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Entropy

Conditioning, Correlation and Entropy Generation in Maxwell’s Demon

Neal G. Anderson

Published Oct 9, 2013• 4 citations

Abstract

Maxwell’s Demon conspires to use information about the state of a confined molecule in a Szilard engine (randomly frozen into a state subspace by his own actions) to derive work from a single-temperature heat bath. It is widely accepted that, if the Demon can achieve this at all, he can do so without violating the Second Law only because of a counterbalancing price that must be paid to erase information when the Demon’s memory is reset at the end of his operating cycle. In this paper, Maxwell’s Demon is analyzed within a “referential” approach to physical information that defines and quantifies the Demon’s information via correlations between the joint physical state of the confined molecule and that of the Demon’s memory. On this view, which received early emphasis in Fahn’s 1996 classical analysis of Maxwell’s Demon, information is erased not during the memory reset step of the Demon’s cycle, but rather during the expansion step, when these correlations are destroyed. Dissipation and work extraction are analyzed here for a Demon that operates a generalized quantum mechanical Szilard engine embedded in a globally closed composite, which also includes a work reservoir, a heat bath and the remainder of the Demon’s environment. Memory-engine correlations lost during the expansion step, which enable extraction of work from the Demon via operations conditioned on the memory contents, are shown to be dissipative when this decorrelation is achieved unconditionally so no work can be extracted. Fahn’s essential conclusions are upheld in generalized form, and his quantitative results supported via appropriate specialization to the Demon of his classical analysis, all without external appeal to classical thermodynamics, the Second Law, phase space conservation arguments or Landauer’s Principle.

DOI: 10.3390/e15104243

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Maxwell’s Demon conspires to use information about the state of a confined molecule in a Szilard engine (randomly frozen into a state subspace by his own actions) to derive work from a single-temperature heat bath. It is widely accepted that, if the Demon can achieve this at all, he can do so without violating the Second Law only because of a counterbalancing price that must be paid to erase information when the Demon’s memory is reset at the end of his operating cycle. In this paper, Maxwell’s Demon is analyzed within a “referential” approach to physical information that defines and quantifies the Demon’s information via correlations between the joint physical state of the confined molecule and that of the Demon’s memory. On this view, which received early emphasis in Fahn’s 1996 classical analysis of Maxwell’s Demon, information is erased not during the memory reset step of the Demon’s cycle, but rather during the expansion step, when these correlations are destroyed. Dissipation and work extraction are analyzed here for a Demon that operates a generalized quantum mechanical Szilard engine embedded in a globally closed composite, which also includes a work reservoir, a heat bath and the remainder of the Demon’s environment. Memory-engine correlations lost during the expansion step, which enable extraction of work from the Demon via operations conditioned on the memory contents, are shown to be dissipative when this decorrelation is achieved unconditionally so no work can be extracted. Fahn’s essential conclusions are upheld in generalized form, and his quantitative results supported via appropriate specialization to the Demon of his classical analysis, all without external appeal to classical thermodynamics, the Second Law, phase space conservation arguments or Landauer’s Principle.

We study the physical mechanism of Maxwell's demon (MD), which helps do extra work in thermodynamic cycles with the heat engine. This is exemplified with one molecule confined in an infinitely deep square potential with a movable solid wall. The MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. The processes in the cycle are described in a quantum fashion. It is discovered that a MD with quantum coherence or one at a temperature lower than the molecule's heat bath can enhance the ability of the whole working substance, formed by the heat engine plus the MD, to do work outside. This observation reveals that the essential role of the MD is to drive the whole working substance off equilibrium, or equivalently, to work between two heat baths with different effective temperatures. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts common sense on a Szilard heat engine (SHE). The quantum SHE's efficiency is evaluated in detail to prove the validity of the second law of thermodynamics.

We analyze an engine whose working fluid consists of a single quantum particle, paralleling Szilard's construction of a classical single-particle engine. Following his resolution of Maxwell's Second Law paradox using the latter, which turned on physically instantiating the demon (control subsystem), the quantum engine's design mirrors the classically-chaotic Szilard Map that operates a thermodynamic cycle of measurement, thermal-energy extraction, and memory reset. Focusing on the thermodynamic costs to observe and control the particle and comparing these in the quantum and classical limits, we detail the thermodynamic tradeoffs behind Landauer's Principle for information-processing-induced thermodynamic dissipation in the quantum and classical regimes. In particular, and as found with the classical engine, we show that the sum of the thermodynamic costs over a cycle obeys a generalized Landauer Principle, exactly balancing energy extraction from the heat bath. Thus, the quantum engine obeys the Second Law. However, the quantum engine does so via substantially different mechanisms: classically measurement and erasure determine the thermodynamics, while in the quantum implementation the cost of partition insertion is key.

The second law of thermodynamics states that the entropy of a closed system is nondecreasing. Discussing the second law in the quantum world poses different challenges and provides different opportunities, involving fundamental quantum-information-theoretic questions and interesting quantum-engineered devices. In quantum mechanics, systems with an evolution described by a so-called unital quantum channel evolve with a nondecreasing entropy. Here, we seek the opposite, a system described by a nonunital and, furthermore, energy-conserving channel that describes a system whose entropy decreases with time. We propose a setup involving a mesoscopic four-lead scatterer augmented by a microenvironment in the form of a spin that realizes this goal. Within this nonunital and energy-conserving quantum channel, the microenvironment acts with two noncommuting operations on the system in an autonomous way. We find that the process corresponds to a partial exchange or swap between the system and environment quantum states, with the system's entropy decreasing if the environment's state is more pure. This entropy-decreasing process is naturally expressed through the action of a quantum Maxwell demon and we propose a quantum-thermodynamic engine with four qubits that extracts work from a single heat reservoir when provided with a reservoir of pure qubits. The special feature of this engine, which derives from the energy conservation in the nonunital quantum channel, is its separation into two cycles, a working cycle and an entropy cycle, allowing us to run this engine with no local waste heat.

The Szilard engine (SZE) is the quintessence of Maxwell's demon, which can extract the work from a heat bath by utilizing information.We present the first complete quantum analysis of the SZE, and derive an analytic expression of the quantum-mechanical work performed by a quantum SZE containing an arbitrary number of molecules, where it is crucial to regard the process of insertion or removal of a wall as a legitimate thermodynamic process.We find that more (less) work can be extracted from the bosonic (fermionic) SZE due to the indistinguishability of identical particles.

Quantum Szilard engine constitutes an adequate interplay of thermodynamics, information theory and quantum mechanics. Szilard engines are in general operated by a Maxwell's Demon where Landauer's principle resolves the apparent paradoxes. Here we propose a Szilard engine setup without featuring an explicit Maxwell's demon. In a demonless Szilard engine, the acquisition of which-side information is not required, but the erasure and related heat dissipation still take place implicitly. We explore a quantum Szilard engine considering quantum size effects. We see that insertion of the partition does not localize the particle to one side, instead creating a superposition state of the particle being in both sides. To be able to extract work from the system, particle has to be localized at one side. The localization occurs as a result of quantum measurement on the particle, which shows the importance of the measurement process regardless of whether one uses the acquired information or not. In accordance with Landauer's principle, localization by quantum measurement corresponds to a logically irreversible operation and for this reason it must be accompanied by the corresponding heat dissipation. This shows the validity of Landauer's principle even in quantum Szilard engines without Maxwell's demon.

The Szilard engine (SZE) is the quintessence of Maxwell's demon, which can extract the work from a heat bath by utilizing information. We present the first complete quantum analysis of the SZE, and derive an analytic expression of the quantum-mechanical work performed by a quantum SZE containing an arbitrary number of molecules, where it is crucial to regard the process of insertion or removal of a wall as a legitimate thermodynamic process. We find that more (less) work can be extracted from the bosonic (fermionic) SZE due to the indistinguishability of identical particles.