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arXiv:quant-ph/0508161 · Physical Review Letters

The Second Law, Maxwell's Demon, and Work Derivable from Quantum Heat Engines

Tien D. Kieu

Published Sep 29, 2004• 373 citations
arXivHTMLPDF

Abstract

With a class of quantum heat engines which consists of two-energy-eigenstate systems undergoing, respectively, quantum adiabatic processes and energy exchanges with heat baths at different stages of a cycle, we are able to clarify some important aspects of the second law of thermodynamics. The quantum heat engines also offer a practical way, as an alternative to Szilard's engine, to physically realize Maxwell's demon. While respecting the second law on the average, they are also capable of extracting more work from the heat baths than is otherwise possible in thermal equilibrium.

DOI
10.1103/physrevlett.93.140403

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With a class of quantum heat engines which consists of two-energy-eigenstate systems undergoing, respectively, quantum adiabatic processes and energy exchanges with heat baths at different stages of a cycle, we are able to clarify some important aspects of the second law of thermodynamics. The quantum heat engines also offer a practical way, as an alternative to Szilard's engine, to physically realize Maxwell's demon. While respecting the second law on the average, they are also capable of extracting more work from the heat baths than is otherwise possible in thermal equilibrium.
We study the physical mechanism of Maxwell's demon (MD), which helps do extra work in thermodynamic cycles with the heat engine. This is exemplified with one molecule confined in an infinitely deep square potential with a movable solid wall. The MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. The processes in the cycle are described in a quantum fashion. It is discovered that a MD with quantum coherence or one at a temperature lower than the molecule's heat bath can enhance the ability of the whole working substance, formed by the heat engine plus the MD, to do work outside. This observation reveals that the essential role of the MD is to drive the whole working substance off equilibrium, or equivalently, to work between two heat baths with different effective temperatures. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts common sense on a Szilard heat engine (SHE). The quantum SHE's efficiency is evaluated in detail to prove the validity of the second law of thermodynamics.
The Szilard engine (SZE) is the quintessence of Maxwell's demon, which can extract the work from a heat bath by utilizing information. We present the first complete quantum analysis of the SZE, and derive an analytic expression of the quantum-mechanical work performed by a quantum SZE containing an arbitrary number of molecules, where it is crucial to regard the process of insertion or removal of a wall as a legitimate thermodynamic process. We find that more (less) work can be extracted from the bosonic (fermionic) SZE due to the indistinguishability of identical particles.
In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quantum thermodynamic cycles. We find that there is no violation of the second law, even in the existence of such a demon, when the demon is included correctly as part of the working substance of the heat engine.
The Szilard engine (SZE) is the quintessence of Maxwell's demon, which can extract the work from a heat bath by utilizing information.We present the first complete quantum analysis of the SZE, and derive an analytic expression of the quantum-mechanical work performed by a quantum SZE containing an arbitrary number of molecules, where it is crucial to regard the process of insertion or removal of a wall as a legitimate thermodynamic process.We find that more (less) work can be extracted from the bosonic (fermionic) SZE due to the indistinguishability of identical particles.
The Szilard engine (SZE) is the quintessence of Maxwell's demon, which can extract the work from a heat bath by utilizing information. We present the first complete quantum analysis of the SZE, and derive an analytic expression of the quantum-mechanical work performed by a quantum SZE containing an arbitrary number of molecules, where it is crucial to regard the process of insertion or removal of a wall as a legitimate thermodynamic process. We find that more (less) work can be extracted from the bosonic (fermionic) SZE due to the indistinguishability of identical particles.
The second law of thermodynamics states that the entropy of a closed system is nondecreasing. Discussing the second law in the quantum world poses different challenges and provides different opportunities, involving fundamental quantum-information-theoretic questions and interesting quantum-engineered devices. In quantum mechanics, systems with an evolution described by a so-called unital quantum channel evolve with a nondecreasing entropy. Here, we seek the opposite, a system described by a nonunital and, furthermore, energy-conserving channel that describes a system whose entropy decreases with time. We propose a setup involving a mesoscopic four-lead scatterer augmented by a microenvironment in the form of a spin that realizes this goal. Within this nonunital and energy-conserving quantum channel, the microenvironment acts with two noncommuting operations on the system in an autonomous way. We find that the process corresponds to a partial exchange or swap between the system and environment quantum states, with the system's entropy decreasing if the environment's state is more pure. This entropy-decreasing process is naturally expressed through the action of a quantum Maxwell demon and we propose a quantum-thermodynamic engine with four qubits that extracts work from a single heat reservoir when provided with a reservoir of pure qubits. The special feature of this engine, which derives from the energy conservation in the nonunital quantum channel, is its separation into two cycles, a working cycle and an entropy cycle, allowing us to run this engine with no local waste heat.