Population leakage outside the qubit subspace presents a particularly harmful source of error that cannot be handled by standard error correction methods. Using a trapped
171Yb+ ion, we demonstrate an optical pumping scheme to suppress leakage errors in atomic hyperfine qubits. The selection rules and narrow linewidth of a quadrupole transition are used to selectively pump population out of leakage states and back into the qubit subspace. Each pumping cycle reduces the leakage population by a factor of $\ensuremath{\sim}3$, allowing for an exponential suppression in the number of cycles. We use interleaved randomized benchmarking on the qubit subspace to show that this pumping procedure has negligible side effects on the qubit subspace, bounding the induced qubit memory error by $\ensuremath{\le}2.0(8)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}5}\text{ }\text{ }\mathrm{per}$ cycle, and qubit population decay to $\ensuremath{\le}1.4(3)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}7}\text{ }\text{ }\mathrm{per}$ cycle. These results clear a major obstacle for implementations of quantum error correction and error mitigation protocols.
Leakage errors take qubits out of the computational subspace and will accumulate if not addressed. A leaked qubit will reduce the effectiveness of quantum error correction protocols due to the cost of implementing leakage reduction circuits and the harm caused by interacting leaked states with qubit states. Ion trap qubits driven by Raman gates have a natural choice between qubits encoded in magnetically insensitive hyperfine states that can leak and qubits encoded in magnetically sensitive Zeeman states of the electron spin that cannot leak. In our previous work, we compared these two qubits in the context of the toric code with a depolarizing leakage error model and found that for magnetic-field noise with a standard deviation less than 32 $\ensuremath{\mu}\mathrm{G}$ that the
174Yb+ Zeeman qubit outperforms the
171Yb+ hyperfine qubit. Here we examine a physically motivated leakage error model based on ions interacting via the M\o{}lmer-S\o{}renson gate. We find that this greatly improves the performance of hyperfine qubits but the Zeeman qubits are more effective for magnetic-field noise with a standard deviation less than 10 $\ensuremath{\mu}\mathrm{G}$. At these low magnetic fields, we find that the best choice is a mixed qubit scheme where the hyperfine qubits are the syndrome qubits and the leakage is handled without the need of an additional leakage reduction circuit.