133Ba
+ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus, visible wavelength electronic transitions, and long D-state lifetimes ($\\tau\\sim
1 min).Usingamicrogramsourceofradioactivematerial,wetrapandlaser−coolthesynthetictextitA=133radioisotopeofbariumII(\\tau_{1/2} \\approx 10.5
yr)inaradio−frequencyiontrap.Todemonstratehighfidelityqubitoperations,anumberofunknownstateenergieswereneeded.Wemeasuretheisotopeshiftandhyperfinestructureofthe6^2
P_{1/2}\\leftrightarrow 5^2
D_{3/2}$ electronic transition needed for laser cooling, state preparation, and state detection of the clock-state hyperfine and optical qubits. For high-fidelity operations with electron shelving, we report measurements of the 6
2P
3/2 and
52D
5/2 hyperfine splittings, as well as the~6
2P
3/2 leftrightarrow 62S
1/2 and ~6
2P
3/2 leftrightarrow 52D
5/2 transition frequencies. Using these transitions, we demonstrate high-fidelity \\ba \\ hyperfine qubit manipulation with electron shelving detection to benchmark qubit state preparation and measurement (SPAM). Using single-shot, threshold discrimination, we measure an average SPAM fidelity of
mathcalF=0.99971(3), a factor of
approx 2 improvement over the best reported performance of any qubit.Finally, we report the 6
2P
1/2leftrightarrow52D
3/2 electronic transition isotope shift for the rare \\textit{A} = 130 and 132 barium nuclides, completing the spectroscopic characterization necessary for laser cooling all long-lived barium II isotopes.
Ion trap system is a leading candidate for quantum information science benefitting from its long coherence time, high-fidelity gate operations. In addition, the ion photon entanglement provides a versatile tool to realize quantum networks by generating an ideal pair of a stationary memory qubit and a flying communication qubit. Rapid developments in nonlinear quantum frequency conversion techniques have enhanced the potential for constructing a trapped ion quantum network via optical fiber connections. The generation of long-distance entanglement has been demonstrated with ions such as Ca+ and Ba+, which emit photons in visible or near-infrared range naturally. On the other hand, as the qubit-native photons reside in ultra-violet (UV) spectrum, the Yb+ ion has not been considered as a strong competitor for telecommunication qubits despite extensive research on it. Here, we demonstrate an efficient difference-frequency conversion of UV photons, emitted from a trapped Yb+ ion, into a visible range. We provide experimental evidence that confirms the converted photons are radiated from the Yb+ ion. Our results provide a crucial step toward realizing a long-distance trapped ion quantum network based on Yb+ ions through quantum frequency conversion.