Quantization of physical systems requires a correct definition of quantum-mechanical observables, such as the Hamiltonian, momentum, etc., as self-adjoint operators in appropriate Hilbert spaces and t
In the theory of quantum mechanics the Hamiltonian H is typically selfadjoint, i.e., H = H *. The self-adjointness ensures that the spectrum of the Hamiltonian, representing the energy spectrum of H , is real but it is not a necessary condition. In the literature on so-called PT -symmetric quantum mechanics (see, e.g., [BB98], [BBM99], [BBJ03], [Ben04b] and [Ben07]), it is believed that self-adjointness is rather a mathematical requirement than a physically established fact. Therefore, it was considered a surprise that operators exist which are not self-adjoint in the given quantum mechanical Hilbert space, but have real spectrum and that – if e.g. complex eigenvalues were present – they occurred only in complex conjugate pairs.
We are focused on the idea that observables in quantum physics are a bit more then just hermitian operators and that this is, in general, a “tricky business”. The origin of this idea comes from the fact that there is a subtle difference between symmetric, hermitian, and self-adjoint operators which are of immense importance in formulating Quantum Mechanics. The theory of self-adjoint extensions is presented through several physical examples and some emphasis is given on the physical implications and applications.
A quantization of a fixed classical mechanical system is firstly an association between quantum mechanical observables (preferably self-adjoint operators on Hilbert space) and classical mechanical observables (i.e. real-valued functions on phase space). Secondly, a quantization should permit an interpretation of the correspondence principle that ‘classical mechanics is the limit of quantum mechanics as Planck's constant approaches zero'. With these two underlying precepts, Section 2 states the four basic requirements, I to IV, of a quantization along with an additional requirement V that characterizes the subclass of special quantizations.
Let H be a self-adjoint operator (a Hamiltonian) on a complex Hilbert space $ \mathcal{H}$
Abstract The object of this book is to present the new quantum mechanics in a unified representation which, so far as it is possible and useful, is mathematically rigorous [A]presentation of the mathematical tools necessary for the purposes of this theory will be given, i.e., a theory of Hilbert spaces and the so-called Hermitian [or self-adjoint] operators. To this end, an accurate introduction to unbounded operators is also necessary; that is, an extension of the theory beyond its classical limits (developed by Hilbert and E. Hellinger, F. Riesz, E. Schmidt, 0. Toeplitz). The following may be said regarding the method employed in this type of treatment: as a rule, calculations should be performed with the operators themselves (which represent physical quantities) and not with the matrices, which, after the introduction of a (special and arbitrary) coordinate system in Hilbert space, result from them. This “coordinate free” (i.e., invariant) method, with its strongly geometric language, possesses noticeable formal advantages.