From the hypotheses that the position-representation of a physical state is the Fourier transform of its momentum-representation and that the timerepresentation is the inverse Fourier transform of its energy-representation, we are able to obtain the Planck relation E = hν , the de Broglie relation p = h /λ , the Dirac fundamental commutation relation, the Schr?dinger equations, the Heisenberg uncertainty principle in quantum mechanics, and the annihilation/creation of a photon from excitation/de-excitation of an atom following Bohr.
From the hypotheses that the position-representation of a physical state is the Fourier transform of its momentum-representation and that the timerepresentation is the inverse Fourier transform of its energy-representation, we are able to obtain the Planck relation E = hν , the de Broglie relation p = h /λ , the Dirac fundamental commutation relation, the Schr?dinger equations, the Heisenberg uncertainty principle in quantum mechanics, and the annihilation/creation of a photon from excitation/de-excitation of an atom following Bohr.
Based on the hypothesis that the position-representation of a physical state <x|α> is the Fourier transform of its momentum-representation <P|α> and that the time-representation <t|α> is the inverse Fourier transform of its energy-representation <E|α>, we are able to find the Planck relation E = hv, the de Broglie relation P = λh. Afterward, utilizing the Dirac delta function δ(x) and the property FTxf(x) = -iℏ∂, pFTxf(x) = -iℏ∂, pF(p) we obtain the links between operators in ordinary and Hilbert spaces leading to the Dirac fundamental commutation relation [p^,x^] = -iℏI^, the Schrödinger equations, the Heisenberg uncertainty principle in quantum mechanics, the annihilation & creation of a photon from excitation & de-excitation of an atom according to Bohr.
In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems. Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.
We propose six principles as the fundamental principles of quantum mechanics: principle of space and time, Galilean principle of relativity, Hamilton's principle, wave principle, probability principle, and principle of indestructibility and increatiblity of particles. We deductively develop the formalism of quantum mechanics on the basis of them: we determine the form of the Lagrangian that satisfies requirements of these principles, and obtain the Schroedinger equation from the Lagrangian. We also derive the canonical commutation relations. Then we adopt the following four guide lines. First, we do not premise the relations between dynamical variables in classical mechanics. Second, we define energy, momentum, and angular momentum as the constants of motion that are derived from homogeneity and isotropy in space and time on the basis of principle of space and time. Since energy and momentum are quantitatively defined in classical mechanics, we define them in quantum mechanics so that the corresponding conservation laws are satisfied in a coupling system of a quantum particle and a classical particle. Third, we define Planck's constant and the mass of a particle as proportionality constants between energy and frequency due to one of Einstein-de Broglie formulas and between momentum and velocity, respectively. We shall obtain the canonical commutation relations and the Schroedinger equation for a particle in an external field in the definitive form. We shall also prove that relations between dynamical variables in quantum mechanics have the same forms for those in classical mechanics.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.