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Cambridge University Press eBooks

Quantum theory of radiation

Marlan O. Scully, Muhammad Suhail Zubairy

Published Sep 4, 1997• 173 citations
Publisher

Abstract

Light occupies a special position in our attempts to understand nature both classically and quantum mechanically. We recall that Newton, who made so many fundamental contributions to optics, championed a particle description of light and was not favorably disposed to the wave picture of light. However, the beautiful unification of electricity and magnetism achieved by Maxwell clearly showed that light was properly understood as the wave-like undulations of electric and magnetic fields propagating through space. The central role of light in marking the frontiers of physics continues on into the twentieth century with the ultraviolet catastrophe associated with black-body radiation on the one hand and the photoelectric effect on the other. Indeed, it was here that the era of quantum mechanics was initiated with Planck's introduction of the quantum of action that was necessary to explain the black-body radiation spectrum. The extension of these ideas led Einstein to explain the photoelectric effect, and to introduce the photon concept. It was, however, left to Dirac to combine the wave-and particlelike aspects of light so that the radiation field is capable of explaining all interference phenomena and yet shows the excitation of a specific atom located along a wave front absorbing one photon of energy. In this chapter, following Dirac, we associate each mode of the radiation field with a quantized simple harmonic oscillator, this is the essence of the quantum theory of radiation.

DOI
10.1017/cbo9780511813993.003

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Light occupies a special position in our attempts to understand nature both classically and quantum mechanically. We recall that Newton, who made so many fundamental contributions to optics, championed a particle description of light and was not favorably disposed to the wave picture of light. However, the beautiful unification of electricity and magnetism achieved by Maxwell clearly showed that light was properly understood as the wave-like undulations of electric and magnetic fields propagating through space. The central role of light in marking the frontiers of physics continues on into the twentieth century with the ultraviolet catastrophe associated with black-body radiation on the one hand and the photoelectric effect on the other. Indeed, it was here that the era of quantum mechanics was initiated with Planck's introduction of the quantum of action that was necessary to explain the black-body radiation spectrum. The extension of these ideas led Einstein to explain the photoelectric effect, and to introduce the photon concept. It was, however, left to Dirac to combine the wave-and particlelike aspects of light so that the radiation field is capable of explaining all interference phenomena and yet shows the excitation of a specific atom located along a wave front absorbing one photon of energy. In this chapter, following Dirac, we associate each mode of the radiation field with a quantized simple harmonic oscillator, this is the essence of the quantum theory of radiation.
The quantum theory of radiation was formulated by Dirac in 1927, when he combined the wave nature of light with the particle behavior and could explain the interference phenomena. He also explained the atomic behavior of absorbing a discrete quantum of radiation for excitation from one level to another. The Michelson-Morley experiment on light led to the formulation of special theory of relativity, while Rayleigh-Jeans formulation on Black Body radiation led Planck to propose the quantum of action that finally marked the beginning of quantum mechanics. The energy of the radiation field of the classical wave has been expressed as the sum of the energies of individual modes in the cavity. The interaction of atom with radiation field was explained by Einstein in terms of stimulated emission, absorption and spontaneous emission. After the development of quantum mechanics, perturbation theory could be used to describe the Einstein B-coefficients.
The idea of the photon has stirred the imaginations of physicists ever since 1905 when Einstein originally proposed the use of light quanta to explain the photoelectric effect. This concept is formalized in the quantum theory of radiation, which has had unfailing success in explaining the interaction of electromagnetic radiation with matter, seemingly limited only by the ability of physicists to perform the indicated calculations. Nevertheless, it has its conceptual problems—various infinities and frequent misinterpretations. Consequently an increasing number of workers are asking, “to what extent is the quantized field really necessary and useful?” In fact the experimental results of the photoelectric effect were explained by G. Wentzel in 1927 without the quantum theory of radiation. Similarly most electro-optic phenomena such as stimulated emission, reaction of the emitted field on the emitting atom, resonance fluorescence, and so on, do not require the quantization of the field for their explanation. As we will see, these processes can all be quantitatively explained and physically understood in terms of the semiclassical theory of the matter–field interaction in which the electric field is treated classically while the atoms obey the laws of quantum mechanics. The quantized field is fundamentally required for accurate descriptions of certain processes involving fluctuations in the electromagnetic field: for example, spontaneous emission, the Lamb shift, the anomalous magnetic moment of the electron, and certain aspects of blackbody radiation. (The Compton effect also fits here, but see later under references 8b and c.) Here we will outline how the photon concept originated and developed, where it is not required and is often misused, and finally where it plays an essential role in the understanding of physical phenomena. In our discussion we will attempt to give a logically consistent definition of the word “photon”—a statement far more necessary than one might think, for so many contradictory uses exist of this elusive beast. In particular consider the original coining of the word by G. N. Lewis: “[because it appears to spend] only a minute fraction of its existence as a carrier of radiant energy, while the rest of the time it remains an important structural element within the atom…, I therefore take the liberty of proposing for this hypothetical new atom which is not light but plays an essential part in every process of radiation, the name photon!” (our exclamation point). Clearly the present usage of the word is very different.
The study of light through the centuries has produced a number of theories and experiments. Newton advanced the corpuscular theory, building on the early Greek view of matter composed of atoms. Then Young essentially proved the wave nature of light through the interference experiments. Maxwell provided the firm theoretical basis for the wave nature. During the late 1800s and early 1900s, further experiments showed predictions based on a continuous wave led to the well-known ultraviolet catastrophe. Plank and Einstein originated and developed the notion of the photon as an elementary quantum of propagating electromagnetic (EM) energy. The first half of the 20th century saw the development of the field quantization and the quantum electrodynamics (QED). Feynmann labeled QED as ‘‘the best theory we have’’ to describe the matter-light interaction. The second half of the 20th century witnessed the development of the coherent and squeezed optical states attributable to Glauber and Yuen. The study of light and electromagnetic fields has a long history. This chapter explores the nature of light in terms of quantum optics.
Abstract With the failure of classical physics to explain the experimentally observed black body radiation spectrum, the photoelectric effect and the existence of narrow spectral lines in the light emitted by excited atoms, physicists were forced to reach out for new ideas. Following Planck’s initial “drastic hypothesis” of light “quanta”, Einstein led the way in exploring some of the myriad implications of this idea. In particular, the study of fluctuations led to a new understanding of the interaction of electromagnetic radiation with atoms. Einstein invented the photon by showing, through fluctuation studies, that light emitted by atoms must be in the form of plane waves. These ideas led to the first notions regarding the quantization of matter and its dynamics.
This chapter provides a basis for an insight into the nature of quantum effects. The Newtonian approach cannot explain diffraction phenomena. The wave theory of the nature of light proposed by Huygens was able to account for these phenomena as well as for geometric optics. Planck was not only able to overcome the difficulties encountered by his predecessors, but included their findings as special cases of his analysis. Planck considered that the radiating surface was composed of electric dipole oscillators, and that a relationship should exist between the energy of the radiation and the frequency of the oscillators. According to classical theory a continuous spectrum is expected when matter is excited by an arc, or spark, as in spectroscopy. It is found experimentally that only “lines”, or discrete radiations, occur when the light is diffracted. Bohr’s revolutinary ideas provided a significant portion of the bases for the modern understanding of spectra and, consequently, of atomic structure.