging non-equilibrium features in the dynamical path towards such a highly-coherent state: particular emphasis is placed on emerging universal features in the dynamics of conservative and open quantum systems, their equilibrium or non-equilibrium nature, and the extent that these can be observed in current experiments with quantum gases. Characteristic examples include symmetry-breaking in the Kibble-Zurek mechanism, coarsening and phase-ordering kinetics, and universal spatiotemporal scalings around non-thermal fixed points and in the context of the Kardar- Parisi-Zhang equation; the Chapter concludes with a brief review of the potential relevance of some of these concepts in modelling the large-scale distribution of dark matter in the universe.