For two-component Fermi gases at zero temperature, through a general derivation based on the BCS wave function, our research shows that the nonuniform molecular Bose-Einstein condensate has off-diagonal long-range order and can be described well by an order parameter when the size of molecules is much smaller than the size of the whole system. We also give the equation of state and nonlinear evolution equation for the order parameter of nonuniform molecular condensates, which is similar to the Gross-Pitaevskii equation of atomic Bose condensate. The nonlinear evolution equation is applied to consider the Josephson effect for two weakly linked molecular condensates in the presence of nonuniform magnetic field. We find clear particle-number oscillation where spatially dependent binding energy of molecules plays an important role.
For two-component Fermi gases at zero temperature, through a general derivation based on the BCS wave function, our research shows that the nonuniform molecular Bose-Einstein condensate has off-diagonal long-range order and can be described well by an order parameter when the size of molecules is much smaller than the size of the whole system. We also give the equation of state and nonlinear evolution equation for the order parameter of nonuniform molecular condensates, which is similar to the Gross-Pitaevskii equation of atomic Bose condensate. The nonlinear evolution equation is applied to consider the Josephson effect for two weakly linked molecular condensates in the presence of nonuniform magnetic field. We find clear particle-number oscillation where spatially dependent binding energy of molecules plays an important role.
Trapped Bose-condensed atomic gases are remarkable because, in spite of the fact that these are very dilute systems, they exhibit robust coherent dynamic behaviour when perturbed. These quantum “wisps of matter” are a new phase of highly coherent matter. While binary collisions are very infrequent, the large coherent mean field associated with the Bose condensate ensures that interactions play a crucial role in determining the collective response of these trapped superfluid gases. In our discussion of the theory of collective oscillations of atomic condensates, the macroscopic Bose wavefunction Φ( r , t ) plays a central role. This wavefunction is the BEC order parameter. As discussed in Chapter 1, the initial attempts at defining this order parameter began with the pioneering work of London (1938a), were further developed by Bogoliubov (1947) and finally extended to deal with any Bose superfluid using the general quantum field theoretic formalism developed by Beliaev (1958a). Almost all this early theoretical work was limited to T = 0 where, in a dilute weakly interacting Bose gas, all the atoms are in the condensate. The first extension of these ideas to nonuniform Bose condensates was by Pitaevskii (1961) and, independently, by Gross (1961), which led to the now famous Gross–Pitaevskii (GP) equation of motion for Φ( r , t ). Before the discovery of BEC in trapped gases, the time-dependent GP equation was mainly used to study vortices in Bose superfluids, which involve a spatially nonuniform ground state. Apart from this application, the GP equation was largely unknown. The situation changed overnight in 1995 with the creation of trapped nonuniform Bose condensates in atomic gases.
We show that the dc Josephson effect with ultracold fermionic gases in the Bose-Einstein-condensate (BEC) regime of composite molecules can be described by a nonlinear Schr\"odinger equation (NLSE). By comparing our results with Bogoliubov--de Gennes calculations [Phys. Rev. Lett. 99, 040401 (2007)] we find that our superfluid NLSE, which generalizes the Gross-Pitaevskii equation taking into account the correct equation of state, is reliable in the BEC regime of the BCS-BEC crossover up to the limit of very large (positive) scattering length. We also predict that the Josephson current displays relevant beyond-mean-field effects.
Abstract This chapter develops the theory of weakly interacting nonuniform Bose gases at zero temperature. Interaction effects are accounted for by a single coupling constant fixed by the value of the s-wave scattering length. The nonlinear Gross–Pitaevskii equation is derived in both the stationary and time-dependent cases. The irrotational nature of the flow and the crucial role played by the chemical potential are highlighted. The classical nature of the equation is emphasized and the analogy with the Maxwell equations of classical electrodynamics is pointed out. The stationary solutions of the Gross–Pitaevskii equation, corresponding to quantized vortex lines, vortex rings, and solitons, are discussed. The time-dependent solutions corresponding to small-amplitude oscillations are derived and the corresponding dispersion relation is shown to coincide with the predictions of Bogoliubov theory for uniform media. The Thomas–Fermi limit is also discussed.
Abstract Chapter 13 addresses Bose condensation in superfluids (and superconductors), which involves the field operator ψ having a c-number component (<ψ(x,t)>≠0), challenging number conservation. The nonlinear Gross-Pitaevskii equation is derived for this condensate wave function <ψ>=ψ−ψ˜, facilitating identification of the coherence length and the core region of vortex motion. The noncondensate Green’s function G˜1(1,1′)=−i<(ψ˜(1)ψ˜+(1′))+> and the nonvanishing anomalous correlation function F˜∗(2,1′)=−i<(ψ˜+(2)ψ˜+(1′))+> describe the dynamics and elementary excitations of the non-condensate states and are discussed in conjunction with Landau’s criterion for viscosity. Associated concepts of off-diagonal long-range order and the interpretation of <ψ> as a superfluid order parameter are also introduced. Anderson’s Bose-condensed state, as a phase-coherent wave packet superposition of number states, resolves issues of number conservation. Superconductivity involves bound Cooper pairs of electrons capable of Bose condensation and superfluid behavior. Correspondingly, the two-particle Green’s function has a term involving a product of anomalous bound-Cooper-pair condensate wave functions of the type F(1,2)=−i<(ψ(1)ψ(2))+>≠0, such that G2(1,2;1′,2′)=F(1,2)F+(1′,2′)+G˜2(1,2;1′,2′). Here, G˜2 describes the dynamics/excitations of the non-superfluid-condensate states, while nonvanishing F,F+ represent a phase-coherent wave packet superposition of Cooper-pair number states and off-diagonal long range order. Employing this form of G2 in the G1-equation couples the condensed state with the non-condensate excitations. Taken jointly with the dynamical equation for F(1,2), this leads to the Gorkov equations, encompassing the Bardeen–Cooper–Schrieffer (BCS) energy gap, critical temperature, and Bogoliubov-de Gennes eigenfunction Bogoliubons. Superconductor thermodynamics and critical magnetic field are discussed. For a weak magnetic field, the Gorkov-equations lead to Ginzburg–Landau theory and a nonlinear Schrödinger-like equation for the pair wave function and the associated supercurrent, along with identification of the Cooper pair density. Furthermore, Chapter 13 addresses the apparent lack of gauge invariance of London theory with an elegant variational analysis involving re-gauging the potentials, yielding a manifestly gauge invariant generalization of the London equation. Consistency with the equation of continuity implies the existence of Anderson’s acoustic normal mode, which is supplanted by the plasmon for Coulomb interaction. Type II superconductors and the penetration (and interaction) of quantized magnetic flux lines are also discussed. Finally, Chapter 13 addresses Josephson tunneling between superconductors.
The recent realization of Bose–Einstein condensation in atomic gases opens new possibilities for the observation of macroscopic quantum phenomena. There are two important features of these systems — weak interaction and significant spatial inhomogeneity. Because of this a non-trivial 'zeroth-order' theory exists, compared to the 'first-order' Bogolubov theory. The zeroth-order theory is based on the mean-field Gross–Pitaevskii equation for the condensate ψ-function. The equation is classical in its essence but contains the constant explicitly. Phenomena such as collective modes, interference, tunneling, Josephson-like current and quantized vortex lines can be described using this equation. Elementary excitations define the thermodynamic behavior of the system and result in a Landau-type damping of collective modes. Fluctuations of the phase of the condensate wave function restrict the monochromaticity of the Josephson current. Fluctuations of the numbers of quanta result in quantum collapse-revival of the collective oscillations.
Using the theoretical formalism of R A Duine and H T C Stoof (arXiv: cond-mat/0303230v) 22 March 2003), we have theoretically evaluated magnetic field and density dependence of the Josephson frequency in coherence atom-molecule oscillation in Bose-Einstein condensed gas.Our theoretically obtained results show that Josephson frequency increases with both magnetic field for constant condensate density and also with condensate density for fixed magnetic field.Our theoretically evaluated results are in good agreement with the experimental data and also with other theoretical workers.Using the theoretical formalism of Markes Greiner etal (Nature, 26 Nov (2005)) , we have studied the emergence of molecular Bose-Einstein condensate from a Fermi gas of 6 Li atoms.The study has been performed with the help of Feshbach resonance.We have evaluated molecular condensate fraction N0/N as a function of (T/TC) and as a function of (T/TF).We have also evaluated scattering length 'a' in unit of a0, of mixture of two lowest hyperfine states of 6 Li atom, temperature (µK) all as a function of magnetic field (mT) near the crossing of the An evaluation …