The main objective of this paper is to introduce a new quantum mechanism of condensates and superconductivity based on a new interpretation of quantum mechanical wavefunctions, and on recent developments in quantum physics and statistical physics. First, we postulate that the wavefunction [Formula: see text]e[Formula: see text] is the common wavefunction for all particles in the same class determined by the external potential V(x), [Formula: see text](x)[Formula: see text] represents the distribution density of the particles, and [Formula: see text] is the velocity field of the particles. Although the new interpretation does not alter the basic theories of quantum mechanics, it is an entirely different interpretation from the classical Bohr interpretation, removes all absurdities and offers new insights for quantum physics and for condensed matter physics. Second, we show that the key for condensation of bosonic particles is that their interaction is sufficiently weak to ensure that a large collection of boson particles are in a state governed by the same condensation wavefunction field [Formula: see text] under the same bounding potential V. For superconductivity, the formation of superconductivity comes down to conditions for the formation of electron pairs, and for the electron pairs to share a common wavefunction. Thanks to the recently developed principle of interaction dynamics (PID) interaction potential of electrons and the average-energy level formula of temperature, these conditions for superconductivity are explicitly derived. Furthermore, we obtain both microscopic and macroscopic formulas for the critical temperature. The field and topological phase transition equations for condensates are also derived.
The main objective of this paper is to introduce a new quantum mechanism of condensates and superconductivity based on a new interpretation of quantum mechanical wavefunctions, and on recent developments in quantum physics and statistical physics. First, we postulate that the wavefunction [Formula: see text]e[Formula: see text] is the common wavefunction for all particles in the same class determined by the external potential V(x), Formula: see text[Formula: see text] represents the distribution density of the particles, and [Formula: see text] is the velocity field of the particles. Although the new interpretation does not alter the basic theories of quantum mechanics, it is an entirely different interpretation from the classical Bohr interpretation, removes all absurdities and offers new insights for quantum physics and for condensed matter physics. Second, we show that the key for condensation of bosonic particles is that their interaction is sufficiently weak to ensure that a large collection of boson particles are in a state governed by the same condensation wavefunction field [Formula: see text] under the same bounding potential V. For superconductivity, the formation of superconductivity comes down to conditions for the formation of electron pairs, and for the electron pairs to share a common wavefunction. Thanks to the recently developed principle of interaction dynamics (PID) interaction potential of electrons and the average-energy level formula of temperature, these conditions for superconductivity are explicitly derived. Furthermore, we obtain both microscopic and macroscopic formulas for the critical temperature. The field and topological phase transition equations for condensates are also derived.
Bose-Einstein condensation, superfluidity, and superconductivity are quantum mechanics made visible. They mark the boundary between the classical and the quantum worlds, and they show the macroscopic role of quantum mechanics in condensed matter. This book presents these phenomena in terms of particles, their positions, and their momenta, giving a concrete visualisation and description that is not possible with traditional wave functions. A single approach that bridges the classical-quantum divide provides new insight into the role of particle interactions in condensation, the nature of collisions in superfluid flow, and the physical form of Cooper pairs in high-temperature superconductors. High-temperature superconductivity is explored with quantum statistical mechanics, which links it to Bose-Einstein condensation. Identifying a new mechanism for Cooper pairing, this explains the differences between the low- and high-temperature superconducting regimes and the role of the molecular structure of the conductor. The new perspective offered by this book on Bose-Einstein condensation, superfluidity, and high-temperature superconductivity gives particle-based explanations as well as mathematical and computational methods for these macroscopic quantum phenomena so that readers understand the role of particle interactions and structure in the physics of these phenomena. This book will appeal to undergraduate and graduate students, lecturers, academics, and scientific researchers in the fields of Bose-Einstein condensation and condensates, superfluidity, and superconductivity. It will also be of interest to those working with thermodynamics, statistical mechanics, statistical physics, quantum mechanics, molecular dynamics, materials science, condensed matter physics, and theoretical chemistry. Key Features: · Explores Bose-Einstein condensation with new evidence for multiple condensed states and novel Monte Carlo simulations for interacting bosons · Establishes the thermodynamic nature of condensed bosons from an analysis of fountain pressure measurements, including that they carry energy and entropy, and the thermodynamic principle of superfluid flow · Derives equations of motion for condensed bosons, and performs molecular dynamics simulations of the viscosity with molecular trajectories that give rise to superfluidity · Identifies the mechanism for electron pairing in high-temperature superconductivity
Various BCS-like pairing theories are still invariably used to describe the unusual superconducting/superfluid states and properties of condensed matters without clarifying the fermionic or bosonic nature of Cooper pairs and the relevant mechanisms of superconductivity and superfluidity. We show that the bosonization of Cooper pairs and the novel superconductivity and superfluidity resulting from the condensation of an attractive Bose gas of Cooper pairs into a superfluid state in high-Tc cuprates and other exotic systems occur under the condition εF≲2εA (where εF is the Fermi energy, εA is the energy of the effective attraction between fermions). We argue that the simple BCS criterion (i.e. formation of an energy gap on the Fermi surface) is insufficient for the occurrence of unconventional superconductivity (superfluidity) and the superconducting/superfluid transition in attractive Bose systems is more λ-like than the usual Bose–Einstein condensation. The new and specific criteria for unconventional superconductivity and superfluidity are formulated. Mean-field theory of the three- and two-dimensional superfluid Bose condensates of Cooper pairs describes reasonably well the novel superconducting states (i.e., two distinct superconducting phases below the bulk superconducting transition temperature Tc and a vortex-like state above Tc) and properties (such as λ-like transition at Tc, first-order phase transition and gapless bosonic excitations somewhat below Tc or even far below Tc) of high-Tc cuprates in full agreement with the experimental findings. The unusual superconducting/superfluid states and properties of heavy-fermion and organic compounds, Sr2RuO4, 3He, 4He and atomic Fermi gases are explained more clearly by this theory.
Macro-orbital representation of a particle (detailed account given in cond-mat/0603784) has been used to develop the microscopic theory of a system of interacting bosons. It concludes that: (i) below certain temperature (say, Tλ), particles assume a state of (q, -q) bound pairs, (ii) the λ−transition is a consequence of inter-particle quantum correlations clubbed with zero-point repulsion and inter-particle attraction and represents an onset of the order-disorder of particles in their ϕ−space followed simultaneously by their BEC as (q, -q) bound pairs in a state of q = qo=π/d and K = 0, (iii) particles at T≤Tλ acquire collective binding which locks them at = 0, = λ/2 and Δϕ=2nπ (with n = 1, 2, 3, ...), (iv) the entire system assumes mechanical strain in inter-particle bonds and behaves like a single macroscopic molecule, (v) there exists an energy gap between the superfluid and normal fluid phases of the system, (vi) the λ−transition represents the twin phenomena of broken gauge symmetry and phase coherence, (vii) the system does not have p = 0 condensate, (viii) a new kind of quantum quasi-particle "omon" (a phononlike wave of the oscillations of the momentum coordinates of particles) exists in superfluid phase, etc. It explains the properties of He-II, including the origin of quantized vortices, critical velocities, logarithmic singularity of specific heat, etc. at quantitative level and provides microscopic foundation to two fluid theory, Ψ−theory, idea of macroscopic wave function, etc. The framework of the theory can unify the physics of interacting bosons and fermions.
The modern theory of Bose-Einstein condensation, superfluidity, and superconductivity is reviewed. The thermodynamic principle for superfluid flow and the equation of motion for condensed bosons are given. Computer simulations of Lennard-Jones 4He give the λ-transition and the superfluid viscosity. The statistical mechanical theory of high-temperature superconductivity is presented. Critical comparison is made with older approaches, such as ground energy state condensation, irrotational superfluid flow, and the macroscopic wavefunction.
The main objective of this paper is to provide a systematic theoretical study on quantum phase transitions associated with the Bose-Einstein condensates, the superfluidity and the su-perconductivity. First, we indicate that there are only two types of phase transitions: dynamical phase transitions and topologi-cal phase transitions (TPTs). A TPT refers to the transition in its topological structure in the physical space of the system, and quantum phase transitions (QPTs) belong to the category of TPTs. Second, the basic physical characteristics of a QPT are precisely formulated. In particular, a QPT is a transition between quantum states, which are described by the wave functions ψ, and the control parameters are non-thermal. Third, we derive the topological structure equations for QPTs, so that the basic geometric theory of incompressible flows can be readily applied. In particular, a topo-logical index for the supercurrent can be defined, leading to precise information on the topological structure and its transitions in the physical space for the underlying system. Fourth, we derive then the basic theory for different TPTs, leading to transparent physical pictures of various condensates. Finally, we derive the microscopic mechanism for the Meissner effect of superconductivity: below the critical temperature, under the applied magnetic field, spin J = 1 Cooper pairs reversely parallel to the applied field can form and are stable, and the total magnetic moment of all Cooper pairs, together with the surface supercurrent, can cancel out the magnetism induced by the applied field and resists the applied field from entering its body.
A balanced combination of introductory and advanced topics provides a new and unique perspective on the quantum field theory approach to condensed matter physics. Beginning with the basics of these subjects, such as static and vibrating lattices, independent and interacting electrons, the functional formulation for fields and different generating functionals and their roles, this book presents a unified viewpoint illustrating the connections and relationships among various physical concepts and mechanisms. Advanced and newer topics bring the book up to date with current developments and include sections on cuprate and pnictide superconductors, graphene, Weyl semimetals, transition metal dichalcogenides and topological insulators. Finally, well-known subjects such as the quantum Hall effect, superconductivity, Mott and Anderson insulators, and the Anderson–Higgs mechanism are examined within a unifying QFT-CMP approach. Presenting new insights on traditional topics, this text allows graduate students and researchers to master the proper theoretical tools required in a variety of condensed matter physics systems.