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Oxford University Press eBooks

Photons

P. K. Basu

Published Jan 23, 2003• 0 citations
Publisher

Abstract

The classical or semiclassical theory presented in Chapter 2 gives a satisfactory account of light-matter interactions in some cases. However, a detailed understanding of different processes requires a quantum mechanical theory of radiation. The quantum theory of light, like classical theory, is also based on Maxwell's equations. However, in quantum theory the electric field F and the magnetic field H are treated as operators. This chapter develops the correspondence between the two and outlines the method for converting field vectors F and H into quantum mechanical operators. Topics discussed include wave equation in a rectangular cavity, quantization of the electric field, time-dependent perturbation theory, interaction of an electron with the magnetic field, and second-order perturbation theory. Exercises are provided at the end of the chapter.

DOI
10.1093/acprof:oso/9780198526209.003.0003

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Oxford University Press eBooks•Sep 28, 2006•1 citation
The classical or semiclassical theory presented in Chapter 2 gives a satisfactory account of light-matter interactions in some cases. However, a detailed understanding of different processes requires a quantum mechanical theory of radiation. The quantum theory of light, like classical theory, is also based on Maxwell's equations. However, in quantum theory the electric field F and the magnetic field H are treated as operators. This chapter develops the correspondence between the two and outlines the method for converting field vectors F and H into quantum mechanical operators. Topics discussed include wave equation in a rectangular cavity, quantization of the electric field, time-dependent perturbation theory, interaction of an electron with the magnetic field, and second-order perturbation theory. Exercises are provided at the end of the chapter.
Many dynamical processes of interest are either initiated or probed by light, and their understanding requires some knowledge of this subject. This chapter is included in order to make this text self contained by providing an overview of subjects that are used in various applications later in the text. In particular, it aims to supplement the elementary view of radiation–matter interaction as a time-dependent perturbation in the Hamiltonian, by describing some aspects of the quantum nature of the radiation field. This is done on two levels: The main body of this chapter is an essentially qualitative overview that ends with a treatment of spontaneous emission as an example. The Appendix gives some more details on the mathematical structure of the theory. In elementary treatments of the interaction of atoms and molecules with light, the radiation field is taken as a classical phenomenon.
This chapter begins with a review of the semi-classical model of the interaction of charged particles with light, and then proceeds to the full quantum theory by replacing the classical fields with the corresponding field operators. A presentation of the quantum Maxwell equations and their behavior under parity and time reversal transformations is followed by a discussion of stationary density operators. The notion of positive- and negative-frequency parts of field operators is extended to interacting fields and used to define multi-time correlation functions that describe experimental results. The perturbation expansion is formulated by means of the interaction picture and combined with the dipole approximation to calculate the Einstein A- and B-coefficients. The chapter ends with a discussion of spontaneous emission in a cavity and Raman scattering.
We investigate in this chapter the general problem of the interaction of an atom (or a molecule) and a classical electromagnetic field. Its importance derives firstly from the fact that a large part of our knowledge of atoms is obtained from a study of the radiation they absorb or emit (we shall consider equally visible radiation and radio-frequency and X-rays) and, secondly, that the interaction with matter modifies the propagation of the electromagnetic field itself, notably through absorption, refraction or scattering. The interactions of atoms with light therefore encompass a vast range of physical effects that we could not hope to cover adequately in a single chapter. In this chapter we shall therefore present the fundamental features of the interaction of an atom, which will be treated quantum mechanically, with a classical electromagnetic field, that is an electromagnetic field described by real electric and magnetic vectors obeying Maxwell's equations. A rigorous description of the atom–light interaction would have to take into account the quantum nature of light. This we shall leave to Chapter 6. It turns out, nevertheless, that many important results can be obtained from the semi-classical viewpoint adopted here (although it is perhaps more appropriate to refer to this treatment as ‘semi-quantized’).
Abstract The chapter first develops the wave equation in a rectangular cavity and gives the definition and number of density-of-modes within it. Prescription for converting the classical expressions of the EM field to quantized forms in terms of creation and annihilation operators is then outlined. After introducing the concept of photons, the interactions of an atomic system with photons are described in terms of the interaction Hamiltonian. The time-dependent perturbation theory, using the Fermi Golden Rule and the dipole approximation is employed to obtain expressions for the absorption and emission rates. The theory is then applied to the case of a two-level atomic system to obtain the expression for Einstein’s A-coefficient. Broadening of emission line is pointed out and the oscillator strength is defined.
We propose to treat Maxwell equations as a wave equation of motion for a photon (a quantum of light) and to develop the photon mechanics on this basis. Consider vectors of electric and magnetic fields E and H as a single object (a bivector) F , which corresponds to the function ψ in the wave theory of the electron. Multiplying the vacuum Maxwell equations − rotH+ 1 c ∂E ∂t = 0, rot E + 1 c ∂H ∂t = 0 (1) by hc 2πi , it is possible to rewrite them in the form HF + h 2πi ∂F ∂t = 0, (2) where H is the operator H = hc 2πi { 0 − rot rot 0 } ; (3) its meaning follows from the comparison of equation (2) with (1). Equation (2) can be interpreted as a wave equation for a photon.
Thus far, we have developed the properties of the electromagnetic field at optical frequencies, based on Maxwell’s equations. These equations further give a classical macroscopic perspective on the coupling of the propagation media to the field, as presented in Chapter 2. The macroscopic properties of a medium are based on averaged microscopic properties. The microscopic energy structure of matter was presented in Chapter 3, covering gases, solids, and liquids by employing mostly quantum models. We now proceed to the next level of development, the dynamic description of the interaction between the optical field and the propagation medium as a function of the field frequency and propagation media variables (e.g., energy structure, temperature, and pressure). In this chapter, the classical electromagnetic field is coupled to discrete frequency oscillators via Newton’s equation of motion. This approach leads to the popular classical oscillator model, often presented in introductory books on lasers. The classical oscillator model is an incomplete theory and can be only a semiempirical model. In the next chapter, a more detailed and comprehensive approach, which also includes statistical and quantum mechanics, is used leading to robust semiclassical and quantum oscillator models. This chapter and the next are the basis for the applied models presented in Part II of this book. Classical electrodynamics is based on Maxwell’s equations, as given in Chapter 2, and the Lorentz force relation, as given below: . . . F = q[E + (v × B)]. (4.1) . . . These equations cover the classical description of the interaction of light and matter. The first term in Eq. 4.1 represents coupling of the electric field to the medium. As discussed in Chapter 2 (Section 2.2), the leading mechanism for this is the electric dipole moment. To see that this is the coupling mechanism in the first term, consider the potential function driving this force, F = −∇V(r) = −∇(−qr · E). The above expression contains the dipole moment, as defined in Chapter 2. The second term in Eq. 4.1 represents coupling of the magnetic field to the medium.