A physical system out of thermal equilibrium is a resource for obtaining useful work when a heat bath at some temperature is available. Information Heat Engines are the devices which generalize the Szilard cylinders and make use of the celebrated Maxwell demons to this end. In this paper, we consider a thermo-chemical reservoir of electrons which can be exchanged for entropy and work. Qubits are used as messengers between electron reservoirs to implement long-range voltage transformers with neither electrical nor magnetic interactions between the primary and secondary circuits. When they are at different temperatures, the transformers work according to Carnot cycles. A generalization is carried out to consider an electrical network where quantum techniques can furnish additional security.
A physical system out of thermal equilibrium is a resource for obtaining useful work when a heat bath at some temperature is available. Information Heat Engines are the devices which generalize the Szilard cylinders and make use of the celebrated Maxwell demons to this end. In this paper, we consider a thermo-chemical reservoir of electrons which can be exchanged for entropy and work. Qubits are used as messengers between electron reservoirs to implement long-range voltage transformers with neither electrical nor magnetic interactions between the primary and secondary circuits. When they are at different temperatures, the transformers work according to Carnot cycles. A generalization is carried out to consider an electrical network where quantum techniques can furnish additional security.
There has been considerable progress in generalizing the conventional second law of thermodynamics to take information as an additional parameter. Carnot engine is the standard practical application. One has two systems A and B, both in thermal equilibrium but with different temperatures TA and TB ≥ TA. By second law one has heat flow Q from A to B the two systems, and Carnot's engine transforms some of this heat to work. Carnot's law gives an upper bound for the efficiency of the engine as η ≡ W/Q ≤ (T2-T1)/T2. The possibility to transform information to work forces to generalize Carnot's law. Since information is basically conscious information, this generalization is highly interesting from the point of view of quantum theories of consciousness and quantum biology. Certainly the generalization is highly non-trivial. Especially so in standard physics framework, where only entropy is defined at fundamental level and is regarded as ensemble entropy and basically has very little to do with conscious information. Therefore, the argumentation is kind of art work.
The emerging field of quantum thermodynamics is beginning to reveal the intriguing role that information can play in quantum thermal engines. Information enters as a resource when considering feedback-controlled thermal machines. While both a general theory of quantum feedback control as well as specific examples of quantum feedback-controlled engines have been presented, still lacking is a general framework for such machines. Here, we present a framework for a generic, two-stroke quantum heat engine interacting with N thermal baths and Maxwell's demon. The demon performs projective measurements on the engine working substance, the outcome of which is recorded in a classical memory, embedded in its own thermal bath. To perform feedback control, the demon enacts unitary operations on the working substance, conditioned on the recorded outcome. By considering the compound machine-memory as a hybrid (classical-quantum) standard thermal machine interacting with N+1 thermal baths, our framework puts the working substance and memory on equal footing, thereby enabling a comprehensible resolution to Maxwell's paradox and elucidating the intricate manner in which information impacts the performance of quantum engines. We illustrate the application of our framework with a two-qubit engine. A remarkable observation is that more information does not necessarily result in better thermodynamic performance: sometimes knowing less is better.
We study the physical mechanism of Maxwell's demon (MD), which helps do extra work in thermodynamic cycles with the heat engine. This is exemplified with one molecule confined in an infinitely deep square potential with a movable solid wall. The MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. The processes in the cycle are described in a quantum fashion. It is discovered that a MD with quantum coherence or one at a temperature lower than the molecule's heat bath can enhance the ability of the whole working substance, formed by the heat engine plus the MD, to do work outside. This observation reveals that the essential role of the MD is to drive the whole working substance off equilibrium, or equivalently, to work between two heat baths with different effective temperatures. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts common sense on a Szilard heat engine (SHE). The quantum SHE's efficiency is evaluated in detail to prove the validity of the second law of thermodynamics.
Maxwell’s Demon conspires to use information about the state of a confined molecule in a Szilard engine (randomly frozen into a state subspace by his own actions) to derive work from a single-temperature heat bath. It is widely accepted that, if the Demon can achieve this at all, he can do so without violating the Second Law only because of a counterbalancing price that must be paid to erase information when the Demon’s memory is reset at the end of his operating cycle. In this paper, Maxwell’s Demon is analyzed within a “referential” approach to physical information that defines and quantifies the Demon’s information via correlations between the joint physical state of the confined molecule and that of the Demon’s memory. On this view, which received early emphasis in Fahn’s 1996 classical analysis of Maxwell’s Demon, information is erased not during the memory reset step of the Demon’s cycle, but rather during the expansion step, when these correlations are destroyed. Dissipation and work extraction are analyzed here for a Demon that operates a generalized quantum mechanical Szilard engine embedded in a globally closed composite, which also includes a work reservoir, a heat bath and the remainder of the Demon’s environment. Memory-engine correlations lost during the expansion step, which enable extraction of work from the Demon via operations conditioned on the memory contents, are shown to be dissipative when this decorrelation is achieved unconditionally so no work can be extracted. Fahn’s essential conclusions are upheld in generalized form, and his quantitative results supported via appropriate specialization to the Demon of his classical analysis, all without external appeal to classical thermodynamics, the Second Law, phase space conservation arguments or Landauer’s Principle.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
The second law of thermodynamics states that the entropy of a closed system is nondecreasing. Discussing the second law in the quantum world poses different challenges and provides different opportunities, involving fundamental quantum-information-theoretic questions and interesting quantum-engineered devices. In quantum mechanics, systems with an evolution described by a so-called unital quantum channel evolve with a nondecreasing entropy. Here, we seek the opposite, a system described by a nonunital and, furthermore, energy-conserving channel that describes a system whose entropy decreases with time. We propose a setup involving a mesoscopic four-lead scatterer augmented by a microenvironment in the form of a spin that realizes this goal. Within this nonunital and energy-conserving quantum channel, the microenvironment acts with two noncommuting operations on the system in an autonomous way. We find that the process corresponds to a partial exchange or swap between the system and environment quantum states, with the system's entropy decreasing if the environment's state is more pure. This entropy-decreasing process is naturally expressed through the action of a quantum Maxwell demon and we propose a quantum-thermodynamic engine with four qubits that extracts work from a single heat reservoir when provided with a reservoir of pure qubits. The special feature of this engine, which derives from the energy conservation in the nonunital quantum channel, is its separation into two cycles, a working cycle and an entropy cycle, allowing us to run this engine with no local waste heat.