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International Journal of Quantum Chemistry

New quantization rules for dissipative systems

Ilya Prigogine, Christophe George

Published Jan 1, 1977• 7 citations
OpenAlex

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In the present paper we propose a method of quantization of mechanical systems that is applicable, inter alia, to systems acted on by nonconservative forces, such as dissipative systems. First, the correspondence between classical and quantum mechanics is considered and we make some important observations that can be used in defining the rules of quantization. Next, the quantization rules are presented and we give a few examples of the application of these rules to mechanical systems that are difficult to quantize within any other systemetic approach. Finally, it is shown that for any quantum-mechanical system there are stationary solutions of the evolution equations, and that the existence of these solutions is directly related to the proposed quantization rules.
Based on the exact quantization rule for the nonrelativistic Schrodinger equation, the exact quantization rule for the relativistic one-dimensional Klein-Gordon equation is suggested. Using the new quantization rule, the exact relativistic energies for exactly solvable potentials, e.g. harmonic oscillator, Morse, and Rosen-Morse II type potentials, are obtained. Consequently the new quantization rule is found to be exact for one-dimensional spinless relativistic quantum systems. Though the physical meanings of the new quantization rule have not been fully understood yet, the present formal derivation scheme may shed light on understanding relativistic quantum systems more deeply.