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Nonuniform Bose Gases at Zero Temperature

Лев П. Питаевский, S. Stringari

Published Jan 1, 2016• 1 citation
Publisher

Abstract

Abstract This chapter develops the theory of weakly interacting nonuniform Bose gases at zero temperature. Interaction effects are accounted for by a single coupling constant fixed by the value of the s-wave scattering length. The nonlinear Gross–Pitaevskii equation is derived in both the stationary and time-dependent cases. The irrotational nature of the flow and the crucial role played by the chemical potential are highlighted. The classical nature of the equation is emphasized and the analogy with the Maxwell equations of classical electrodynamics is pointed out. The stationary solutions of the Gross–Pitaevskii equation, corresponding to quantized vortex lines, vortex rings, and solitons, are discussed. The time-dependent solutions corresponding to small-amplitude oscillations are derived and the corresponding dispersion relation is shown to coincide with the predictions of Bogoliubov theory for uniform media. The Thomas–Fermi limit is also discussed.

DOI
10.1093/acprof:oso/9780198758884.003.0005

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Abstract This chapter develops the theory of weakly interacting nonuniform Bose gases at zero temperature. Interaction effects are accounted for by a single coupling constant fixed by the value of the s-wave scattering length. The nonlinear Gross–Pitaevskii equation is derived in both the stationary and time-dependent cases. The irrotational nature of the flow and the crucial role played by the chemical potential are highlighted. The classical nature of the equation is emphasized and the analogy with the Maxwell equations of classical electrodynamics is pointed out. The stationary solutions of the Gross–Pitaevskii equation, corresponding to quantized vortex lines, vortex rings, and solitons, are discussed. The time-dependent solutions corresponding to small-amplitude oscillations are derived and the corresponding dispersion relation is shown to coincide with the predictions of Bogoliubov theory for uniform media. The Thomas–Fermi limit is also discussed.
In the present chapter we consider the structure of the Bose–Einstein condensed state in the presence of interactions. Our discussion is based on the Gross–Pitaevskii equation, which describes the zero-temperature properties of the non-uniform Bose gas when the scattering length a is much less than the mean interparticle spacing. We shall first derive the Gross–Pitaevskii equation at zero temperature by treating the interaction between particles in a mean-field approximation (Sec. 6.1). Following that, in Sec. 6.2 we discuss the ground state of atomic clouds in a harmonic-oscillator potential. We compare results obtained by variational methods with those derived in the Thomas-Fermi approximation, in which the kinetic energy operator is neglected in the Gross–Pitaevskii equation. The Thomas–Fermi approximation fails near the surface of a cloud, and in Sec. 6.3 we calculate the surface structure using the Gross–Pitaevskii equation. Finally, in Sec. 6.4 we determine how the condensate wave function ‘heals’ when subjected to a localized disturbance. The Gross–Pitaevskii equation In the previous chapter we have shown that the effective interaction between two particles at low energies is a constant in the momentum representation, U 0 = 4πħ 2 a / m . In coordinate space this corresponds to a contact interaction U 0 δ( r – r ′), where r and r ′ are the positions of the two particles. To investigate the energy of man y-body states we adopt a Hartree or mean-field approach, and assume that the wave function is a symmetrized product of single-particle wave functions.
In the present chapter we consider the structure of the Bose–Einstein condensed state in the presence of interactions. Our discussion is based on the Gross–Pitaevskii equation, which describes the zero-temperature properties of the non-uniform Bose gas when the scattering length a is much less than the mean interparticle spacing. We shall first derive the Gross–Pitaevskii equation at zero temperature by treating the interaction between particles in a mean-field approximation (Sec. 6.1). Following that, in Sec. 6.2 we discuss the ground state of atomic clouds in a harmonic-oscillator potential. We compare results obtained by variational methods with those derived in the Thomas–Fermi approximation, in which the kinetic energy operator is neglected in the Gross–Pitaevskii equation. The Thomas–Fermi approximation fails near the surface of a cloud, and in Sec. 6.3 we calculate the surface structure using the Gross–Pitaevskii equation. In Sec. 6.4 we determine how the condensate wave function ‘heals’ when subjected to a localized disturbance. Finally, in Sec. 6.5 we show how the magnetic dipole–dipole interaction, which is long-ranged and anisotropic, may be included in the Gross–Pitaevskii equation and determine within the Thomas–Fermi approximation its effect on the density distribution. The Gross–Pitaevskii equation In the previous chapter we have shown that the effective interaction between two particles at low energies is a constant in the momentum representation, U 0 = 4π ħ 2 a/m .
Trapped Bose-condensed atomic gases are remarkable because, in spite of the fact that these are very dilute systems, they exhibit robust coherent dynamic behaviour when perturbed. These quantum “wisps of matter” are a new phase of highly coherent matter. While binary collisions are very infrequent, the large coherent mean field associated with the Bose condensate ensures that interactions play a crucial role in determining the collective response of these trapped superfluid gases. In our discussion of the theory of collective oscillations of atomic condensates, the macroscopic Bose wavefunction Φ( r , t ) plays a central role. This wavefunction is the BEC order parameter. As discussed in Chapter 1, the initial attempts at defining this order parameter began with the pioneering work of London (1938a), were further developed by Bogoliubov (1947) and finally extended to deal with any Bose superfluid using the general quantum field theoretic formalism developed by Beliaev (1958a). Almost all this early theoretical work was limited to T = 0 where, in a dilute weakly interacting Bose gas, all the atoms are in the condensate. The first extension of these ideas to nonuniform Bose condensates was by Pitaevskii (1961) and, independently, by Gross (1961), which led to the now famous Gross–Pitaevskii (GP) equation of motion for Φ( r , t ). Before the discovery of BEC in trapped gases, the time-dependent GP equation was mainly used to study vortices in Bose superfluids, which involve a spatially nonuniform ground state. Apart from this application, the GP equation was largely unknown. The situation changed overnight in 1995 with the creation of trapped nonuniform Bose condensates in atomic gases.
The time-dependent behaviour of Bose–Einstein condensed clouds, such as collective modes and the expansion of a cloud when released from a trap, is an important source of information about the physical nature of the condensate. In addition, the spectrum of elementary excitations of the condensate is an essential ingredient in calculations of thermodynamic properties. In this chapter we treat the dynamics of a condensate at zero temperature starting from a time-dependent generalization of the Gross–Pitaevskii equation used in Chapter 6 to describe static properties. From this equation one may derive equations very similar to those of classical hydrodynamics, which we shall use to calculate properties of collective modes. We begin in Sec. 7.1 by describing the time-dependent Gross–Pitaevskii equation and deriving the hydrodynamic equations. We then use the hydrodynamic equations to determine the excitation spectrum of a homogeneous Bose gas (Sec. 7.2). Subsequently, we consider modes in trapped clouds (Sec. 7.3) within the hydrodynamic approach, and also describe the method of collective coordinates and the related variational method. In Sec. 7.4 we consider surface modes of oscillation, which resemble gravity waves on a liquid surface. The variational approach is used in Sec. 7.5 to treat the free expansion of a condensate upon release from a trap. Finally, in Sec. 7.6 we discuss solitons, which are exact one-dimensional solutions of the time-dependent Gross-Pitaevskii equation. General formulation In the previous chapter we saw that the equilibrium structure of the condensate is described by a time-independent Schrödinger equation with a nonlinear contribution to the potential to take into account interactions between particles.
Abstract Using the linearized version of the time dependent Gross–Pitaevskii equation, we calculate the dynamic response of a Bose–Einstein condensed gas to periodic density and particle perturbations. The zero temperature limit of the fluctuation—dissipation theorem is used to evaluate the corresponding quantum fluctuations induced by the elementary excitations in the ground state. In uniform conditions the predictions of Bogoliubov theory, including the infrared divergency of the particle distribution function and the quantum depletion of the condensate, are exactly reproduced by Gross–Pitaevskii theory. Results are also given for the crossed particle-density response function and the extension of the formalism to nonuniform systems is discussed. The generalization of the Gross–Pitaevskii equation to include beyond mean field effects is finally considered and an explicit result for the chemical potential is found, in agreement with the prediction of Lee–Huang–Yang theory.
For two-component Fermi gases at zero temperature, through a general derivation based on the BCS wave function, our research shows that the nonuniform molecular Bose-Einstein condensate has off-diagonal long-range order and can be described well by an order parameter when the size of molecules is much smaller than the size of the whole system. We also give the equation of state and nonlinear evolution equation for the order parameter of nonuniform molecular condensates, which is similar to the Gross-Pitaevskii equation of atomic Bose condensate. The nonlinear evolution equation is applied to consider the Josephson effect for two weakly linked molecular condensates in the presence of nonuniform magnetic field. We find clear particle-number oscillation where spatially dependent binding energy of molecules plays an important role.