This chapter addresses phase transitions and dynamic scaling occurring in systems comprised of interacting indistinguishable quantum particles, for which entanglement correlations are crucial. It first describes how the dynamics (in real time) and thermodynamics (in imaginary time) of quantum many-particle Hamiltonians can be mapped onto field theories based on coherent-state path integrals. While bosons are described by complex-valued fields, fermions are represented by anticommuting Grassmann variables. Since quantum-mechanical systems are of inherently dynamical nature, the corresponding field theory action entails d + 1 dimensions, with time playing a special role. For Hamiltonians that incorporate only two-particle interactions, we can make contact with the previously studied Langevin equations, yet with effectively multiplicative rather than additive noise. As an illustration, this formalism is applied to deduce fundamental properties of weakly interacting boson superfluids. Whereas Landau–Ginzburg theory already provides a basic hydrodynamic description, the Gaussian approximation allows the computation of density correlations, the Bose condensate fraction, and the normal- and superfluid densities from the particle current correlations. We next establish that quantum fluctuations are typically irrelevant for thermodynamic critical phenomena, provided that T c > 0, and readily extend finite-size scaling theory to the imaginary time axis to arrive at general scaling forms for the free energy. Intriguing novel phenomena emerge in the realm of genuine quantum phase transitions at zero temperature, governed by other control parameters such as particle density, interaction or disorder strengths.
This chapter addresses phase transitions and dynamic scaling occurring in systems comprised of interacting indistinguishable quantum particles, for which entanglement correlations are crucial. It first describes how the dynamics (in real time) and thermodynamics (in imaginary time) of quantum many-particle Hamiltonians can be mapped onto field theories based on coherent-state path integrals. While bosons are described by complex-valued fields, fermions are represented by anticommuting Grassmann variables. Since quantum-mechanical systems are of inherently dynamical nature, the corresponding field theory action entails d + 1 dimensions, with time playing a special role. For Hamiltonians that incorporate only two-particle interactions, we can make contact with the previously studied Langevin equations, yet with effectively multiplicative rather than additive noise. As an illustration, this formalism is applied to deduce fundamental properties of weakly interacting boson superfluids. Whereas Landau–Ginzburg theory already provides a basic hydrodynamic description, the Gaussian approximation allows the computation of density correlations, the Bose condensate fraction, and the normal- and superfluid densities from the particle current correlations. We next establish that quantum fluctuations are typically irrelevant for thermodynamic critical phenomena, provided that T c > 0, and readily extend finite-size scaling theory to the imaginary time axis to arrive at general scaling forms for the free energy. Intriguing novel phenomena emerge in the realm of genuine quantum phase transitions at zero temperature, governed by other control parameters such as particle density, interaction or disorder strengths.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.
Introduction The quantum phase transitions considered so far in this book are mostly continuous, second order. They are associated with the divergence of a correlation length and of a characteristic time that renders the quantum critical point scale invariant. However, there are many important phase transitions at which the order parameter goes abruptly to zero and, more important, at which the characteristics of length and critical time do not diverge. In general there is also a latent heat , or work required, to transform one phase into another. In this and the next chapter we study these discontinuous quantum phase transitions. We proceed by considering initially some important cases of what is known as fluctuation induced quantum phase transitions to next treat a more general case of a first-order quantum phase transition. We will show through the study of these problems that the concepts of critical exponents and scaling remain useful, even though these systems do not exhibit scale invariance at their critical point. In Chapter 15 we present the scaling theory of first-order quantum phase transitions and use its results to treat some general problems. One of the most interesting cases of fluctuation-induced transitions occurs in superconductors due to the coupling of the charged carriers to the electromagnetic field. We consider initially a wider class of systems with macroscopic wave functions, the superfluids, of which superconductors are the charged version. We adopt a macroscopic approach to this problem and describe the superfluid by a complex order parameter φ , such that | φ | 2 is proportional to the density of condensed particles. The zero temperature phase diagram is expressed in terms of a control parameter, m 2 , such that, at m 2 = 0, the system presents a quantum phase transition from a superfluid state, for m 2 < 0, φ ≠ 0, to a normal state for m 2 > 0 where φ = 0. In the case of the superconductor with particles of charge q = 2 e , we will include the coupling of these particles to the electromagnetic field and study its effect in the phase diagram of these systems. We show that in the neutral superfluid, the zero temperature transition to the normal state is continuous and occurs at a quantum critical point.
The dynamical critical exponent is introduced. The phase diagram and the phase transitions in the Bose–Hubbard model of interacting bosons on a lattice are determined. The concept of quantum fluctuations is introduced on the example of an interacting superfluid, and finally the special scaling of conductivity is discussed. Dynamical critical exponent The finite temperature phase transitions studied in previous chapters are the result of the competition between the entropy and the energy terms in the free energy: the weight of entropy increases with temperature, and ultimately destroys the order that may be existing in the system. A sharp phase transition between two phases exhibiting qualitatively different correlations may, however, occur even at zero temperature, by varying a coupling constant in the Hamiltonian. The transition then corresponds to a non-analyticity of the energy of the ground state. A simple example is provided by the interacting bosons, where the superfluid transition may be brought about by tuning the chemical potential at T = 0. Such T = 0 phase transitions are called quantum phase transitions , and will be the subject of the present chapter. In general, a quantum phase transition may lie at the end of a line of thermal phase transitions, as in the bosonic example mentioned above. It is possible, however, that the system may not even have an ordered state at finite temperatures, but still exhibits a quantum critical point. Two different situations are depicted in Fig. 8.1. Examples of such phase diagrams are provided by the system of interacting bosons which will be discussed in Sections 8.2 and 8.3.
Abstract Interacting many-particle systems may undergo phase transitions and exhibit critical phenomena in the limit of infinite system size, while the precursors of these phenomena are studied in the theory of finite-size scaling. After surveying the basic notions of phases, phase diagrams, and phase transitions, this chapter focuses on critical behaviour at a second-order phase transition. The Landau-Ginzburg theory and the concept of scaling prepare readers for an elementary introduction to the concepts of the renormalization group, followed by an introduction into the field of quantum phase transitions where quantum fluctuations take over the role of thermal fluctuations.
In the first part of the Thesis we mostly concentrate on spectral properties of strongly correlated systems and on their equilibrium properties. This is accomplished by the general concept of imaginary-time dynamics which we apply to a number of different problems in which different strengths of this approach emerge. In Chapter 1 we introduce the formalism that allows for a connection between the quantum and the classical worlds. The connection is established by means of the imaginary-time quantum evolution which, under certain circumstances, is shown to be equivalent to a classical stochastic process. It is further shown that exact static and spectral properties of correlated systems can be obtained when this mapping is feasible. The relationship between the imaginary-time dynamics in different frameworks such as the path-integral and the perturbative one is also underlined. In Chapter 2 we present a specific implementation of the general ideas previously presented. In particular we introduced an extension to lattice systems of the Reptation Monte Carlo algorithm [30] which benefits of a sampling scheme based on directed updates. Specific improvements over the existing methodologies consist in the unbiased evaluation of the imaginary-time path integrals for bosons and a systematic scheme to improve over the Fixed-node approximation for fermions. Applications to the Hubbard and the Heisenberg models are presented. In Chapter 3 we demonstrate the application of the imaginary-time dynamics to the exact study of spectral properties. Subject of our attention is a highly anharmonic and correlated quantum crystal such as Helium 4 at zero temperature.[33] Concerning this system, we have obtained the first ab-initio complete phonon dispersion in good agreement with neutron spectroscopy experiments. Moreover, we have also studied the density excitations of solid helium in a region of wave-vectors in between the collective (phonon) and the single-particle regimes, where the presence of residual coherence in the dynamics shows analogies between the highly anharmonic crystal and the superfluid phase. In Chapter 4 we introduce a novel method, based on the imaginary-time dynamics, to obtain unbiased estimates of fermionic properties.[34] By means of this method and of a very accurate variational state, we provide strong evidence for the stability of a saturated ferromagnetic phase in the high-density regime of the two-dimensional infinite-U Hubbard model. By decreasing the electron density, we observe a discontinuous transition to a paramagnetic phase, accompanied by a divergence of the susceptibility on the paramagnetic side. This behavior, resulting from a high degeneracy among different spin sectors, is consistent with an infinite-order phase transition scenario. In Chapter 5 the use of imaginary-time dynamics in the context of finite-temperature response functions is highlighted. As an application, we study an intriguing quantum phase featuring both glassy order and Bose-Einstein condensation. [35] We introduce and validate a model for the role of geometrical frustration in the coexistence of off-diagonal long range order with an amorphous density profile. The exact characterization of the response of the system to an external density perturbation is what allows here to establish the existence of a spin-glass phase. The differences between such a phase and the otherwise insulating "Bose glasses" are further elucidated in the Chapter. In the second part of the Thesis we focus our attention on the dynamics of closed systems out of equilibrium. This is accomplished by both non-stochastic exact methods for the dynamics and the introduction of a novel time-dependent Variational Monte Carlo scheme. In Chapter 6 exact diagonalization schemes and renormalization-based methods for one-dimensional systems are introduced. We identify key phenomenological traits resulting from the many-body correlation in closed systems driven sufficiently away from equilibrium.[31] We provide evidences that the dynamics of interacting lattice bosons away from equilibrium can be trapped into extremely long-lived inhomogeneous metastable states. The slowing down of incoherent density excitations above a threshold energy, much reminiscent of a dynamical arrest on the verge of a glass transition, is identified as the key feature of this phenomenon. In Chapter 7 we present an extension to dynamical properties of the Variational Quantum Monte Carlo method.[32] This is accomplished by introducing a general class of time-dependent variational states which is based on the mapping of the many-body dynamics onto an instantaneous ground-state problem. The application of the method to the experimentally relevant quantum quenches of interacting bosons reveals the accuracy and the reliability of the introduced numerical scheme. We indeed obtain for the first time a consistent variational description of the approach to the equilibrium of local observables and underline the origin of the metastability and glassy behavior previously identified. In the very last part we draw our conclusions and show some possible paths for stimulating future research.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.