We review some of the difficulties previously encountered in defining the phase operator for finite quantum systems. We then propose the Wigner–Weyl quantization of the angle function φ on phase space as the phase operator, and derive a closed expression for its matrix elements with respect to the Hermite functions. We also determine the quantization of e^{iφ} , which turns out to be a weighted shift operator, its spectrum and that of its adjoint. This is done in the framework of quantization of a certain symbol class of phase space distributions, specialized to those which depend on one variable only. After recalling some results for the position and momentum variables, we apply the scheme to functions of radius or angle. We give necessary and sufficient conditions for operators obtained by quantizing functions of the angle to be elements of \mathscr L^+ [\mathscr S(\mathbf R)] and \mathscr L^+ [\mathscr S (\mathbf R), L^2(\mathbf R)] , and a sufficient condition for boundedness. We then consider the associated questions of commutation relations and uncertainties for operators in \mathscr L^+ [\mathscr S(\mathbf R), L^2(\mathbf R)] , which we define as bilinear forms. As must be the case, the commutator between our phase operator and the number operator exhibits noncanonical terms. Not surprisingly, the Poisson bracket of their phase space symbols also exhibits a noncanonical term.
In the usual treatment of the field theory of the nonrelativistic Schrödinger equation, there are more dynamical variables than is warranted by the number of degrees of freedom. This causes difficulties in the canonical quantization. Working in momentum space it is possible to eliminate the extra dynamical variables, leaving a number of independent dynamical variables appropriate to the number of degrees of freedom. The canonical commutation relations can then be applied in a straightforward manner.
The quantum mechanical description of the azimuthal rotation angle and the orbital angular momentum around the polar axis differs greatly from the description of position and momentum. This has led to a controversy over the existence of a self-adjoint angle operator in the literature. It is possible to circumvent the problems of defining a self-adjoint operator for a periodic variable by using trigonometric functions of operators as a basis for the quantum mechanical description. This approach, however, does not allow us to study the properties of the angle operator itself. By using a state space of an arbitrarily large yet finite number of dimensions, it is possible to introduce angle and orbital angular momentum as a conjugate pair of variables both represented by Hermitian matrices. After physical and measurable quantities have been calculated in this state space the number of dimensions is allowed to tend to infinity in a limiting procedure. The first part of this chapter reviews the difficulties associated with the quantum mechanical formulation of angle and orbital angular momentum and presents a way to overcome these problems using a finite-dimensional state space. In the second part this formulation is generalised to include the phenomenon of non-integer orbital angular momentum. This part is based on a chapter of the PhD thesis of Götte [1], where further details may be found. Introduction The correct description of a periodic variable such as a rotation angle or the optical phase has been a long standing problem in quantum mechanics. At the root of the problem is the question of whether the variable itself is restricted in a 2 π radian range or whether it evolves continuously without bound.
The question how to quantize a classical system where an angle $\ensuremath{\varphi}$ is one of the basic canonical variables has been controversial since the early days of quantum mechanics. The problem is that the angle is a multivalued or discontinuous variable on the corresponding phase space. The remedy is to replace $\ensuremath{\varphi}$ by the smooth periodic functions $\mathrm{cos}\phantom{\rule{0.2em}{0ex}}\ensuremath{\varphi}$ and $\mathrm{sin}\phantom{\rule{0.2em}{0ex}}\ensuremath{\varphi}$. In the case of the canonical pair $(\ensuremath{\varphi},{p}_{\ensuremath{\varphi}})$, where ${p}_{\ensuremath{\varphi}}$ is the orbital angular momentum (OAM), the phase space ${\mathcal{S}}_{\ensuremath{\varphi},{p}_{\ensuremath{\varphi}}}={\ensuremath{\varphi}∊\mathbb{R}\phantom{\rule{0.2em}{0ex}}\mathrm{mod}\phantom{\rule{0.2em}{0ex}}2\ensuremath{\pi},{p}_{\ensuremath{\varphi}}∊\mathbb{R}}$ has the global topological structure ${S}^{1}\ifmmode\times\else\texttimes\fi{}\mathbb{R}$ of a cylinder on which the Poisson brackets of the three functions $\mathrm{cos}\phantom{\rule{0.2em}{0ex}}\ensuremath{\varphi},\mathrm{sin}\phantom{\rule{0.2em}{0ex}}\ensuremath{\varphi}$, and ${p}_{\ensuremath{\varphi}}$ obey the Lie algebra of the Euclidean group
E(2) in the plane. This property provides the basis for the quantization of the system in terms of irreducible unitary representations of the group
E(2) or of its covering groups. A crucial point is that, due to the fact that the subgroup $\mathrm{SO}(2)\ensuremath{\cong}{S}^{1}$ is multiply connected, these representations allow for fractional OAM $l=\ensuremath{\hbar}(n+\ensuremath{\delta}),n∊\mathbb{Z},\ensuremath{\delta}∊[0,1)$. Such $\ensuremath{\delta}\ensuremath{\ne}0$ have already been observed in cases like the Aharonov-Bohm and fractional quantum Hall effects, and they correspond to the quasimomenta of Bloch waves in ideal crystals. The proposal of the present paper is to look for fractional OAM in connection with the quantum optics of Laguerre-Gaussian laser modes in external magnetic fields. The quantum theory of the phase space ${\mathcal{S}}_{\ensuremath{\varphi},{p}_{\ensuremath{\varphi}}}$ in terms of unitary representations of
E(2) allows for two types of ``coherent'' states, the properties of which are discussed in detail: nonholomorphic minimal-uncertainty states and holomorphic ones associated with Bargmann-Segal Hilbert spaces.
The foundations of quantum mechanics are analyzed, and some problems that appeared during its crea-tion and remain unsolved today are emphasized. It is shown that the introduction of variable wave number k, depending on electron coordinates, and the omission of the azimuth part of the wave function ̂ ψ, were erro-neous. Including the azimuth factor of the wave function and taking into consideration the constant value of k result in wave-equation solutions showing a discrete nodal structure of intratomic space, and arrives at a peri-odic-nonperiodic law for behavior of atomic structures. Viewing atoms as quasi-spherical neutron molecules makes it possible to understand characteristic features of the periodic table. PACS Numbers: 03.65.Bz, 03.65.Ge 1.