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arXiv:cond-mat/9609279 · Reviews of Modern Physics

Continuous quantum phase transitions

Shivaji L. Sondhi, S. M. Girvin, John P. Carini, D. Shahar

Published Jan 1, 1997• 1,294 citations
arXivHTMLPDF

Abstract

A quantum system can undergo a continuous phase transition at the absolute zero of temperature as some parameter entering its Hamiltonian is varied. These transitions are particularly interesting for, in contrast to their classical finite-temperature counterparts, their dynamic and static critical behaviors are intimately intertwined. Considerable insight is gained by considering the path-integral description of the quantum statistical mechanics of such systems, which takes the form of the classical statistical mechanics of a system in which time appears as an extra dimension. In particular, this allows the deduction of scaling forms for the finite-temperature behavior, which turns out to be described by the theory of finite-size scaling. It also leads naturally to the notion of a temperature-dependent dephasing length that governs the crossover between quantum and classical fluctuations. Using these ideas, a scaling analysis of experiments on Josephson-junction arrays and quantum-Hall-effect systems is presented.

DOI
10.1103/revmodphys.69.315

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A quantum system can undergo a continuous phase transition at the absolute zero of temperature as some parameter entering its Hamiltonian is varied. These transitions are particularly interesting for, in contrast to their classical finite-temperature counterparts, their dynamic and static critical behaviors are intimately intertwined. Considerable insight is gained by considering the path-integral description of the quantum statistical mechanics of such systems, which takes the form of the classical statistical mechanics of a system in which time appears as an extra dimension. In particular, this allows the deduction of scaling forms for the finite-temperature behavior, which turns out to be described by the theory of finite-size scaling. It also leads naturally to the notion of a temperature-dependent dephasing length that governs the crossover between quantum and classical fluctuations. Using these ideas, a scaling analysis of experiments on Josephson-junction arrays and quantum-Hall-effect systems is presented.
This chapter addresses phase transitions and dynamic scaling occurring in systems comprised of interacting indistinguishable quantum particles, for which entanglement correlations are crucial. It first describes how the dynamics (in real time) and thermodynamics (in imaginary time) of quantum many-particle Hamiltonians can be mapped onto field theories based on coherent-state path integrals. While bosons are described by complex-valued fields, fermions are represented by anticommuting Grassmann variables. Since quantum-mechanical systems are of inherently dynamical nature, the corresponding field theory action entails d + 1 dimensions, with time playing a special role. For Hamiltonians that incorporate only two-particle interactions, we can make contact with the previously studied Langevin equations, yet with effectively multiplicative rather than additive noise. As an illustration, this formalism is applied to deduce fundamental properties of weakly interacting boson superfluids. Whereas Landau–Ginzburg theory already provides a basic hydrodynamic description, the Gaussian approximation allows the computation of density correlations, the Bose condensate fraction, and the normal- and superfluid densities from the particle current correlations. We next establish that quantum fluctuations are typically irrelevant for thermodynamic critical phenomena, provided that T c > 0, and readily extend finite-size scaling theory to the imaginary time axis to arrive at general scaling forms for the free energy. Intriguing novel phenomena emerge in the realm of genuine quantum phase transitions at zero temperature, governed by other control parameters such as particle density, interaction or disorder strengths.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.
Classical and quantum criticality In most cases the phases of quantum field theories, in particular those of interest in condensed matter physics, can be described in terms of the behavior of local observables, such as order parameters or currents that transform properly under the symmetries of the theory. Quantum and thermal phase transitions are characterized by the behavior of these observables as a function of temperature and of the coupling constants of the theory. The phase transitions themselves, quantum or thermal, are classified into universality classes, which are represented by the critical exponents which specify the scaling laws of the expectation values of the observables. Historically, the development of this approach to critical behavior goes back to the Landau theory of critical behavior. It acquired its most complete form with the development of the renormalization group (RG) in the late 1960s and early 1970s. It is the centerpiece of Wilson’s approach to quantum field theory, in which all local quantum field theories are defined by the scaling regime of a physical system near a continuous phase transition. From this point of view there is no fundamental difference between classical (or thermal) phase transitions, which are described by the theory of classical critical behavior, and quantum phase transitions. For example, the expectation value of a local order parameter M as the thermal phase transition is approached from below behaves as M ~ (Tc − T) β . Here T c is the critical temperature and β is a critical exponent that depends on the universality class of the thermal phase transition and on the dimensionality of space. While quantum mechanics can play a key role in the existence of the ordered phase, e.g. superfluidity and superconductivity are macroscopic manifestations of essentially quantum-mechanical phenomena, the thermal transition itself is governed entirely by classical statistical mechanics, and quantum mechanics plays a role in setting the value of non-universal quantities such as the critical temperature, etc. On the other hand, in the case of a quantum phase transition, the order parameter M has a similar scaling behavior as a function of the coupling constant, M~(gc−g)β˜, where g is the coupling constant, g c is the critical coupling constant, and β˜ is a critical exponent that depends on the universality class of the quantum phase transition. Here we assume that M has a non-vanishing expectation value only for g < g c .
Many electronic systems (e.g., the cuprate superconductors and heavy fermions) exhibit striking features in their dynamical response over a prominent range of experimental parameters. While there are some empirical suggestions of particular increasing length scales that accompany such transitions in some cases, this identification is not universal and in numerous instances no large correlation length is evident. To better understand, as a matter of principle, such behavior in quantum systems, we extend a known mapping (earlier studied in stochastic or supersymmetric quantum mechanics) between finite temperature classical Fokker-Planck systems and related quantum systems at zero temperature to include general nonequilibrium dynamics. Unlike Feynman mappings or stochastic quantization methods in field theories (as well as more recent holographic type dualities), the classical systems that we consider and their quantum duals reside in the same number of space-time dimensions. The upshot of our very broad and rigorous result is that a Wick rotation exactly relates (i) the dynamics in general finite temperature classical dissipative systems to (ii) zero temperature dynamics in the corresponding dual many-body quantum systems. Using this correspondence, we illustrate that, even in the absence of imposed disorder, many continuum quantum fluid systems (and possible lattice counterparts) may exhibit a zero-point ``quantum dynamical heterogeneity'' wherein the dynamics, at a given instant, is spatially nonuniform. While the static length scales accompanying this phenomenon do not seem to exhibit a clear divergence in standard correlation functions, the length scale of the dynamical heterogeneities can increase dramatically. We further study ``quantum jamming'' and illustrate how a hard-core bosonic system can undergo a zero temperature quantum critical metal-to-insulator-type transition with an extremely large effective dynamical exponent z>4z>4z>4 that is consistent with length scales that increase far more slowly than the relaxation time as a putative critical transition is approached. Similar results may hold for spin-liquid-type as well as interacting electronic systems. We suggest ways to analyze experimental data in order to adduce such phenomena. Our approach may be used to analyze other quenched quantum systems.
Zero-temperature or quantum phase transitions in itinerant electronic systems both with and without quenched disordered are discussed. Phase transitions considered include, the ferromagnetic transition, the antiferromagnetic transition, the superconductor-metal transition, and various metal-insulator transitions. Emphasis is placed on how to determine the universal properties that characterize these quantum phase transitions. For the first three of the phase transitions listed above, one of the main physical ideas established is that in zero-temperature systems there are soft or slow modes that exist in addition to the soft order parameter fluctuations, and that these modes can couple to the critical modes. These extra soft modes are shown to have a profound effect on the quantum critical properties. For quantum phase transitions involving zero wavenumber order parameters, i.e., the ferromagnetic and superconductor-metal transitions, these extra modes effectively lead to long-ranged effective interactions between order parameter fluctuations, which in turn lead to exactly soluble critical behaviors. For the antiferromagnetic case, we argue that while in low enough dimensions disorder fluctuation effects tend to destroy long-range order, quantum fluctuations counteract this effect and in some parameter regions manage to re-establish antiferromagnetic long-range order. For the metal-insulator transition, some recent new ideas are reviewed. In particular, it is pointed out that for interacting disordered electrons, one expects that in high dimensions the metal-insulator transition is related to the phase transition that occurs in random-field magnets in high dimensions. If the analogy also holds in three dimensions this suggests that the metal-insulator transition might have glassy characteristics.