133Ba
+ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus, visible wavelength electronic transitions, and long D-state lifetimes ($\\tau\\sim
1 min).Usingamicrogramsourceofradioactivematerial,wetrapandlaser−coolthesynthetictextitA=133radioisotopeofbariumII(\\tau_{1/2} \\approx 10.5
yr)inaradio−frequencyiontrap.Todemonstratehighfidelityqubitoperations,anumberofunknownstateenergieswereneeded.Wemeasuretheisotopeshiftandhyperfinestructureofthe6^2
P_{1/2}\\leftrightarrow 5^2
D_{3/2}$ electronic transition needed for laser cooling, state preparation, and state detection of the clock-state hyperfine and optical qubits. For high-fidelity operations with electron shelving, we report measurements of the 6
2P
3/2 and
52D
5/2 hyperfine splittings, as well as the~6
2P
3/2 leftrightarrow 62S
1/2 and ~6
2P
3/2 leftrightarrow 52D
5/2 transition frequencies. Using these transitions, we demonstrate high-fidelity \\ba \\ hyperfine qubit manipulation with electron shelving detection to benchmark qubit state preparation and measurement (SPAM). Using single-shot, threshold discrimination, we measure an average SPAM fidelity of
mathcalF=0.99971(3), a factor of
approx 2 improvement over the best reported performance of any qubit.Finally, we report the 6
2P
1/2leftrightarrow52D
3/2 electronic transition isotope shift for the rare \\textit{A} = 130 and 132 barium nuclides, completing the spectroscopic characterization necessary for laser cooling all long-lived barium II isotopes.
Quantum state preparation for trapped-ion qubits often relies on high-quality circularly polarized light, which may be difficult to achieve with chip-based integrated optics technology. We propose and implement a hybrid optical and microwave scheme for intermediate-field hyperfine qubits which instead relies on frequency selectivity. Experimentally, we achieve 99.94 % fidelity for linearly polarized ( σ + / σ − ) light, using Ca + 43 at 28.8 mT. We find that the fidelity remains above 99.8 % for a mixture of all polarizations ( σ + / σ − / π ) . We calculate that the method is capable of 99.99 % fidelity in Ca + 43 , and even higher fidelities in heavier ions such as Ba + 137 . Published by the American Physical Society 2024