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Bulletin of the Korean Chemical Society

Quantization Rule for Relativistic Klein-Gordon Equation

Hosung Sun

Published Dec 20, 2011• 15 citations
Publisher

Abstract

Based on the exact quantization rule for the nonrelativistic Schrodinger equation, the exact quantization rule for the relativistic one-dimensional Klein-Gordon equation is suggested. Using the new quantization rule, the exact relativistic energies for exactly solvable potentials, e.g. harmonic oscillator, Morse, and Rosen-Morse II type potentials, are obtained. Consequently the new quantization rule is found to be exact for one-dimensional spinless relativistic quantum systems. Though the physical meanings of the new quantization rule have not been fully understood yet, the present formal derivation scheme may shed light on understanding relativistic quantum systems more deeply.

DOI
10.5012/bkcs.2011.32.12.4233

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Based on the exact quantization rule for the nonrelativistic Schrodinger equation, the exact quantization rule for the relativistic one-dimensional Klein-Gordon equation is suggested. Using the new quantization rule, the exact relativistic energies for exactly solvable potentials, e.g. harmonic oscillator, Morse, and Rosen-Morse II type potentials, are obtained. Consequently the new quantization rule is found to be exact for one-dimensional spinless relativistic quantum systems. Though the physical meanings of the new quantization rule have not been fully understood yet, the present formal derivation scheme may shed light on understanding relativistic quantum systems more deeply.
Quantum relativistic solutions for a particle in a one-dimensional Morse potential are presented using methods previously proposed and applied to a particle in a harmonic oscillator. The methods lead to both numerical and analytical solutions, with the latter allowing smooth variation of the system parameters from non-relativistic to ultrarelativistic limits. Analytical expressions for the energy levels and wavefunctions are obtained, as solutions to a Schrödinger-type equation, including relativistic effects through a state dependent rescaled mass. The eigenstates of the Morse potential exhibit suitable and smooth behavior, and approach the corresponding harmonic oscillator solutions as the depth of the Morse potential well increases, as expected. A comparison is also presented between the relativistic harmonic oscillator obtained with this method, and the so-called Klein-Gordon oscillator.
Abstract. – An exact quantization rule for the Schrödinger equation is presented. In the exact quantization rule, in addition to Nπ, there is an integral term, called the quantum correction. For the exactly solvable systems we find that the quantum correction is an invariant, independent of the number of nodes in the wave function. In those systems, the energy levels of all the bound states can be easily calculated from the exact quantization rule and the solution for the ground state, which can be obtained by solving the Riccati equation. With this new method, we re-calculate the energy levels for the one-dimensional systems with a finite square well, with the Morse potential, with the symmetric and asymmetric Rosen-Morse potentials, and with the first and the second Pöschl-Teller potentials, for the harmonic oscillators both in one dimension and in three dimensions, and for the hydrogen atom. In the development of quantum mechanics, the Bohr-Sommerfeld quantization rules of the old quantum theory [1] occupy a position intermediate between classical and quantum mechanics. The WKB approximation [2–4] is a method for the approximate treatment of the Schrödinger wave function with another quantization rule [1]. Both quantization rules are approximate. We are going to derive an exact quantization rule for the one-dimensional Schrödinger equation: d2 ψ(x) = −2M dx2 2 [E − V (x)] ψ(x), (1) ¯h where M is the mass of the particle, and the potential V (x) is a piecewise continuous real function of x satisfying for definiteness V (x)> E, − ∞ < x < xA or xB < x < ∞, V (x) = E, x = xA or x = xB, V (x) < E, xA < x < xB, (2) where xA and xB are two turning points. Between two turning points, the momentum is k(x) = √ 2M [E − V (x)]/¯h.
The Klein Gordon equation for the harmonic oscillator may be written as (E-.5kx2)2=p2+mo2 ((1)) where mo is the rest mass and p the relativistic momentum. In the literature, it is argued that the resulting x4 term dominates for large x and prevents the Klein Gordon equation from being solved for bound states. As a result, it is replaced with an equation of the form: (E2-mo2) = (p-imwx)(p+imw) ((2)) where p=-ihbar d/dx in one dimension which may be solved exactly. Recently, the authors of (1) have used perturbation theory to calculate energy changes to ((1)) by using -.5V2 - e2 +2eV as a perturbative potential where V=.5kx2 and E=e+mo. They utilise the unperturbed wavefunction exp(-ax2) so large x4 values are damped. Their results are close to the exact calculations of ((2)) for the case of k=1 and m=1. In this note, we argue that for an oscillator there are classical turning points at which the quantum average kinetic energy -1/2m d/dx d/dx W should be zero and small nearby even if the average kinetic energy near x=0 corresponds to relativistic momenta. Thus, it is argued there are different spatial regions, each with its own quantum equation. The Schrodinger equation may be applied to regions near the classical turning point moving to infinite. In such a case, there is no issue with an x4 term. Near x=0, the full Klein Gordon equation ((1)) may be applied. There are questions of then matching the two sets of solutions. In this note, we attempt to investigate this scenario and compare results with those of (1) and (2). (1) and (2) suggest similar relativistic corrections to the nonrelativistic ground state oscillator energy of more than 20%. In this note, we suggest a smaller value.
A new relativistic quantum wave equation has been derived by applying the quantum prescription to the momentum and the kinetic energy rather than to the momentum and the total energy, since after all it is the kinetic energy that generates the momentum. The resulting equation reduces to the Schrodinger equation in the nonrelativistic limit and to the Klein-Gordon equation for “massless particles” in the relativistic limit, i.e., if the velocity of the particle approaches that of light, c. For massive particles in general, the new equation deviates from the Klein-Gordon equation. The same equation is shown to decouple according to the Dirac formalism, yielding a modified form of Dirac equation. When applied to a rest particle, the modified Dirac equation is shown to avoid a negative energy solution and instead include a constant solution. The other, the time-dependent particle solution of the modified Dirac equation, has the characteristic frequency Mc2/(ћ/2) , i.e., twice those of the Dirac solutions, Mc2/ћ.
Abstract Using the proper quantization rule, we investigate the exact solution of Dirac equation for Hartmann and the ring-shaped non-spherical harmonic oscillator potentials under the condition of equal scalar and vector potentials. By considering the proper quantization condition within angular and radial variables, the exact relativistic energy spectra are obtained for each system. Then by the mean of suitable changes of variables, the corresponding spinor wave-functions are constructed where the normalization constants are exactly calculated. We also derived the non-relativistic limit of energy spectra.