Based on the hypothesis that the position-representation of a physical state <x|\(\alpha\)> is the Fourier transform of its momentum-representation <P|\(\alpha\)> and that the time-representation <t|\(\alpha\)> is the inverse Fourier transform of its energy-representation <E|\(\alpha\)>, we are able to find the Planck relation E = hv, the de Broglie relation P = \(\frac{h}{\lambda}\). Afterward, utilizing the Dirac delta function \(\delta\)(x) and the property FTxf(x) = -i\(\hbar\)\(\partial\), pFTxf(x) = -i\(\hbar\)\(\partial\), pF(p) we obtain the links between operators in ordinary and Hilbert spaces leading to the Dirac fundamental commutation relation [\(\hat{p}, \hat{x}\)] = -i\(\hbar\)\(\hat{I}\), the Schrödinger equations, the Heisenberg uncertainty principle in quantum mechanics, the annihilation & creation of a photon from excitation & de-excitation of an atom according to Bohr.
Based on the hypothesis that the position-representation of a physical state <x|(\alpha)> is the Fourier transform of its momentum-representation <P|(\alpha)> and that the time-representation <t|(\alpha)> is the inverse Fourier transform of its energy-representation <E|(\alpha)>, we are able to find the Planck relation E = hv, the de Broglie relation P = (\frac{h}{\lambda}). Afterward, utilizing the Dirac delta function (\delta)(x) and the property FTxf(x) = -i(\hbar)(\partial), pFTxf(x) = -i(\hbar)(\partial), pF(p) we obtain the links between operators in ordinary and Hilbert spaces leading to the Dirac fundamental commutation relation [(\hat{p}, \hat{x})] = -i(\hbar)(\hat{I}), the Schrödinger equations, the Heisenberg uncertainty principle in quantum mechanics, the annihilation & creation of a photon from excitation & de-excitation of an atom according to Bohr.
From the hypotheses that the position-representation of a physical state is the Fourier transform of its momentum-representation and that the timerepresentation is the inverse Fourier transform of its energy-representation, we are able to obtain the Planck relation E = hν , the de Broglie relation p = h /λ , the Dirac fundamental commutation relation, the Schr?dinger equations, the Heisenberg uncertainty principle in quantum mechanics, and the annihilation/creation of a photon from excitation/de-excitation of an atom following Bohr.
This paper is a small discussion about the uncertainty principle. With the great discoveries and researches made by predecessors, I try to answer some questions within the uncertainty principle. Using the definition of momentum, the momentum in de Broglie wave, the property of cosine function, the Euler’s formula, the basic property of plane wave, the law of derivative, the energy of quantum discovered by Max Planck, the photon energy discovered by Albert Einstein, the energy equation of a system and the Hamiltonian operator, I figure out the Schrodinger equation successfully. With the help of Schrodinger equation, the possibility density of a wave function, the concept of normalization, the average value of position and momentum, the Fourier transform, the integration by parts and the limit of normalized wave functions, I find the position operator and the momentum operator. Then using some knowledge of the standard deviation and the variance, the concept of inner product of vectors, some property of Dirac symbol, the law of calculation of complex number and the law of operator calculation, I obtain the general uncertainty relationship of abstract mathematical quantities. According to the general relationship, I get the inequality of uncertainty principle, and discuss the specific relationship between the position and the momentum. After getting the inequality, I use Heisenberg’s experiment of measuring an electron by using the γ ray to hit the electron to explain why we cannot measure the position and the momentum simultaneously. Based on Heisenberg’s experiment, I give my own explanation by discussing the earth and a spacecraft. Transforming the perspective, we can easily see how the accuracies of position and momentum change. In addition, I attempt to figure out why the uncertainty exists. However, I can only explain it by discussing the time and frequency in mathematical method and have no idea to work it out in a pure physics approach.
In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems. Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.
Toward the end of the nineteenth century, it became clear that some experiments cannot be explained on the basis of known physics, now referred to as classical physics. In 1900, Max Planck was able to correctly describe the distribution of blackbody radiation energy as a function of wavelength λ or frequency ν = c/λ. He had to accept the existence of energy packets (quanta) with energy E = hν. A few years later, Albert Einstein found that this unexpected relation between energy and frequency is also necessary in order to understand photoemission from metallic surfaces. A decade later, Niels Bohr arrived at the correct equation for the electronic spectrum of the hydrogen atom by applying “quantum conditions” on the motion of the electron around the nucleus and the Planck’s relation E = hν on the energy difference between the energy levels (1916). A decade later, Heisenberg, Born, and Jordan introduced “quantum mechanics” and de Broglie and Schrödinger (1925-1926) introduced “wave mechanics.”
I consider in this book a formulation of Quantum Mechanics. Usually QM is formulated based on the notion of time and space, both of which are thought a priori given quantities or notions. However, when we try to define the notion of velocity or momentum, we encounter a difficulty as we will see in chapter 1. The problem is that if the notion of time is given a priori, the velocity is definitely determined when given a position, which contradicts the uncertainty principle of Heisenberg. We then set the basis of QM on the notion of position and momentum operators as in chapter 2. Time of a local system then is defined approximately as a ratio ∣x∣/∣v∣ between the space coordinate x and the velocity v. In this formulation of QM, we can keep the uncertainty principle, and time is a quantity that does not have precise values unlike the usually supposed notion of time has. The feature of local time is that it is a time proper to each local system, which is defined as a finite set of quantum mechanical particles. We now have an infinite number of local times that are unique and proper to each local system. Based on the notion of local time, the motion inside a local system is described by the usual Schrodinger equation. We investigate such motion in a given local system in part II. This is a usual quantum mechanics. After some excursion of the investigation of local motion, we consider in part III the relative relation or motion between plural local systems. In the final part IV, we will prove that there is at least one Universe wave function ϕ in which all local systems have local motions and thus local times. This concludes our formulation of Quantum Mechanics.