Over the last several decades, two theoretical tools have been indispensable in the field of statistical physics. Spontaneous symmetry breaking has allowed for the description of systems which exhibit second order phase transitions, while the eigenstate thermalization hypothesis has provided a theoretical framework for understanding how isolated quantum many-body systems come to thermal equilibrium. In this dissertation, we will explore the compatibility of these two paradigms of theoretical physics.We will begin with a brief introduction to the relevant topics discussed in the main body of the dissertation, along with a brief overview of the numerical tools used in the subsequent investigations.Following this, we will numerically explore the compatibility between spontaneous symmetry breaking and eigenstate thermalization through a sequence of papers which have been previously published by myself and a collection of other authors. We will study the compatibility of these two theoretical frameworks through an exact diagonalization and Quantum Monte Carlo study of the Transverse-Field Ising model, a quantum non-integrable system which, we argue, displays both spontaneous symmetry breaking and eigenstate thermalization.Following this exposition, we will briefly comment on several corollaries which follow from these previously published papers, some of which we are currently preparing to incorporate into future publications. These corollaries largely focus on the subject of time evolution in quantum systems which display both spontaneous symmetry breaking and eigenstate thermalization, as well as the possibility that individual eigenstates of such systems may contain information about the critical behaviour of the corresponding finite-temperature phase transition.
Over the last several decades, two theoretical tools have been indispensable in the field of statistical physics. Spontaneous symmetry breaking has allowed for the description of systems which exhibit second order phase transitions, while the eigenstate thermalization hypothesis has provided a theoretical framework for understanding how isolated quantum many-body systems come to thermal equilibrium. In this dissertation, we will explore the compatibility of these two paradigms of theoretical physics.We will begin with a brief introduction to the relevant topics discussed in the main body of the dissertation, along with a brief overview of the numerical tools used in the subsequent investigations.Following this, we will numerically explore the compatibility between spontaneous symmetry breaking and eigenstate thermalization through a sequence of papers which have been previously published by myself and a collection of other authors. We will study the compatibility of these two theoretical frameworks through an exact diagonalization and Quantum Monte Carlo study of the Transverse-Field Ising model, a quantum non-integrable system which, we argue, displays both spontaneous symmetry breaking and eigenstate thermalization.Following this exposition, we will briefly comment on several corollaries which follow from these previously published papers, some of which we are currently preparing to incorporate into future publications. These corollaries largely focus on the subject of time evolution in quantum systems which display both spontaneous symmetry breaking and eigenstate thermalization, as well as the possibility that individual eigenstates of such systems may contain information about the critical behaviour of the corresponding finite-temperature phase transition.
Understanding how quantum matter behaves when driven out of equilibrium is one of the key focuses in quantum physics. Thanks to impressive progress in the control and precision achieved in quantum synthetic matter over the past decades, the nonequilibrium quantum many-body physics has become one of the most active research areas today, especially after the experimental realization of Bose-Einstein condensates and optical lattices, which allows us to directly observe and study nonequilibrium quantum matter with great accuracy and controllability. In this dissertation, I explore the rich landscape of nonequilibrium quantum many-body physics and how quantum phase transitions, both symmetry-breaking and topological, can be extended to the nonequilibrium setting. In the first part of the dissertation, I focus on spinor Bose-Einstein condensates as an isolated quantum many-body system, and reveal their various dynamical behaviors, including quantum collapse and revivals, thermalization and nonthermal equilibration with no revival even though the system has finite degrees of freedom. In contrast to typical integrable systems, which usually do not thermalize, we find that spinor condensates have a parameter range in which the system thermalizes via the Eigenstate Thermalization Hypothesis (ETH). We show that this observation is linked to the presence of rare nonthermal states whose fraction vanishes with system size, and contributes to the notion of thermalization via weak ETH. Next, I explore a dynamical process that is complementary to thermalization in isolated quantum systems: information scrambling, which could be probed via out-of-time-order correlators (OTOC). I propose a nonintegrable, disordered and quasi-1D spin model, the ladder-XX model, for a feasible detection of information scrambling in a cold atom simulator. This chapter poses a fundamental question: "What are the signatures of quantum phases and phase transitions in isolated interacting systems driven out-of-equilibrium?" I study the ladder-XX model in both clean and disordered potentials, and characterize different nonequilibrium phases, i.e., ergodic and many-body localized, of the model based on the decay properties of OTOCs. Emergent light cone shows sublinear behavior, while the butterfly cones drastically differ from the light cone by demonstrating superlinear spread of information with a velocity that is bounded by the light cone velocity. In the second part of the dissertation, I continue to search for answers to the question posed above, however this time with a particular focus on symmetry-breaking and topological quantum phase transitions. I pin down a universal mechanism underlying the relation between information scrambling at any temperature and quantum phases at low temperatures. Our method points to key ingredients to dynamically detect long-range order in gapped phases through OTOCs for symmetry-breaking quantum phase transitions and Z2 topological order associated with Majorana zero modes localized at the edges. Our results pave the way to an intriguing observation that phases of quantum matter could protect the information from scrambling and thermalization, even when the system is interacting and nonintegrable. Finally, I explore and propose utilizing short-time transient temporal regimes and single-site probes to detect the phases and phase transitions in quantum matter. These studies reveal a dynamical crossover and a dynamical phase transition, respectively for periodic and open-boundary chains. In both cases, a nonequilibrium scaling law appears in the vicinity of the crossover/transition with associated exponents that differ from the analytical predictions for long times. Feasibility of detecting such dynamical criticality in experimental systems are discussed.
A very fundamental problem in quantum statistical mechanics involves whether—and how—an isolated quantum system will reach thermal equilibrium after waiting a long time. In quantum systems that do thermalize, the long-time expectation value of any “reasonable” operator will match its predicted value in the canonical ensemble. The Eigenstate Thermalization Hypothesis (ETH) posits that this thermalization occurs at the level of each individual energy eigenstate; in fact, any single eigenstate in a microcanonical energy window will predict the expectation values of such operators exactly. In the first part of this dissertation, we identify, for a generic model system, precisely which operators satisfy ETH, as well as limits to the information contained in a single eigenstate. Remarkably, our results strongly suggest that a single eigenstate can contain information about energy densities—and therefore temperatures—far away from the energy density of the eigenstate.Additionally, we study the possible breakdown of quantum thermalization in a model of itinerant electrons on a one-dimensional chain, with both spin and charge degrees of freedom. This model exhibits peculiar properties in the entanglement entropy, the apparent scaling of which is modified from a “volume law” to an “area law” after performing a partial, site-wise measurement on the system. These properties and others suggest that this model realizes a new, non-thermal phase of matter, known as a Quantum Disentangled Liquid (QDL). The putative existence of this phase has striking implications for the foundations of quantum statistical mechanics.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
A strongly nonintegrable system is expected to satisfy the eigenstate thermalization hypothesis, which states that the expectation value of an observable in an energy eigenstate is the same as the thermal value. This must be revised if the observable is an order parameter for a spontaneously broken symmetry, which has multiple thermal values. We propose that in this case the system is unstable towards forming nearby eigenstates which yield each of the allowed thermal values. We provide strong evidence for this from a numerical study of the two-dimensional transverse-field quantum Ising model.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
We consider the statistical properties of eigenstates of the time-evolution operator in chaotic many-body quantum systems. Our focus is on correlations between eigenstates that are specific to spatially extended systems and that characterize entanglement dynamics and operator spreading. In order to isolate these aspects of dynamics from those arising as a result of local conservation laws, we consider Floquet systems in which there are no conserved densities. The correlations associated with scrambling of quantum information lie outside the standard framework established by the eigenstate thermalization hypothesis (ETH). In particular, ETH provides a statistical description of matrix elements of local operators between pairs of eigenstates, whereas the aspects of dynamics we are concerned with arise from correlations among sets of four or more eigenstates. We establish the simplest correlation function that captures these correlations and discuss features of its behavior that are expected to be universal at long distances and low energies. We also propose a maximum-entropy ansatz for the joint distribution of a small number n of eigenstates. In the case n = 2 , this ansatz reproduces ETH. For n = 4 it captures both the growth with time of entanglement between subsystems, as characterized by the purity of the time-evolution operator, and also operator spreading, as characterized by the behavior of the out-of-time-order correlator. We test these ideas by comparing results from Monte Carlo sampling of our ansatz with exact diagonalization studies of Floquet quantum circuits. Published by the American Physical Society 2024